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Supercapacitance properties of porous carbon from chemical blending of phenolic resin and aliphatic dicarboxylic acids

  • Xiaohong Xia (a1), Xuefang Zhang (a2), Shangqi Yi (a2), Hui Chen (a2) and Hongbo Liu (a1)...

Abstract

We have reported the chemical blending carbonization method to obtain microporous carbon with high surface area for application as electrode materials in supercapacitors. Aliphatic dicarboxylic acids with different methylene numbers (n = 2, 4, 6, and 8) react with phenolic resin (PF) during curing process. Abundant micropores are created in the carbon matrix after the decomposition of grafted or blocked diacids at temperature higher than 400 °C. The specific surface area (SSA) of the carbonized blending system increases with the diacid chain length, but decreases after n > 4 of the chain length. The maximum SSA of the blending system is up to 605.9 m2/g, which increased approximately 68% compared to that of the neat carbonized PF. Electrochemical investigation indicates that the highest specific capacitances of the blending system reaches 175 F/g at a specific current of 0.1 A/g in 30 wt% KOH aqueous electrolyte. Furthermore, the capacitance maintenance achieves 82.8% as the current density enlarged 55 times.

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Corresponding author

a)Address all correspondence to this author. e-mail: xxh@hnu.edu.cn

References

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1.Chen, T. and Dai, L.: Carbon nanomaterials for high-performance supercapacitors. Mater. Today 16, 272280 (2013).
2.Zhang, J., Yang, D., Li, W., Gao, Y., and Li, H.: Synthesis and electrochemical performance of porous carbons by carbonization of self-assembled polymer bricks. Electrochim. Acta 130, 699706 (2014).
3.Xiao, Z., Zhu, Y., Yi, H., and Chen, X.: A simple CaCO3-assisted template carbonization method for producing nitrogen-containing nanoporous carbon spheres and its electrochemical improvement by the nitridation of azodicarbonamide. Electrochim. Acta 155, 93102 (2015).
4.Ruiz-Rosas, R., Valero-Romero, M.J., Salinas-Torres, D., Rodríguez-Miraso, J., Cordero, T., Morallón, E., and Cazorla-Amorós, D.: Electrochemical performance of hierarchical porous carbon materials obtained from the infiltration of lignin into zeolite templates. ChemSusChem 7, 14581467 (2014).
5.Wu, X.L. and Xu, A.W.: Carbonaceous hydrogels and aerogels for supercapacitors. J. Mater. Chem. A 2, 48524864 (2014).
6.Ju, H., Song, W., and Fan, L.: Rational design of graphene/porous carbon aerogels for high-performance flexible all-solid-state supercapacitors. J. Mater. Chem. A 2, 1089510903 (2014).
7.Lee, Y., Kim, G., Bang, Y., Yi, J., Seo, J., and Song, I.K.: Activated carbon aerogel containing graphene as electrode material for supercapacitor. Mater. Res. Bull. 50, 240245 (2014).
8.Wang, G., Wang, H., Lu, X., Ling, Y., Yu, M., Zhai, T., Tong, Y., and Li, Y.: Solid-state supercapacitor based on activated carbon cloths exhibits excellent rate capability. Adv. Mater. 26, 26762682 (2014).
9.Kima, B., Yanga, K.S., and Ferraris, J.P.: Highly conductive, mesoporous carbon nanofiber web as electrode material for high-performance supercapacitors. Electrochim. Acta 75, 325331 (2012).
10.Kalra, C.V.: Fabrication of porous carbon nanofibers with adjustable pore sizes as electrodes for supercapacitors. J. Power Sources 235, 289296 (2013).
11.Heather, A.A., Kate, L., and Alicia, M.O.: Effect of Fe-contamination on rate of self-discharge in carbon-based aqueous electrochemical capacitors. J. Power Sources 187, 275283 (2009).
12.Suarez-Garcia, F., Vilaplana-Ortego, E., Kunowsky, M., Kimura, M., Oya, A., and Linares-Solano, A.: Activation of polymer blend carbon nanofibres by alkaline hydroxides and their hydrogen storage performances. Int. J. Hydrogen Energy 34, 91419150 (2009).
13.Jung, K.H. and Ferraris, J.P.: Preparation and electrochemical properties of carbon nanofibers derived from polybenzimidazole/polyimide precursor blends. Carbon 50, 53095315 (2012).
14.Niu, H., Zhang, J., Xie, Z., Wang, X., and Lin, T.: Preparation, structure and supercapacitance of bonded carbon nanofiber electrode materials. Carbon 49, 23802388 (2011).
