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The application of statistical methods to immobile adsorbed films

Published online by Cambridge University Press:  24 October 2008

J. K. Roberts  and
A. R. Miller
J. K. Roberts
Affiliation:
Department of Colloid ScienceCambridge
A. R. Miller
Affiliation:
Department of Colloid ScienceCambridge
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Extract

Bethe's method is applied to determine statistically the rate of condensation of diatomic molecules which are adsorbed with dissociation to form an immobile film, the two atoms of one adsorbed molecule occupying two neighbouring sites. A lower limit to the number of gaps, or isolated unoccupied sites, in the final film is also obtained. The results calculated statistically agree with those obtained earlier by using models.

Type
Research Article
Information
Mathematical Proceedings of the Cambridge Philosophical Society , Volume 35 , Issue 2 , April 1939 , pp. 293 - 297
Copyright
Copyright © Cambridge Philosophical Society 1939

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References

* Roberts, J. K., Proc. Cambridge Phil. Soc. 34 (1938), 399.CrossRefGoogle Scholar

† Bethe, , Proc. Roy. Soc. A, 154 (1936), 207.Google Scholar

* Roberts, loc. cit. Equation (19) of this paper is quoted below as our equation (10).

* Roberts, J. K., Proc. Roy. Soc. A, 152 (1935), 473.Google Scholar