Hostname: page-component-8448b6f56d-dnltx Total loading time: 0 Render date: 2024-04-25T02:22:10.690Z Has data issue: false hasContentIssue false
  • English
  • Français

Interaction between SiC and Ti powder

Published online by Cambridge University Press:  03 March 2011

I. Gotman ,
E.Y. Gutmanas  and
P. Mogilevsky
I. Gotman
Affiliation:
Department of Materials Engineering, Technion, Haifa 32000, Israel
E.Y. Gutmanas
Affiliation:
Department of Materials Engineering, Technion, Haifa 32000, Israel
P. Mogilevsky
Affiliation:
Department of Materials Engineering, Technion, Haifa 32000, Israel
Get access

Abstract

The interaction between SiC and Ti powder at 1073–1523 K was investigated employing a combination of x-ray diffraction, scanning electron microscopy with EDS, Auger spectroscopy, and transmission electron microscopy. As a result of the interaction, a triple-layer reaction zone was formed. The most important part of the reaction zone was a mixed TiC–Ti5Si3(C) layer. Thin TiC sublayers were formed on both the inner and the outer sides of the mixed reaction layer. The reaction zone was found to grow by a parabolic law with the kinetic constant, k = 1.3 × 10−3 exp (-21800/t) cm2/s. The growth process of the SiC/Ti reaction zone was assumed to be controlled by diffusion of all three components of the system: Ti, Si, and C. Thin reaction layers (<5 μm) obtained after short exposures at relatively low temperatures formed coatings on the SiC surface; thicker reaction layers spalled off the ceramic surface. Experiments with the samples partially immersed into the metal powder showed that interaction between SiC and Ti was very sensitive to the environment.

Type
Articles
Information
Journal of Materials Research , Volume 8 , Issue 10 , October 1993 , pp. 2725 - 2733
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Choi, S. K., Froyen, L., and Brabers, M. J., in Joining Ceramics, Glass and Metal, edited by Kraft, W. (DGM Informationgesellshaft, 1984), p. 297.Google Scholar
2Chamberlain, M. B., Thin Solid Films 72, 305 (1980).CrossRefGoogle Scholar
3Martineau, P., Pailler, R., Lahaye, M., and Naslain, R., J. Mater. Sci. 19, 2749 (1984).CrossRefGoogle Scholar
4Backhaus-Ricoult, M., in Designing Interfaces for Technological Applications: Ceramic-Ceramic, Ceramic-Metal Joining, edited by Peteves, S. D. (Elsevier, London, 1989), p. 79.Google Scholar
5Gotman, I. and Gutmanas, E. Y., Powder Met. Int. 21, 30 (1989).Google Scholar
6Gotman, I. and Gutmanas, E. Y., J. Mater. Sci. Lett. 9, 813 (1990).CrossRefGoogle Scholar
7Gotman, I. and Gutmanas, E. Y., Mater. Lett. 10, 370 (1991).CrossRefGoogle Scholar
8Gutmanas, E. Y., Gotman, I., and Kaysser, W., Mater. Sci. Eng. A 157, 233 (1992).CrossRefGoogle Scholar
9Gotman, I. and Gutmanas, E. Y., Acta Metall. Mater. 40, S121 (1992).CrossRefGoogle Scholar
10Pearson's Handbook of Crystallographic Data for Intermetallic Phases (American Society for Metals, Metals Park, OH, 1986), Vol. 3, edited by Villars, P. and Calvert, L. D..Google Scholar
11Goldschmidt, H. J., Interstitial Alloys (Butterworths, London, 1967).CrossRefGoogle Scholar
12Kosolapova, T. Ya., Carbides (Plenum Press, New York, 1971).Google Scholar
13Nickl, J. J., Schweitzer, K. K., and Luxenberg, P., J. Less-Comm. Met. 26, 335 (1972).CrossRefGoogle Scholar
14Barin, I., Thermochemical Data of Pure Substances (VCH, Weinheim, 1989).Google Scholar
15van Loo, F. J. J. and Bastin, G. F., Metall. Trans. A 20A, 403 (1989).CrossRefGoogle Scholar
16Sarian, S., J. Appl. Phys. 38, 3305 (1967).CrossRefGoogle Scholar