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The mechanism of hydrolytic polymerization of zirconyl solutions

Published online by Cambridge University Press:  31 January 2011

Abraham Clearfield
Abraham Clearfield
Affiliation:
Department of Chemistry, Texas A&M University, College Station, Texas 77843
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Abstract

Solutions of zirconyl salts can be treated in a variety of ways to precipitate hydrous amorphous ZrO2. The phases formed upon heating these precipitates are described and rationalized based upon a theory of hydrolytic polymerization which had been proposed at an earlier stage.

Type
Articles
Information
Journal of Materials Research , Volume 5 , Issue 1 , January 1990 , pp. 161 - 162
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

1 Davis, B. H., J. Am. Ceram. Soc. 67, C-168 (1984).Google Scholar
2 Srinivasan, R., DeAngelis, R. J., and Davis, B. H., J. Mater. Res. 1, 583 (1986).CrossRefGoogle Scholar
3 Tau, L-M., Srinivasan, R., DeAngelis, R. J., Pinder, T., and Davis, B. H., J. Mater. Res. 3, 561 (1988).CrossRefGoogle Scholar
4 Srinivasan, R., Harris, M. B., Simpson, S. F., DeAngelis, R. J., and Davis, B. H., J. Mater. Res. 3, 787 (1988)CrossRefGoogle Scholar
5 Clearfield, A., Inorg. Chem. 3, 146 (1964).CrossRefGoogle Scholar
6 Clearfield, A., Rev. Pure Appl. Chem. 14, 91 (1964).Google Scholar
7 Clearfield, A. and Vaughan, P. A., Acta Crystallogr. 9, 555 (1956).CrossRefGoogle Scholar
8 Muha, G. M. and Vaughan, P. A., J. Chem. Phys. 33, 194 (1960).CrossRefGoogle Scholar
9 Johnson, J. S. and Kraus, K. A., J. Am. Chem. Soc. 78, 3937 (1956).CrossRefGoogle Scholar
10 Clearfield, A., Nancollas, G. H., and Blessing, R. H., Ion Exchange and Solvent Extraction, edited by Marinsky, J. A. and Marcus, Y. (Marcel Dekker, Inc., New York, 1973), Vol. 5.Google Scholar
11 Fryer, J. R., Hutchenson, J. L., and Paterson, R., J. Colloid Interface Sci. 34, 238 (1970).CrossRefGoogle Scholar
12 Sheka, I.A. and Peuzner, Ts. V., Russ. J. Inorg. Chem. 5, 1119 (1960).Google Scholar
13 Bleier, A. and Cannon, R. M., in Better Ceramics Through Chemistry, II. edited by Brinker, C. J., Clark, D. E., and Ulrich, D. R. (Mater. Res. Soc, Pittsburgh, PA, 1986), p. 71.Google Scholar
14 Blesa, M. A., Maroto, A. J. G., Passagio, S. I., Figliolia, N. E., and Rigotti, G., J. Mater. Sci. 20, 4601 (1985).CrossRefGoogle Scholar