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Preparation and characterization of CuInS2 nanorods and nanotubes from an elemental solvothermal reaction

Published online by Cambridge University Press:  31 January 2011

Yang Jiang ,
Yue Wu ,
Shengwen Yuan ,
Bo Xie ,
Shuyuan Zhang  and
Yitai Qian
Yang Jiang
Affiliation:
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, People's Republic of China 230026
Yue Wu
Affiliation:
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, People's Republic of China 230026
Shengwen Yuan
Affiliation:
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, People's Republic of China 230026
Bo Xie
Affiliation:
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, People's Republic of China 230026
Shuyuan Zhang
Affiliation:
Structure Research Laboratory, University of Science and Technology of China, Hefei, Anhui, People's Republic of China 230026
Yitai Qian*
Affiliation:
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, People's Republic of China 230026 and Structure Research Laboratory, University of Science and Technology of China, Hefei, Anhui, People's Republic of China 230026
*
a)Address all correspondence to this author.
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Abstract

A simple and convenient solvothermal reaction has been developed to produce CuInS2 nanorods and nanotubes from the elements in ethylenediamine at 280 °C. The products were characterized by x-ray diffraction, transmission electron microscopy, high-resolution transmission electron microscopy, scanning electron microscopy, and x-ray photoelectron spectroscopy. Analysis shows that the coordinating ability of ethylenediamine and the existence of liquid In may play important roles in the growth of one-dimension nanocrystallites and the electron-transfer reaction. In addition, spherical CuInS2 micrometer particles were obtained at 350 °C.

Type
Articles
Information
Journal of Materials Research , Volume 16 , Issue 10 , October 2001 , pp. 2805 - 2809
Copyright
Copyright © Materials Research Society 2001

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