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Reactive wetting of polycrystalline TiC by molten Zr55Cu30Al10Ni5 metallic glass alloy

Published online by Cambridge University Press:  31 January 2011

Ping Shen ,
Qiaoli Lin ,
Qichuan Jiang ,
Hidetoshi Fujii  and
Kiyoshi Nogi
Ping Shen*
Affiliation:
Key Laboratory of Automobile Materials of Ministry of Education, Department of Materials Science and Engineering, Jilin University, Changchun 130025, People's Republic of China
Qichuan Jiang
Affiliation:
Key Laboratory of Automobile Materials of Ministry of Education, Department of Materials Science and Engineering, Jilin University, Changchun 130025, People's Republic of China
Kiyoshi Nogi
Affiliation:
Joining and Welding Research Institute, Osaka University, Ibaraki, Osaka 567-0047, Japan
*
a) Address all correspondence to this author. e-mail: shenping@jlu.edu.cn
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Abstract

The isotherm wetting and spreading behaviors of polycrystalline TiC by molten Zr55Cu30Al10Ni5 alloy were investigated at 1133 to 1253 K in a vacuum by using a modified sessile drop method. The system displays good wettability with the initial and final stable contact angles of 44 to 50° and 10 to 14°, respectively, mildly depending on the temperature. The spreading kinetics follows well defined exponential functions and could be described by a molecular dynamic model. On the other hand, a ZrC reaction layer was formed at the interface. The wetting was primarily promoted by the Zr adsorption at the triple junction and then by the formation of the reaction layer.

Keywords

AdsorptionChemical reactionKinetics
Type
Articles
Information
Journal of Materials Research , Volume 24 , Issue 7 , July 2009 , pp. 2420 - 2427
Copyright
Copyright © Materials Research Society 2009

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