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Preparation of hydroxy double salts exchanged by organic compounds

Published online by Cambridge University Press:  31 January 2011

Hiroyuki Morioka ,
Hideyuki Tagaya ,
Masa Karasu ,
Jun-ichi Kadokawa  and
Koji Chiba
Hiroyuki Morioka
Affiliation:
Department of Materials Science and Engineering, Yamagata University, Jonan, Yonezawa, Yamagata 992, Japan
Hideyuki Tagaya
Affiliation:
Department of Materials Science and Engineering, Yamagata University, Jonan, Yonezawa, Yamagata 992, Japan
Masa Karasu
Affiliation:
Department of Materials Science and Engineering, Yamagata University, Jonan, Yonezawa, Yamagata 992, Japan
Jun-ichi Kadokawa
Affiliation:
Department of Materials Science and Engineering, Yamagata University, Jonan, Yonezawa, Yamagata 992, Japan
Koji Chiba
Affiliation:
Department of Materials Science and Engineering, Yamagata University, Jonan, Yonezawa, Yamagata 992, Japan
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Abstract

Hydroxy double salts (HDS's) comprise a class of layered materials that are similar to layered double hydroxides (LDH's) and show a comparable intracrystalline reactivity. Their anion exchange reactions occur with preincorporated anions in the hydroxide layer and with anions bound as gegenions of the positively charged layers, respectively. In this study, nitrate and acetate anions of HDS's were exchanged with anionic monoand di-carboxylic acids, and we confirmed that interlayer spacing of HDS's increased depending on the size of mono- and di-carboxylic acids. Moreover, we have prepared photofunctional materials by exchange reaction with azobenzene-p-carboxylic acid and 4–4′-azobenzenedicarboxylic acid.

Type
Articles
Information
Journal of Materials Research , Volume 13 , Issue 4 , April 1998 , pp. 848 - 851
Copyright
Copyright © Materials Research Society 1998

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References

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