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Mechanochemical synthesis of ReB2 powder

  • Nina Orlovskaya (a1), Zhilin Xie (a1), Mikhail Klimov (a2), Helge Heinrich (a3), David Restrepo (a4), Richard Blair (a4) and Challapalli Suryanarayana (a5)...

Abstract

ReB2 was recently reported to exhibit high hardness and low compressibility, which both are strong functions of its stoichiometry, namely Re to B ratio. Most of the techniques used for ReB2 synthesis reported 1:2.5 Re to B ratio because of the loss of the B during high temperature synthesis. However, as a result of B excess, the amorphous boron, located along the grain boundaries of polycrystalline ReB2, would degrade the ReB2 properties. Therefore, techniques which could allow synthesizing the stoichiometric ReB2 preferably at room temperature are in high demand. Here, we report synthesis of ReB2 powders using mechanochemical route by milling elemental crystalline Re and amorphous B powders in the SPEX 8000 high-energy ball mill for 80 h. The formation of boron and perrhenic acids are also reported after ReB2 powder was exposed to the moist air environment for a 12-month period of time.

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Corresponding author

a)Address all correspondence to this author. e-mail: norlovsk@mail.ucf.edu

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1.Chung, H.Y., Weinberger, M.B., Levine, J.B., Cumberland, R.W., Kavner, A., Yang, J.M., Tolbert, S.H., and Kaner, R.B.: Synthesis of ultra-incompressible superhard rhenium diboride at ambient pressure. Science 316, 436 (2007).
2.Latini, A., Rau, J.V., Ferro, D., Teghil, R., Albertini, V.R., and Barinov, S.M.: Superhard rhenium diboride films: Preparation and characterization. Chem. Mater. 20, 4507 (2008).
3.Levine, J.B., Nguyen, S.L., Rasool, H.I., Wright, J.A., Brown, S.E., and Kaner, R.B.: Preparation and properties of metallic, superhard rhenium diboride crystals. J. Am. Chem. Soc. 130, 16953 (2008).
4.Zhou, W., Wu, H., and Yildirim, T.: Electronic, dynamical, and thermal properties of ultra-incompressible superhard rhenium diboride: A combined first-principles and neutron scattering study. Phys. Rev. B 76, 184113 (2007).
5.Aydin, S. and Simsek, M.: First-principles calculations of MnB2, TcB2, and ReB2 within the ReB2-type structure. Phys. Rev. B 80, 134107 (2009).
6.Liang, Y. and Zhang, B.: Mechanical and electronic properties of superhard ReB2. Phys. Rev. B 76, 132101 (2007).
7.Chen, X.Q., Fu, C.L., Krčmar, M., and Painter, G.S.: Electronic and structural origin of ultraincompressibility of 5d transition-metal diborides MB2 (M=W, Re, Os). Phys. Rev. Lett. 100, 196403 (2008).
8.Pellicer-Porres, J., Segural, A., Munoz, A., Polian, A., and Congeduti, A.: Bond length compressibility in hard ReB2 investigated by x-ray absorption under high pressure. J. Phys. Condens. Matter 22, 045701 (2010).
9.Koehler, M.R., Keppens, V., Sales, B.C., Jin, R., and Mandrus, D.: Elastic moduli of superhard rhenium diboride. J. Phys. D: Appl. Phys. 42, 095414 (2009).
10.Zhang, R.F., Veprek, S., and Argon, A.S.: Mechanical and electronic properties of hard rhenium diboride of low elastic compressibility studied by first-principles calculation. Appl. Phys. Lett. 91, 201914 (2007).
11.Dubrovinskaia, N., Dubrovinsky, L., and Solozhenko, V.L.: Comment on “Synthesis of ultra-incompressible superhard rhenium diboride at ambient pressure”. Science 318, 1550 (2007).
12.Otani, S., Korsukova, M.M., and Aizawa, T.: High-temperature hardness of ReB2 single crystals. J. Alloy. Comp. 477, L28 (2009).
