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Mechanical and microstructural characterization of magnesium single crystals

Published online by Cambridge University Press:  24 November 2017

Pravahan Salunke
Affiliation:
Department of Mechanical and Materials Engineering, University of Cincinnati, Cincinnati, Ohio 45221, USA
Vibhor Chaswal
Affiliation:
Department of Mechanical and Materials Engineering, University of Cincinnati, Cincinnati, Ohio 45221, USA
Guangqi Zhang
Affiliation:
Department of Mechanical and Materials Engineering, University of Cincinnati, Cincinnati, Ohio 45221, USA
Svitlana Fialkova
Affiliation:
Center for Advanced Materials and Smart Structures, North Carolina A&T State University, Fort Interdisciplinary Research Center, Greensboro, North Carolina 27411, USA
Sergei Yarmolenko
Affiliation:
Center for Advanced Materials and Smart Structures, North Carolina A&T State University, Fort Interdisciplinary Research Center, Greensboro, North Carolina 27411, USA
Vesselin Shanov*
Affiliation:
Department of Mechanical and Materials Engineering, University of Cincinnati, Cincinnati, Ohio 45221, USA; and Department of Biomedical, Chemical and Environmental Engineering, University of Cincinnati, 601 Engineering Research Center, Cincinnati, Ohio 45221, USA
*
a) Address all correspondence to this author. e-mail: shanovvn@ucmail.uc.edu
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Abstract

This study describes results from mechanical tests conducted on magnesium single crystals in comparison with polycrystalline magnesium. It was found by impact testing that the magnesium single crystal is highly ductile due to energy absorption by twinning and slip, while the polycrystalline samples fracture easily upon impact. Compressive testing along two orthogonal directions at low plastic strains was also performed. The microstructure studies by electron backscatter diffraction and XRD pole figure analysis revealed profuse ( $10\overline12$ ) twinning when compression is done along the growth plane (72 16 $\overline {88}$ 62). The twinning and interaction between different twin modes resulted in incipient recrystallization at strains as low as 8% at room temperature. Compression along the nearly orthogonal plane (2 2 $\bar{4}$ 15) was marked by a much lower degree of both twinning and recrystallization. The variation in microstructural response with the orientation of loading allows for a wide range for tailoring mechanical properties of pure magnesium single crystals without any need of alloying.

