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 The authors thank Masashi Watanabe for the Digital Micrograph PCA plug-in, Andrew Lupini for the atom mapping scripts and J. Luck for help with the specimen preparation. Research at ORNL was supported by the U.S. Department of Energy, Basic Energy Sciences, Materials Sciences and Engineering. Research at UCM was supported by Spanish MICINN through grants MAT2011-27470- C02 and Consolider Ingenio 2010-CSD2009-00013 (Imagine), by CAM through grant S2009/MAT- 1756 (Phama) and by the ERC Starting Investigator Grant #239739 STEMOX.