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Substrate-independent stress–strain behavior of diamond-like carbon thin films by nanoindentation with a spherical tip

  • Naoki Fujisawa (a1), Teng Fei Zhang (a2), Oi Lun Li (a3) and Kwang Ho Kim (a4)

Abstract

A method for extracting the substrate-independent stress–strain curves of thin films was developed using spherical nanoindentation to investigate the yield behavior of diamond-like carbon (DLC) thin films with Young’s moduli of ∼73 GPa and ∼76 GPa. The resulting stress–strain curves showed that these films commence yielding at ∼13 GPa and ∼14 GPa, respectively. These yield strength values agree with the critical pressure necessary to initiate the transformation of sp 2-bonded carbon into significantly harder sp 3-bonded carbon, indicating that the yielding of the materials is associated with the sp 2-to-sp 3 phase transition. The ability of a DLC film to accommodate a progressively increasing contact stress with strain beyond the yield point while dissipating part of the accumulated strain energy, as evidenced in this work, implies a unique mechanism of the brittle material for passively mitigating contact deformation and fracture in tribological applications.

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Corresponding author

a) Address all correspondence to this author. e-mail: kwhokim@pusan.ac.kr

References

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