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In situ X-ray Investigation of Hydrogen Charging in Thin Film Bimetallic Electrodes

  • Najeh M. Jisrawi (a1), Harold Wiesmann (a1), M. W. Ruckman (a1), T. R. Thurston (a1), G. Reisfeld (a1), B. M. Ocko (a1) and Myron Strongin (a1)...

Abstract

Hydrogen uptake and discharge by thin metallic films under potentiostatic control was studied using x-ray diffraction at the National Synchroton Light Source (NSLS). The formation of metal-hydrogen phases in Pd, Pd-capped Nb, and Pd/Nb multilayer electrode structures was deduced from x-ray diffraction data and correlated with the cyclic voltammetry (CV) peaks. The x-ray data were also used to construct a plot of the hydrogen concentration as a function of cell potential for a multilayered thin film.

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1. A good review of the current status of electrochemical technology is given in Surface Electrochemistry–A Molecular Approach, Bockris, J. O'M. and Khan, S. U. M. (Plenum Press, New York, 1994), Chap. 9.
2. See, for example, “Hydrogen Storage Materials, Batteries and Electrochemistry,” edited by Corrigan, A. and Srinvagan, S., PV 92-5, The Electrochemical Society Proceedings Series, Pennington, NJ (1992).
3.Iwakura, C., Sakai, T., and Ishikawa, H., Chem. Ind. 40, 248 (1988).
4.Ovshinsky, S. R., Fetcenko, M. A., and Ross, J., Science 260, 176 (1993); S. R. Ovshinsky, H. Sapru, K. Dea, and K. C. Hong, U.S. Patent 4,431,561 (1984).
5.McCormack, M., Badding, M. E., Vyas, B., Zahurak, S. M., and Murphy, D. W., J. Electrochem. Soc. 143, L31 (1996).
6.Briggs, G. W. D., Electrochimica Acta 1, 297 (1959); J. N. Andrews and A. R. Ubbelohde, Proc. Roy. Soc. A 253, 6 (1959); S. Uno Falk, J. Electrochem. Soc. 107, 661 (1960); G. W. D. Briggs and W. F. K. Wynne-Jones, Electrochimica Acta 7, 241 (1962); A. J. Salkind and P. F. Bruins, J. Electrochem. Soc. 109, 356 (1962).
7.Chianelli, R. R., Scanlon, J. C., and Rao, B. M. L., J. Electrochem. Soc. 125, 1563 (1978).
8.Fleischmann, M. and Mao, B. W., J. Electroanal. Chem. 229, 125 (1987).
9.Nazri, G. and Muller, R. H., J. Electrochem. Soc. 132, 1385 (1985).
10.Samant, M. G., Toney, M. F., Borges, G. L., Blum, L., and Melroy, O. R., Surf. Sci. 193, L29 (1988).
11.Adzic, G. D., Johnson, J. R., Reilly, J. J., McBreen, J., Mukerjee, S., Sridhar-Kumar, M. P., Zhang, W., and Srinvasan, S., J. Electrochem. Soc. 142, 3429 (1995).
12.Latroche, M., Percheron-Guegan, A., Chabre, Y., Poinsignon, C., and Pannetier, J., J. Alloys and Compounds 189, 59 (1992).
13. J. O'Bockris, M. and Reddy, A. K. N., Modern Electrochemistry (Plenum Press, New York, 1970), Vol. 2.
14.Koch, E., Handbook on Synchrotron Radiation (Elsevier Scientific Publishers, Amsterdam, The Netherlands, 1983), Vols. 1–4.
15.Will, F. G. and Knorr, C. A., Z. Electrochim. 64, 258 (1960); R. S. Nicholson and I. Shain, Anal. Chem. 26, 706 (1964).
16.Reisfeld, G., Jisrawi, N. M., Ruckman, M. W., and Strongin, Myron, Phys. Rev. B 53, 4974 (1996).
17.Pasternak, R. A. and Evans, B., J. Electrochem. Soc. 114, 452 (1967).
18.Wang, J., Ocko, B. M., Davenport, A. J., and Isaacs, H., Phys. Rev. B 46, 10, 321 (1992).
19. “NSLS User's Manual, Guide to the VUV and X-ray Beam Lines,” edited by N. F. Gmur, BNL Informal Report No. 48724 (1993).
20.Warren, B. E., X-ray Diffraction (Addison-Wesley Publishers, Reading, MA 1969), Chap. 13, p. 251.
21.Peisl, H., in Hydrogen in Metals I, edited by Alefeld, G. and J., Völkl, Topics in Appl. Phys. (Springer-Verlag, Berlin, 1978), Vol. 28 p. 55).
22.Bond, R. A. and Ross, D. K., J. Phys. F 12, 597 (1982).
23.Capon, A. and Parsons, R., J. Electroanal. Chem. 39, 275 (1972); R. R. Adzic, M. D. Spasojevic, and A. R. Despic, J. Electroanal. Chem. 92, 31 (1978); J. P. Chevillot, J. Farcy, C. Hinner, and A. Rousseau, J. Electroanal. Chem. 64, 39 (1975); J. Horkans, J. Electroanal. Chem. 106, 245 (1980); S. Szpak, P. A. Mosier-Boss, S. R. Scharber, and J. J. Smith, J. Electroanal. Chem. 337, 147 (1992).
24. Ibid, Ref. 21, p. 65.
25.Schöber, T. and Wenzl, H., in Hydrogen in Metals II, edited by Alefeld, G. and J., Völkl, Topics in Appl. Phys. (Springer-Verlag, Berlin, 1978), Vol. 28, p. 11.
26.Zabel, H. and Peisl, J., J. Phys. F 9, 1461 (1979).
27.Alefeld, G., Phys. Chem. 76, 355 (1972); R. Feenstra, G. J. de Bruin-Hordijk, H. L. M. Bakker, R. Griessen, and D. G. de Groot, J. Phys. F 13, L13 (1983).
28.Moehlecke, S., Majkrzak, C. F., and Strongin, M., Phys. Rev. B 31, 6804 (1985).
29.Fukai, Y., The Metal-Hydrogen System: Basic Bulk Properties, Springer Series in Materials Science (Springer-Verlag, Berlin, 1993), Vol. 21, p. 2.

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In situ X-ray Investigation of Hydrogen Charging in Thin Film Bimetallic Electrodes

  • Najeh M. Jisrawi (a1), Harold Wiesmann (a1), M. W. Ruckman (a1), T. R. Thurston (a1), G. Reisfeld (a1), B. M. Ocko (a1) and Myron Strongin (a1)...

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