15.Xia, Z., Li, W., Ding, J., Li, A., and Gan, W.: Effect of PS-b-PCL block copolymer on reaction-induced phase separation in epoxy/PEI blend. J. Polym. Sci., Part B: Polym. Phys. 52, 13951402 (2014).
16.Li, X. and Wei, B.: Supercapacitors based on nanostructured carbon. Nano Energy 2, 159173 (2013).
17.Xia, X., Liu, H., He, Y., Shi, L., Chen, H., and Yang, L.: Investigation of porous carbon fabricated by polymer blending of phenolic resin and suberic acid. J. Iran. Chem. Soc. 9, 545550 (2012).
18.Bueno, P.R., Mizzon, G., and Davis, J.J.: Capacitance spectroscopy: A versatile approach to resolving the redox density of states and kinetics in redox-active self-assembled monolayers. J. Phys. Chem. B 116, 88228829 (2012).
19.Goes, M.S., Rahman, H., Ryall, J., Davis, J.J., and Bueno, P.R.: A dielectric model of self-assembled monolayer interfaces by capacitive spectroscopy. Langmuir 28, 96899699 (2012).
20.Xing, W., Huang, C.C., Zhuo, S.P., Yuan, X., Wang, G.Q., Hulicova-Jurcakova, D., Yan, Z.F., and Lu, G.Q.: Hierarchical porous carbons with high performance for supercapacitor electrodes. Carbon 47, 17151722 (2009).
21.Choi, M.H., Byun, H.Y., and Chung, I.J.: The effect of chain length of flexible diacid on morphology and mechanical property of modified phenolic resin. Polymer 43, 44374444 (2002).
22.Ko, T.H., Kuo, W.S., and Chang, Y.H.: Microstructural changes of phenolic resin during pyrolysis. J. Appl. Polym. Sci. 81(5), 10841089 (2001).
23.Lee, K.T., Lytle, J.C., Ergang, N.S., Oh, S.M., and Stein, A.: Synthesis and rate performance of monolithic macroporous carbon electrodes for lithium-ion secondary batteries. Adv. Funct. Mater. 15, 547556 (2005).
24.Huang, W., Zhang, H., Huang, Y., Wang, W., and Wei, S.: Hierarchical porous carbon obtained from animal bone and evaluation in electric double-layer capacitors. Carbon 49, 838843 (2011).
25.Wang, Q., Liang, X.Y., and Qiao, W.M.: Preparation of polystyrene-based activated carbon spheres with high surface area and their adsorption to dibenzothiophene. Fuel Process. Technol. 90, 381387 (2009).
26.Xia, X.H., Shi, L., Liu, H.B., Yang, L., and He, Y.D.: A facile production of microporous carbon spheres and their electrochemical performance in EDLC. J. Phys. Chem. Solids 73, 385390 (2012).
27.Zhu, Y., Murali, S., Stoller, M.D., Ganesh, K.J., Cai, W., Ferreira, P.J., Pirkle, Adam, Wallace, R.M., Cychosz, K.A., Thommes, M., Su, D., Stach, E.A., and Ruoff, R.S.: Carbon-based supercapacitors produced by activation of graphene. Science 332, 15371541 (2011).
28.Jisha, M.R., Hwang, Y.J., and Shin, J.S.: Electrochemical characterization of supercapacitors based on carbons derived from coffee shells. Mater. Chem. Phys. 115, 3339 (2009).
29.Qu, D.: Studies of the activated carbons used in double-layer supercapacitors. J. Power Sources 109, 403411 (2002).
30.Bard, A.J., Abruna, H.D., Chidsey, C.E., Faulkner, L.R., Feldberg, S.W., and Itaya, K.: The electrode/electrolyte interface-A status report. J. Phys. Chem. 97, 71477173 (1993).
31.Sawangphruk, M., Srimuk, P., Chiochan, P., Krittayavathananon, A., Luanwuthi, S., and Limtrakul, J.: High-performance supercapacitor of manganese oxide/reduced graphene oxide nanocomposite coated on flexible carbon fiber paper. Carbon 60, 109116 (2013).
32.Chen, W., Rakhi, R.B., Hu, L., Xie, X., Cui, Y., and Alshareef, H.N.: High-performance nanostructured supercapacitors on a sponge. Nano Lett. 11, 51655172 (2011).
33.Song, H.K., Sung, J.H., and Jung, Y.H.: Electrochemical porosimetry. J. Electrochem. Soc. 151, E102E109 (2004).
34.Tooming, T., Thomberg, T., Kurig, H., Janes, A., and Lust, E.: High power density supercapacitors based on the carbon dioxide activated D-glucose derived carbon electrodes and 1-ethyl-3-methylimidazolium tetrafluoroborate ionic liquid. J. Power Sources 280, 667677 (2015).

Keywords

Supercapacitance properties of porous carbon from chemical blending of phenolic resin and aliphatic dicarboxylic acids

  • Xiaohong Xia (a1), Xuefang Zhang (a2), Shangqi Yi (a2), Hui Chen (a2) and Hongbo Liu (a1)...

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