13.Qin, J., He, D., Wang, J., Fang, L., Lei, L., Li, Y., Hu, J., Kou, Z., and Bi, Y.: Is rhenium diboride a superhard material? Adv. Mater. 20, 4780 (2008).
14.Levine, J.B., Betts, J.B., Garrett, J.D., Guo, S.Q., Eng, J.T., Miglion, A., and Kaner, R.B.: Full elastic tensor of a crystal of the superhard compound ReB2. Acta Mater. 58, 1530 (2010).
15.McAlister, A.J.: Binary Alloy Phase Diagrams, edited by Massalski, T.B., Okamoto, H., Subramanian, P.R. and Kacprzak, L. (ASM International, Materials Park, OH, 1990), p. 136.
16.Ivanov, B.L., Wellons, M.S., and Lukehart, C.M.: Confined-plume chemical deposition: Rapid synthesis of crystalline coatings of known hard or superhard materials on inorganic or organic supports by resonant IR decomposition of molecular precursors. J. Am. Chem. Soc. 131, 11744 (2009).
17.Lyashchenko, A.B., Paderno, V.N., Filippov, V.B., and Borshchevskii, D.F.: Preparation and some properties of rhenium diboride monocrystals. Sverkhtverd. Mater. 28, 72 (2006).
18.LaPlaca, S.J. and Post, B.: The crystal structure of rhenium diboride. Acta Crystallogr. 15, 97 (1962).
19.Frotscher, M., Holzel, M., and Albert, B.Z.: Crystal structures of the metal diborides ReB2, RuB2, and OsB2 from neutron powder diffraction. Z. Anorg. Allg. Chem. 636, 1783 (2010).
20.Locci, A.M., Licheri, R., Orru, R., and Cao, G.: Reactive spark plasma sintering of rhenium diboride. Ceram. Int. 35, 397 (2009).
21.Suryanarayana, C.: Mechanical alloying and milling. Prog. Mater. Sci. 46, 1 (2001).
22.Suryanarayana, C.: Mechanical Alloying and Milling (Marcel Dekker, Inc., New York, NY, 2004), p. 466.
23.Boldyrev, V.V. and Tkacova, K.: Mechanochemistry of solids: Past, present, and prospects. J. Mater. Synth. Process. 8, 121 (2000).
24.Takacs, L.: Self-sustaining reactions induced by ball milling. Prog. Mater. Sci. 47, 355 (2002).
25.Haessler, W., Herrmann, M., Birajdar, B., Rodig, C., Schubert, M., Holzapfel, B., Eibl, O., and Schultz, L.: Superconducting MgB2 tapes prepared using mechanically alloyed nanocrystalline precursor powder. IEEE Trans. Appl. Supercond. 17, 2919 (2007).
26.Hwang, Y. and Lee, J.K.: Preparation of TiB2 powders by mechanical alloying. Mater. Lett. 54, 1 (2002).
27.Millet, P. and Hwang, T.: Preparation of TiB2 and ZrB2: Influence of a mechanochemical treatment on the borothermic reduction of titania and zirconia. J. Mater. Sci. 31, 351 (1996).
28.Radev, D.D. and Klisurski, D.: Properties of TiB2 powders obtained in a mechanochemical way. J. Alloy. Comp. 206, 39 (1994).
29.Setoudeh, N. and Welham, N.J.: Formation of zirconium diboride (ZrB2) by room temperature mechanochemical reaction between ZrO2, B2O3 and Mg. J. Alloy. Comp. 420, 225 (2006).
30.Varin, R.A. and Chiu, C.: Synthesis of nanocrystalline magnesium diboride (MgB2) metallic superconductor by mechano-chemical reaction and post-annealing. J. Alloy. Comp. 407, 268 (2006).
31.Boyd, G.E., Cobble, J.W., and Smith, W.T.: Thermodynamic properties of technetium and rhenium compounds. III. Heats of formation of rhenium heptoxide and trioxide, and a revised potential diagram for rhenium. J. Am. Chem. Soc. 75, 5783 (1953).
32.Meschel, S.V. and Kleppa, O.J.: Standard enthalpies of formation of NbB2, MoB, and ReB2 by high-temperature direct synthesis calorimetry. Metall. Mater. Trans. A 24, 947 (1993).

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Mechanochemical synthesis of ReB2 powder

  • Nina Orlovskaya (a1), Zhilin Xie (a1), Mikhail Klimov (a2), Helge Heinrich (a3), David Restrepo (a4), Richard Blair (a4) and Challapalli Suryanarayana (a5)...

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