Hostname: page-component-848d4c4894-xm8r8 Total loading time: 0 Render date: 2024-06-30T20:04:48.362Z Has data issue: false hasContentIssue false
  • English
  • Français

Mechanisms for species-selective oriented crystal growth at organic templates

Published online by Cambridge University Press:  31 January 2011

Sumit Kewalramani ,
Kyungil Kim ,
Guennadi Evmenenko ,
Paul Zschack ,
Evguenia Karapetrova ,
Jianming Bai  and
Pulak Dutta
Sumit Kewalramani
Affiliation:
Department of Physics and Astronomy, Northwestern University, Evanston, Illinois 60208
Kyungil Kim
Affiliation:
Department of Physics and Astronomy, Northwestern University, Evanston, Illinois 60208
Guennadi Evmenenko
Affiliation:
Department of Physics and Astronomy, Northwestern University, Evanston, Illinois 60208
Paul Zschack
Affiliation:
Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439
Evguenia Karapetrova
Affiliation:
Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439
Jianming Bai
Affiliation:
Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831
Pulak Dutta*
Affiliation:
Department of Physics and Astronomy, Northwestern University, Evanston, Illinois 60208
*
a)Address all correspondence to this author. e-mail: pdutta@northwestern.edu
Get access

Abstract

Langmuir monolayers floating on supersaturated aqueous subphases can act as templates for the growth of oriented inorganic films—a “bioinspired” nucleation process. We have performed in situ grazing incidence x-ray diffraction studies of the selective nucleation of BaClF and BaF2 under fatty acid monolayers. The arrangement of the fatty acid headgroups, the monolayer charge, and ion-specific effects all play important roles in selecting the inorganic species. When the monolayer is in a neutral state, both BaClF and BaF2 nucleate at the interface and are well aligned, but when the monolayer headgroup is deprotonated, only oriented BaF2 grows at the interface. We also observe an enhanced alignment of BaF2 crystals during growth from highly supersaturated solutions, presumably due to reorganization of preformed crystals at the organic template. These results show that a delicate interplay between multiple factors governs the oriented growth of inorganic films at organic templates.

Keywords

Biomimetic (assembly)Crystal growthX-ray diffraction (XRD)
Type
Articles
Information
Journal of Materials Research , Volume 22 , Issue 10 , October 2007 , pp. 2785 - 2790
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Mann, S.: Biomineralization Principles and Concepts in Bioinorganic Materials Chemistry Oxford University Press Oxford 2001CrossRefGoogle Scholar
2Rapaport, H., Kuzmenko, I., Berfeld, M., Kjaer, K., Als-Nielsen, J., Popovitz-Biro, R., Weisbuch, I., Lahav, M.Leiserovitz, L.: From nucleation to engineering of crystalline architectures at air—liquid interfaces. J. Phys. Chem. B 104, 1399 2000CrossRefGoogle Scholar
3Lu, L., Cui, H., Li, W., Zhang, H.Xi, S.: Study of the mechanism for controlled crystallization of BaF2 under two kinds of monolayers. J. Mater. Res. 16, 2415 2001Google Scholar
4Lu, L., Cui, H., Li, W., Zhang, H.Xi, S.: Selective crystallization of BaF2 under a compressed Langmuir monolayer of behenic acid. Chem. Mater. 13, 325 2001CrossRefGoogle Scholar
5Kmetko, J., Yu, C-J., Evmenenko, G., Kewalramani, S.Dutta, P.: Evidence of registry at the interface during inorganic nucleation at an organic template. Phys. Rev. Lett. 89, 186102 2002CrossRefGoogle ScholarPubMed
6Kewalramani, S., Dommett, G., Kim, K., Evmenenko, G., Mo, H., Stripe, B.Dutta, P.: Aggregation-governed oriented growth of inorganic crystals at an organic template. J. Chem. Phys. 125, 224713 2006CrossRefGoogle ScholarPubMed
7Dimasi, E., Olszta, M.J., Patel, V.M.Gower, L.B.: When is template directed mineralization really template directed? Cryst. Eng. Commun. 5, 346 2003CrossRefGoogle Scholar
8Kmetko, J., Yu, C-J., Evmenenko, G., Kewalramani, S.Dutta, P.: Organic-template-directed nucleation of strontium fluoride and barium fluoride: Epitaxy and strain. Phys. Rev. B 68, 085415 2003CrossRefGoogle Scholar
9Yuste, M., Rahmani, M., Jumeau, D., Taurel, L.Badoz, J.: ESR study of U2 centers in BaClF. J. Phys. C: Solid State Phys. 6, 3167 1973CrossRefGoogle Scholar
10Barton, S., Thomas, B., Flom, E., Rice, S., Lin, B., Peng, J., Ketterson, J.Dutta, P.: X-ray diffraction study of a Langmuir monolayer of C21H43OH. J. Chem. Phys. 89, 2257 1988CrossRefGoogle Scholar
11Kaganer, V.M., Möhwald, H.Dutta, P.: Structure and phase transitions in Langmuir monolayers. Rev. Mod. Phys. 71, 779 1999CrossRefGoogle Scholar
12Peters, R.A.: Interfacial tension and hydrogen-ion concentration. Proc. R. Soc. London Ser. A 133, 140 1931Google Scholar
13Jungwirth, P.Tobias, D.J.: Specific ion effects at the air/water interface. Chem. Rev. 106, 1259 2006CrossRefGoogle ScholarPubMed
14Aroti, A., Leontidis, E., Maltseva, E.Brezesinski, G.: Effects of Hofmeister anions on DPPC Langmuir monolayers at the air-water interface. J. Phys. Chem. B 108, 15238 2004CrossRefGoogle Scholar
15Weast, R.C.: CRC Handbook of Chemistry and Physics, 58th ed., CRC Press, Boca Raton, FL, 1977–1978 B92Google Scholar
16Wulfsberg, G.: Principles of Descriptive Inorganic Chemistry University Science Books Herndon, VA 1991Google Scholar