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Nanostructured resorcinol-formaldehyde ink for 3D direct writing

Published online by Cambridge University Press:  11 May 2018

Yingting Ge ,
Ting Zhang ,
Bin Zhou ,
Hongqiang Wang Open the ORCID record for Hongqiang Wang [Opens in a new window] ,
Zhihua Zhang ,
Jun Shen  and
Ai Du
Yingting Ge
Affiliation:
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China
Ting Zhang
Affiliation:
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China
Bin Zhou*
Affiliation:
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China
Hongqiang Wang
Affiliation:
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China
Zhihua Zhang
Affiliation:
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China
Jun Shen
Affiliation:
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China
Ai Du*
Affiliation:
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China
*
a)Address all correspondence to these authors. e-mail: zhoubin863@tongji.edu.cn
b)e-mail: duai@tongji.edu.cn
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Abstract

We designed a resorcinol-formaldehyde (RF) sol–gel ink for direct ink writing of the microlattices. To improve the formability, the fresh microlattices were strengthened by surface catalysis with HCl atmosphere. After supercritical drying and carbonization, the sample’s specific surface area was 631 m2/g and the average pore size was 3.81 nm. Both RF aerogel and carbonized RF aerogel samples had millimeter-scale pore, micron-scale pore, and nanoscale skeleton. The pore and skeleton could provide high surface area and diffusion channels, which were beneficial to the adsorption performances. The carbonized RF aerogel sample fully adsorbed Dulbecco’s modified eagle medium in 250 min, which exhibited a good capacity of quick adsorption and indicated the potential application for cell supports.

Keywords

3D printingdirect writingsol–gelself-supportingadsorption
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 14: Focus Issue: 3D Printing of Biomaterials , 27 July 2018 , pp. 2052 - 2061
Copyright
Copyright © Materials Research Society 2018 

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