Type
Articles
Copyright
Copyright © Materials Research Society 2017 

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Footnotes

Contributing Editor: Jürgen Eckert

References

REFERENCES

Witte, F., Hort, N., Vogt, C., Cohen, S., Kainer, K.U., Willumeit, R., and Feyerabend, F.: Degradable biomaterials based on magnesium corrosion. Curr. Opin. Solid State Mater. Sci. 12(5), 63 (2008).CrossRefGoogle Scholar
Witte, F.: The history of biodegradable magnesium implants: A review. Acta Biomater. 6(5), 1680 (2010).Google Scholar
Kirkland, N.T.: Magnesium biomaterials: Past, present and future. Corros. Eng., Sci. Technol. 47(5), 322 (2012).CrossRefGoogle Scholar
Witte, F., Eliezer, A., and Cohen, S.: The history, challenges and the future of biodegradable metal implants. Adv. Mater. Res. 95, 3 (2010).CrossRefGoogle Scholar
Pollock, T.M.: Weight loss with magnesium alloys. Science 328(5981), 986 (2010).Google Scholar
Reed-Hill, R.E. and Robertson, W.D.: The crystallographic characteristics of fracture in magnesium single crystals. Acta Metall. 5(12), 728 (1957).CrossRefGoogle Scholar
Yoshinaga, H. and Horiuchi, R.: Deformation mechanisms in magnesium single crystals compressed in direction parallel to hexagonal axis. Trans. Jpn. Inst. Met. 4(1), 1 (1963).Google Scholar
Wonsiewicz, B.C. and Backofen, W.A.: Plasticity of magnesium crystals. Trans. Metall. Soc. AIME 239, 1422 (1967).Google Scholar
Kelley, E.W. and Hosford, W.F.: Plane strain compression of magnesium and magnesium alloy crystals. Trans. Metall. Soc. AIME 242, 5 (1968).Google Scholar
Kitahara, H., Maruno, F., Tsushida, M., and Ando, S.: Deformation behavior of Mg single crystals during a single ECAP pass at room temperature. Mater. Sci. Eng., A 590, 274 (2014).Google Scholar
Li, Q.Z.: Fatigue behavior and microstructure of 0001 and 1014 magnesium single crystals under compression-compression cyclic loading. Mater. Sci. Eng., A 556, 301 (2012).Google Scholar
Bian, M.Z. and Shin, K.S.: {1012} twinning behavior in magnesium single crystal. Met. Mater. Int. 19(5), 999 (2013).Google Scholar
Chapuis, A.: Low temperature plane strain compression of a magnesium single crystal with 〈c〉 axis constrained. Mater. Sci. Eng., A 590, 401 (2014).CrossRefGoogle Scholar
Syed, B., Geng, J., Mishra, R.K., and Kumar, K.S.: [0001] compression response at room temperature of single-crystal magnesium. Scr. Mater. 67(7), 700 (2012).CrossRefGoogle Scholar
Chapuis, A. and Driver, J.H.: Temperature dependency of slip and twinning in plane strain compressed magnesium single crystals. Acta Mater. 59(5), 1986 (2011).CrossRefGoogle Scholar
Al-Samman, T., Molodov, K.D., Molodov, D.A., Gottstein, G., and Suwas, S.: Softening and dynamic recrystallization in magnesium single crystals during c-axis compression. Acta Mater. 60(2), 537 (2012).CrossRefGoogle Scholar
Hartt, W.H. and Reed-Hill, R.E.: The irrational habit of second-order {1011}–{1012} twins in magnesium. Trans. Metall. Soc. AIME 239, 1511 (1967).Google Scholar
Hartt, W.H. and Reed Hill, R.E.: Internal deformation and fracture of second-order {1011}–{1012} twins in magnesium. Trans. Metall. Soc. AIME 242, 1127 (1968).Google Scholar
Ando, D., Koike, J., and Sutou, Y.: Relationship between deformation twinning and surface step formation in AZ31 magnesium alloys. Acta Mater. 58(13), 4316 (2010).Google Scholar
Jiang, L., Jonas, J.J., Luo, A.A., Sachdev, A.K., and Godet, S.: Twinning-induced softening in polycrystalline AM30 Mg alloy at moderate temperatures. Scr. Mater. 54(5), 771 (2006).Google Scholar
Molodov, K.D., Al-Samman, T., Molodov, D.A., and Gottstein, G.: Mechanisms of exceptional ductility of magnesium single crystal during deformation at room temperature: Multiple twinning and dynamic recrystallization. Acta Mater. 76, 314 (2014).Google Scholar
Salunke, P., Joshi, M., Chaswal, V., Zhang, G., Rosenbaum, L., Dowling, K., Decker, P., and Shanov, V.: Magnesium single crystals for biomedical applications grown in vertical Bridgman apparatus. Rev. Sci. Instrum. 87(10), 105126 (2016).Google Scholar
Bachmann, F., Hielscher, R., Johnson, O.K., and Mainprice, D.: MTEX toolbox (2015). Available at: https://mtex-toolbox.github.io (accessed 23 March 2017).Google Scholar
Nieh, T.G., Wadsworth, J., and Sherby, O.D.: Superplasticity in Metals and Ceramics (Cambridge University Press, Cambridge U.K., 1997); pp. 2227.Google Scholar
Schmid, E. and Boas, W.: Plasticity of Crystals with Special Reference to Metals (F. A. Hughes and Company, London U.K., 1950); pp. 287321.Google Scholar
Hayden, H.W., Moffatt, W.G., and Wulff, J.: The Structure and Properties of Materials, Vol. III (Wiley, New York, 1965); pp. 97120.Google Scholar
Christian, J.W. and Mahajan, S.: Deformation twinning. Prog. Mater. Sci. 39(1), 1 (1995).Google Scholar
Yu, Q., Jiang, Y., and Wang, J.: Cyclic deformation and fatigue damage in single-crystal magnesium under fully reversed strain-controlled tension–compression in the [1 0 0] direction. Scr. Mater. 96, 41 (2015).Google Scholar
Reed-Hill, R.E. and Abbaschian, R.: Physical Metallurgy Principles (PWS-Kent Publishing Company, Boston, Mass, 1992); pp. 521561.Google Scholar
Yoo, M.H.: Slip, twinning, and fracture in hexagonal close-packed metals. Metall. Trans. A 12(3), 409 (1981).CrossRefGoogle Scholar
Zheng, Y.: Magnesium Alloys as Degradable Biomaterials (CRC Press, Boca Rotan, FL, 2015); pp. 136.Google Scholar
Avedesian, M.M. and Baker, H.: Magnesium and Magnesium Alloys (ASM International, Materials Park, OH, 1999); pp. 711.Google Scholar
Magnesium databank. Available at: www.magnesium.com (accessed 14 January 2017).Google Scholar