Hostname: page-component-76fb5796d-skm99 Total loading time: 0 Render date: 2024-04-27T04:51:21.519Z Has data issue: false hasContentIssue false

Silicide precipitation and silicon crystallization in nickel implanted amorphous silicon thin films

Published online by Cambridge University Press:  31 January 2011

R. C. Cammarata
Affiliation:
Department of Materials Science and Technology, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
C. V. Thompson
Affiliation:
Department of Materials Science and Technology, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
C. Hayzelden
Affiliation:
Division of Applied Sciences, Harvard University, Cambridge, Massachusetts 02138
K. N. Tu
Affiliation:
IBM Thomas J. Watson Research Center, Yorktown Heights, New York 10598
Get access

Abstract

The nucleation and growth kinetics of NiSi2 precipitation in amorphous silicon thin films ion implanted with nickel was investigated using scanning transmission electron microscopy. It was found that the nucleation rate could be approximately described by a delta function at time t = 0 when the films were annealed between 325 and 400 °C. The growth kinetics of the precipitates at these temperatures were described by rtn, where r was the average radius and n was about 1/3. This behavior is consistent with models for growth of three-dimensional particles in a two-dimensional diffusion field. It was also found that the implanted amorphous films displayed an enhanced rate of single crystal silicon formation, apparently catalyzed by migrating silicide precipitates.

Type
Articles
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Tu, K. N., in Advances in Electronic Materials, edited by Wessels, B. and Chin, G. V. (American Society for Metals, Metals Park, OH, 1986), p. 147.Google Scholar
2Murarka, S. P., Silicides for VLSI Applications (Academic Press, Orlando, FL, 1983).Google Scholar
3White, A. E., Short, K. T., Dynes, R. C., Garno, J. P., and Gibson, J. M., Appl. Phys. Lett. 50, 95 (1987).CrossRefGoogle Scholar
4Cammarata, R. C., Thompson, C. V., and Tu, K. N., Appl. Phys. Lett. 51, 1108 (1987).CrossRefGoogle Scholar
5Smithells Metals Reference Book, edited by Brandes, E. A. (Butterworth's, London, 1983), p. 618.Google Scholar
6Christian, J. W., The Theory of Transformations in Metals and Alloys (Pergamon Press, Oxford, 1981), p. 418.Google Scholar
7de Avillez, R. R., Clevenger, L. A., and Thompson, C. V. (to be published).Google Scholar
8Clevenger, L. A., Ph. D. Thesis, Massachusetts Institute of Technology, 1989 (unpublished).Google Scholar
9Charkraverty, B. K., J. Phys. Chem. Solids 28, 2401 (1967).CrossRefGoogle Scholar
10Charkraverty, B. K., J. Phys. Chem. Solids 28, 2413 (1967).CrossRefGoogle Scholar
11Thompson, C. V., Acta Metall. 36, 2929 (1988).CrossRefGoogle Scholar
12Nygren, E., Williams, J. S., Pogany, A., Elliman, R. G., Olson, G. L., and McCallum, J. C., in Beam-Solid Interactions and Transient Processes, edited by Thompson, M. O., Picraux, S. T., and Williams, J. S. (Mater. Res. Soc. Symp. Proc. 74, Pittsburgh, PA, 1987), p. 307.Google Scholar
13Nygren, E., Pogany, A. P., Short, K. T., Williams, J. S., Elliman, R. G., and Poate, J. M., Appl. Phys. Lett. 52, 439 (1988).CrossRefGoogle Scholar
14Nygren, E., McCallum, J. C., Thorton, R., Williams, J. S., and Olson, G. L., in Fundamentals of Beam-Solid Interactions and Transient Thermal Processing, edited by Aziz, M. J., Rehn, L. E., and Stritzker, B. (Mater. Res. Soc. Symp. Proc. 100, Pittsburgh, PA, 1988), p. 405.Google Scholar