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Crystallographic Origin of the Alternate Bright/Dark Contrast in 6H-SiC and other Hexagonal Crystal HREM Images

Published online by Cambridge University Press:  31 July 2003

J.S. Bow
Affiliation:
Science and Engineering of Materials Program, and Center for Solid State Science, Arizona State University, Tempe, AZ 85287-1704 Now at: Materials Research Laboratories, Industrial Technology Research Institute, 195-5 Chung Hsing Rd, Sec. 4, Bldg. 77, Chutung, Hsinchu, Taiwan 31015, R. O. C.
R.W. Carpenter
Affiliation:
Science and Engineering of Materials Program, and Center for Solid State Science, Arizona State University, Tempe, AZ 85287-1704 Also with: Chemical, Bio, and Materials Engineering Department, Arizona State University, Tempe, AZ 85287-1704
M.J. Kim
Affiliation:
Science and Engineering of Materials Program, and Center for Solid State Science, Arizona State University, Tempe, AZ 85287-1704
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Abstract

Alternating bright/dark anomalous subunitcell contrast in HREM images along or near the close-packed direction of 6H-SiC, Ti5Si3, α-Ti, and 4H-SiC, all of which are hexagonal, was examined using computer-generated crystal models, HREM image simulations, and digital diffractograms from the corresponding experimental images. The primary variables were crystal tilt and thickness. Crystal model projections showed that the scattering potential was smeared anisotropically within the unit cells by small crystal tilts, which reproduced the experimentally observed anomalous subunit-cell contrast modulations in the corresponding simulations. The effect increased with thickness, but it did not occur in exact zone axis simulations for any crystal thickness. Structural considerations indicated that the contrast resulted from tilt-induced violations of Gjonnes-Moodie dynamical extinctions and excitation of kinematically forbidden reflections in the imaging zone. Digital diffractograms from experimental HREM images confirmed their presence in the imaging zone diffraction patterns. These effects were absent in HREM images from cubic crystals in this material system because the structurally induced requisite kinematically forbidden reflections do not occur in the imaging zone.

Type
Research Article
Copyright
1996 Microscopy Society of America

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