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Phase Identification in Mixed Oxide Capacitors Using Electron Backscatter Diffraction and X-Ray Diffraction

Published online by Cambridge University Press:  02 July 2020

P. M. Adams
Affiliation:
The Aerospace Corporation, P. O. Box 92957, Los Angeles, CA90009
C. T. Hoskinson
Affiliation:
The Aerospace Corporation, P. O. Box 92957, Los Angeles, CA90009
R. Witt
Affiliation:
TSL, 392 East 12300 South, Suite H, Draper, UT84020
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Extract

A group of mixed oxide ceramic capacitors used in several electronic systems recently failed as a result of voltage breakdown in the specified test ranges. These capacitors consist predominantly of mixed oxides of magnesium, titanium, silicon and aluminum (with minor amounts of strontium and calcium) and contain palladium mesh electrodes. Preliminary results suggest that phase transformations have occurred in some lots of capacitors that have been over-fired as a result of a manufacturing change. Several years’ production of capacitors has potentially been affected. The formation of a phase with inferior dielectric properties, and which can exhibit semiconducting properties (P/N junction), probably resulted in the failure of the capacitors. This new phase is typically rich in strontium and is only present at levels of several volume percent. The low concentration of this phase has made its identification difficult. If this new phase could be identified it might be possible to determine/establish if its dielectric properties are consistent with the proposed failure mechanism.

Type
Advances in the Instrumentation and Application of Electron Backscatter Diffraction in the SEM
Copyright
Copyright © Microscopy Society of America

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