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Optoelectronics properties of tin-doped indium oxide films fabricated by DC magnetron sputtering in pure argon with post-annealing in oxygen atmosphere

Published online by Cambridge University Press:  05 June 2015

Oleksandr Malik*
Affiliation:
Electronics Department, Instituto Nacional de Astrofísica, Óptica y Electrónica (INAOE), 72000 Puebla, Mexico
Francisco Javier De la Hidalga-Wade
Affiliation:
Electronics Department, Instituto Nacional de Astrofísica, Óptica y Electrónica (INAOE), 72000 Puebla, Mexico
*
a)Address all correspondence to this author. e-mail: amalik@inaoep.mx
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Abstract

We report on the study of the characteristics of indium–tin oxide (ITO) films prepared by well-controlled and reproducible DC magnetron sputtering in argon with consequent annealing in oxygen atmosphere. The structural, electrical, and optical properties of the ITO films were investigated. It was found that the films deposited in argon atmosphere with a commercial ITO target have low transparency and high resistivity. The lower value of the resistivity around 3 × 10−4 Ω cm and the higher value of the figure of merit of 7.4 × 10−3 Ω−1 for 200 nm thick films are obtained after postannealing the films at the optimal temperature T = 300 °C for 1 h. It was found experimentally that postannealing at different temperatures allows tuning effective work function of the ITO films in the range of 4.2–5.5 eV. The latter is an important issue for applications in optoelectronic devices. The fabrication method is useful for the fabrication of ITO films with high electro-optical parameters on flexible polyimide substrates.

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Articles
Copyright
Copyright © Materials Research Society 2015 

