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Various applications demand various kinds of ions. Charge state, energy and the amount of laser produced ions depend, primary, on the wavelength, the energy, the pulse duration, and the focusing ability of the laser used. Angle of the target irradiation, angle of the ion extraction (recording), and mainly the focus setting may significantly influence especially the portion of ions with the highest charge states. The participation of non-linear processes on the generation of ions with extremely high parameters is demonstrated. The observed effects support the idea of a longitudinal structure of the self-focused laser beam with a space period of ∼200 µm.