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The microstructure and creep deformation of hot-pressed Si3N4 with different amounts of sintering additives

Published online by Cambridge University Press:  31 January 2011

Sang-Young Yoon
Affiliation:
Research Laboratory of Engineering Materials, Tokyo Institute of Technology, Yokohama, 226, Japan
Takashi Akatsu
Affiliation:
Research Laboratory of Engineering Materials, Tokyo Institute of Technology, Yokohama, 226, Japan
Eiichi Yasuda
Affiliation:
Research Laboratory of Engineering Materials, Tokyo Institute of Technology, Yokohama, 226, Japan
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Abstract

Compressive creep deformation of hot-pressed silicon nitride with different amounts of grain boundary glassy phase was investigated at 1300–1400 °C under 30–100 MPa. The stress exponent of the creep rate was determined to be nearly unity. The apparent activation energy of silicon nitride with a larger amount of glassy phase was measured to be about 700 kJ/mole, and that with a smaller amount of glassy phase was found to be 400 kJ/mole. In addition, the microstructural observation found that no cavity appeared and grain boundary glass was recrystallized during creep test. Thus, the rate-limiting steps in solution/precipitation creep mechanism change from the solution-reprecipitation of Si3N4 grains to the diffusion through the grain boundary with increasing the amount of glassy phase.

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Articles
Copyright
Copyright © Materials Research Society 1996

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References

REFERENCES

1.Ziegler, G., Henrich, J., and Wötting, G., J. Mater. Sci. 22, 3041 (1987).CrossRefGoogle Scholar
2.Mazdiyasni, K. S. and Cooke, C. M., J. Am. Ceram. Soc. 57, 536 (1974).CrossRefGoogle Scholar
3.Voandrager, B. L. and Pharr, G. M., Acta Metall. 37, 1057 (1989).CrossRefGoogle Scholar
4.Raj, R. and Chung, C. K., Acta Metall. 29, 159 (1981).CrossRefGoogle Scholar
5.Pharr, G. M. and Ashby, M. F., Acta Metall. 31, 129 (1983).CrossRefGoogle Scholar
6.Wakai, F., Acta Metall. 42, 1163 (1994).CrossRefGoogle Scholar
7.Lange, F. F., Davis, B. I., and Clarke, D. R., J. Mater. Sci. 15, 601 (1980).CrossRefGoogle Scholar
8.Marion, J. E., Evans, A. G., Drory, M. D., and Clarke, D. R., Acta Metall. 31, 1445 (1983).CrossRefGoogle Scholar
9.Clarke, D. R., J. Mater. Sci. 20, 1321 (1985).CrossRefGoogle Scholar
10.Chadwick, M. M., Jupp, R. S., and Wilkinson, D. S., J. Am. Ceram. Soc. 76, 385 (1993).CrossRefGoogle Scholar
11.Todd, J. A. and Xu, Z-Y., J. Mater. Sci. 24, 4443 (1989).CrossRefGoogle Scholar
12.Wiederhorn, S. M., Hockey, B. J., Cranmer, D. C., and Yeckley, R., J. Mater. Sci. 28, 445 (1993).CrossRefGoogle Scholar
13.Menon, M.N., Fang, H.T., Wu, D.C., Jenkins, M. G., and Ferber, M.K., J. Am. Ceram. Soc. 77, 1228 (1994).CrossRefGoogle Scholar
14.Chakraborty, D. and Mukhopadhyay, A. K., Ceram. Int. 15, 237 (1989).CrossRefGoogle Scholar
15.Hockey, B. J., Wiederhorn, S. M., Liu, W., Baldoni, J. G., and Buljan, S-T., J. Mater. Sci. 26, 3931 (1991).CrossRefGoogle Scholar
16.Suda, A., Tajima, I., Ishii, M., Tada, M., Ukyo, Y., and Wada, S., J. Ceram. Soc. Jpn. 101, 217 (1993).CrossRefGoogle Scholar
17.Ramesh, K., Yasuda, E., and Kimura, S., J. Mater. Sci. 21, 3147 (1986).CrossRefGoogle Scholar
18.Ferber, M. K. and Jenkins, M. G., J. Am. Ceram. Soc. 75, 2453 (1992).CrossRefGoogle Scholar
19.Dryden, J. R., Kucerovshy, D., Wilkinson, D. S., and Watt, D. F., Acta Metall. 37, 2007 (1989).CrossRefGoogle Scholar
20.Levin, E. M., Robbins, C. R., and MacMurdie, H. F., Phase Diagrams for Ceramists, edited by Reser, M. K. (The American Ceramic Society, Westerville, OH, 1969), Fig. 2586.Google Scholar
21.Din, S. U. and Nicholson, P. S., J. Am. Ceram. Soc. 58, 500 (1975).CrossRefGoogle Scholar
22.Bowen, L. J., Weston, R. J., Carruthers, T. G., and Brook, R. J., J. Mater. Sci. 13, 341 (1978).CrossRefGoogle Scholar
23.Wiederhorn, S. M., Hockey, B. J., Cranmer, D. C., and Yeckley, R., J. Mater. Sci. 28, 445 (1993).CrossRefGoogle Scholar
24.Rouxel, T., Besson, J-L., Gault, C., Goursat, P., Leigh, M., and Hamshire, D., J. Mater. Sci. Lett. 8, 1158 (1989).CrossRefGoogle Scholar