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Structure and strong ultraviolet emission characteristics of amorphous ZnO films grown by electrophoretic deposition

Published online by Cambridge University Press:  31 January 2011

Zhijian Wang
Affiliation:
Laboratory of Excited State Processes, Chinese Academy of Sciences, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130021, People's Republic of China
Haiming Zhang
Affiliation:
Laboratory of Excited State Processes, Chinese Academy of Sciences, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130021, People's Republic of China
Zhijun Wang
Affiliation:
Laboratory of Excited State Processes, Chinese Academy of Sciences, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130021, People's Republic of China
Ligong Zhang
Affiliation:
Laboratory of Excited State Processes, Chinese Academy of Sciences, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130021, People's Republic of China
Jinshan Yuan
Affiliation:
Laboratory of Excited State Processes, Chinese Academy of Sciences, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130021, People's Republic of China
Shenggang Yan
Affiliation:
School of Chemical Engineering, Dalian University of Technology Dalian, 116012 People's Republic of China
Chunyan Wang
Affiliation:
School of Chemical Engineering, Dalian University of Technology Dalian, 116012 People's Republic of China
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Abstract

Structure and ultraviolet emission characteristics of amorphous ZnO films grown on indium tin oxide coated glass substrates by electrophoretic deposition were investigated using Raman spectra and photoluminescence. The Raman spectrum shows a unique resonant multiphonon process within amorphous ZnO films. The photoluminescence spectrum of amorphous ZnO films shows a strong ultraviolet emission while the visible emission is nearly fully quenched. The transmission electron microscopy, x-ray diffraction, x-ray photoelectron spectrum, and infrared spectrum are used to detect the structure of amorphous ZnO powder. The complex water plays an important role in the photoluminescence intensity emission.

Type
Articles
Copyright
Copyright © Materials Research Society 2003

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