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References

REFERENCES

Haines, W.G. and Bube, R.H.: Effects of heat treatment on the optical and electrical properties of indium-tin oxide films. J. Appl. Phys. 49, 304 (1978).Google Scholar
Ginley, D., Hosono, H., and Paine, D.C. eds.: Handbook of Transparent Conductors (Springer, New York, 2011); 534p.Google Scholar
Malik, O., De la Hidalga-Wade, F.J., Zúñiga-Islas, C., and Abundis-Patiño, J.H.: UV-sensitive optical sensors based on ITO-GaP heterojunctions. Phys. Status Solidi C 7, 1176 (2010).CrossRefGoogle Scholar
Malik, O., De la Hidalga-Wade, F.J., Zúñiga-Islas, C., and Ruíz-T, G.: Efficient ITO–Si solar cells and power modules fabricated with a low temperature technology: Results and perspectives. J. Non-Cryst. Solids 354, 2472 (2008).Google Scholar
Malik, O., Martinez, A.I., and De la Hidalga-Wade, F.J.: The physical reason of intense electroluminescence in ITO–Si heterostructures. Thin Solid Films 515, 8615 (2007).Google Scholar
Malik, O. and De la Hidalga-Wade, F.J.: Spray deposited thin films of tin-doped indium oxide for optoelectronic applications. Adv. Mater. Res. 677, 173 (2013).Google Scholar
Enoki, H., Echigoya, J., and Suto, H.: The intermediate compound in the In2O3–SnO2 system. J. Mater. Sci. 26, 4110 (1991).Google Scholar
Heward, W.J. and Swenson, D.J.: Phase equilibrium in the pseudo-binary In2O3–SnO2 system. J. Mater. Sci. 42, 7135 (2007).Google Scholar
González, G.B., Mason, T.O., Okasinski, J.S., Buslaps, T., and Honkimäki, V.: Determination of stability of tin in indium oxide in situ and ex situ x-ray diffraction. J. Am. Ceram. Soc. 1, 1 (2011).Google Scholar
Falk, G.: Sintering of transparent conductive oxides: From oxide ceramic powders to advanced optoelectronic materials. In Sintering of Ceramics-new Emerging Techniques, Lakshmanan, A. ed.; InTech: Croatia, 2012; pp. 587610.Google Scholar
Minami, T., Sonohara, H., Kakumu, T., and Takata, S.: Physics of very thin ITO conducting films with high transparency prepared by DC magnetron sputtering. Thin Solid Films 270, 37 (1995).Google Scholar
Gheidari, M., Dabaghi, H.H., Kalhor, D., Iraj, M., Kazemzad, M., and Behafarid, F.: Post annealing effects on the properties of sputtered nano-crystallite indium tin oxide thin films on flexible polyimide substrate. Phys. Status Solidi C 10, 3338 (2008).Google Scholar
Gessert, T.A., Yoshida, Y., Fesenmaier, C.C., and Coutts, T.J.: Sputtered In2O3 and ITO films containing zirconium. J. Appl. Phys. 105, 083547 (2009).CrossRefGoogle Scholar
Gulen, M., Yildirim, G., Bal, S., Varilci, A., Belenli, I., and Oz, M.: Role of annealing temperature on microstructural and electro-optical properties of ITO films produced by sputtering. J. Mater. Sci.: Mater. Electron. 24, 467 (2013).Google Scholar
Cessert, T.A., Voshida, Y., Fesenmaier, C.C., and Coutts, T.J.: High-transparency sputtered In2O3 and ITO films containing zirconium. NREL/PR-520-42307. Presented at AVS 54th International Symposium & Exhibition, October, Seattle, Washington, USA, 2007; p. 14.Google Scholar
Udawatte, C.P. and Yanagisawa, K.: Hydrothermal preparation of highly sinterable tin doped indium oxide powders: The effect of the processing parameters. In Proceedings of the 7th International Conference on Ceramic Processing Science, Inuyama, Japan, 2000; p. 46.Google Scholar
Nisha, M., Anusha, S., Antony, A., Manoj, R., and Jayaraj, M.K.: Effect of substrate temperature on the growth of ITO films. Appl. Surf. Sci. 252, 1430 (2005).Google Scholar
Nisha, N.: Growth and characterisation of radio frequency magnetron sputtered indium tin oxide thin films. PhD Thesis, Cochin University, Kerala, India, 2006; p. 116.Google Scholar
Haacke, G.: New figure of merit for transparent conductors. J. Appl. Phys. 47, 4086 (1976).Google Scholar
Fallah, H.R., Ghasemi, M., Hassanzadeh, A., and Steki, H.: The effect of annealing on structural, electrical and optical properties of nanostructured ITO films prepared by e-beam evaporation. MRS Bull. 42(3), 487 (2007).Google Scholar
Guillén, C. and Herrero, J.: Influence of oxygen in the deposition and annealing atmosphere on the characteristics of ITO thin films prepared by sputtering at room temperature. Vacuum 80, 615 (2006).Google Scholar
Viespe, C., Nicolae, I., Sima, C., Grigoriu, C., and Medianu, R.: ITO thin films deposited by advanced pulsed laser deposition. Thin Solid Films 515, 8771 (2007).CrossRefGoogle Scholar
Aouaj, M.A., Diaz, R., Belayachi, A., Rueda, F., and Abd-Lefdil, M.: Comparative study of ITO and FTO thin films grown by spray pyrolysis. MRS Bull. 44(7), 1458 (2009).CrossRefGoogle Scholar
Alam, M.J. and Cameron, D.C.: Investigation of annealing effects on sol–gel deposited indium tin oxide thin films in different atmospheres. Thin Solid Films 420421, 76 (2002).Google Scholar
Shewchun, J., Dubow, J., Wilmsen, C.W., Singh, R., Burk, D., and Wager, J.F.: The operation of the semiconductor-insulator-semiconductor solar cell: Experiment. J. Appl. Phys. 50, 2832 (1979).Google Scholar
Bakasybramanian, N. and Subrahmanyan, A.: Studies on evaporated indium tin oxide (ITO)/silicon junctions and an estimation of ITO work function. J. Electrochem. Soc. 138, 322 (1991).Google Scholar
Parker, I.D.: Carrier tunneling and device characteristics in polymer light-emitting diodes. J. Appl. Phys. 75, 1656 (1994).Google Scholar
Park, Y., Choong, V., and Gao, Y.: Work function of indium tin oxide transparent conductor measured by photoelectron spectroscopy. Appl. Phys. Lett. 68, 2699 (1996).Google Scholar
Schlaf, R., Murata, H., and Kafafi, Z.H.: Work function measurements on indium tin oxide films. J. Electron Spectrosc. Relat. Phenom. 120, 149 (2001).CrossRefGoogle Scholar
Ishida, T., Kobayashi, H., and Nakato, Y.: Structures and properties of electron-beam-evaporated indium tin oxide films as studied by X-ray photoelectron spectroscopy and work-function measurements. J. Appl. Phys. 73(9), 4344 (1993).Google Scholar
Nicollian, E.H. and Brews, J.R.: MOS (Metal Oxide Semiconductor) Physics and Technology (Willey, New York, 2003); p. 468.Google Scholar
Sato, Y., Tokumaru, R., Nishimura, E., Song, P., and Shigesato, Y.: Structural, electrical, and optical properties conductive In2O3–SnO2 films. J. Vac. Sci. Technol. A 34(4), 1167 (2005).CrossRefGoogle Scholar
Schmid, W.: Consumption measurements on SnO2 sensors in low and normal oxygen concentration. PhD Thesis, Eberhard-Karls-Universität, Tübingen, Baden-Württemberg, Germany, 2004; p.17.Google Scholar
Low, B., Zhu, F., Zhang, K., and Chua, S.: Improvement of hole injection in phenyl-substituted electroluminescent devices by reduction of oxygen deficiency near the indium tin oxide surface. Appl. Phys. Lett. 80, 4659 (2002).Google Scholar
Song, W., So, S.K., Wang, D., Qiu, Y., and Cao, L.: Angle dependent X-ray photoemission study on UV-ozone treatments of indium tin oxide. Appl. Surf. Sci. 177, 158 (2001).CrossRefGoogle Scholar
Helander, M.G., Wang, Z.B., Qiu, J., Greiner, M.T., Puzzo, D.P., Liu, Z.W., and Lu, Z.H.: Chlorinated indium tin oxide electrodes with high work function for organic device compatibility. Science 332, 944 (2011).Google Scholar
Yang, Q.Q., Zhao, S-L., Xu, Z., Zhang, F.J., Yan, G., Kong, C., Fan, X., Zhang, Y-F., and Xu, X-R.: Enhanced performance in organic photovoltaic devices with a KMnO4 solution treated indium tin oxide anode modification. Chin. Phys. B 21, 128402 (2012).Google Scholar