- Cited by 19
Pompe, Constantin and Pfitzner, Arno 2012. Na3SbSe3: Synthesis, Crystal Structure Determination, Raman Spectroscopy, and Ionic Conductivity. Zeitschrift für anorganische und allgemeine Chemie, Vol. 638, Issue. 12-13, p. 2158.
Huber, Sebastian Preitschaft, Christian Weihrich, Richard and Pfitzner, Arno 2012. Preparation, Crystal Structure, Electronic Structure, Impedance Spectroscopy, and Raman Spectroscopy of Li3SbS3and Li3AsS3. Zeitschrift für anorganische und allgemeine Chemie, Vol. 638, Issue. 15, p. 2542.
Xiang, Yong Zhang, Xiaokun and Zhang, Shu 2013. Insight into the mechanism of Sb promoted Cu(In,Ga)Se2 formation. Journal of Solid State Chemistry, Vol. 204, Issue. , p. 278.
Majsztrik, P. W. Kirkham, M. Garcia-Negron, V. Lara-Curzio, Edgar Skoug, E. J. and Morelli, D. T. 2013. Effect of thermal processing on the microstructure and composition of Cu–Sb–Se compounds. Journal of Materials Science, Vol. 48, Issue. 5, p. 2188.
Huber, Sebastian and Pfitzner, Arno 2014. LiSbS2-mC16: Structure Determination from X-ray Powder Diffraction Data. Zeitschrift für anorganische und allgemeine Chemie, Vol. 640, Issue. 8-9, p. 1596.
Tyagi, Kriti Gahtori, Bhasker Bathula, Sivaiah Srivastava, A. K. Shukla, A. K. Auluck, Sushil and Dhar, Ajay 2014. Thermoelectric properties of Cu3SbSe3 with intrinsically ultralow lattice thermal conductivity. J. Mater. Chem. A, Vol. 2, Issue. 38, p. 15829.
Samanta, K. Gupta, N. Kaur, H. Sharma, L. Dogra Pandey, S. Singh, J. Senguttuvan, T.D. Dilawar Sharma, N. and Bandyopadhyay, A.K. 2015. Order–disorder transition and Fano-interference in thermoelectric Cu3SbSe3 nanoparticles. Materials Chemistry and Physics, Vol. 151, Issue. , p. 99.
Qiu, Wujie Wu, Lihua Ke, Xuezhi Yang, Jihui and Zhang, Wenqing 2015. Diverse lattice dynamics in ternary Cu-Sb-Se compounds. Scientific Reports, Vol. 5, Issue. 1,
Blichfeld, A. B. and Iversen, B. B. 2015. Fast direct synthesis and compaction of phase pure thermoelectric ZnSb. Journal of Materials Chemistry C, Vol. 3, Issue. 40, p. 10543.
Wei, Tian-Ran Wu, Chao-Feng Sun, Wei Pan, Yu and Li, Jing-Feng 2015. Is Cu3SbSe3 a promising thermoelectric material?. RSC Advances, Vol. 5, Issue. 53, p. 42848.
Vaqueiro, P. Al Orabi, R. A. R. Luu, S. D. N. Guélou, G. Powell, A. V. Smith, R. I. Song, J.-P. Wee, D. and Fornari, M. 2015. The role of copper in the thermal conductivity of thermoelectric oxychalcogenides: do lone pairs matter?. Physical Chemistry Chemical Physics, Vol. 17, Issue. 47, p. 31735.
Huber, Sebastian and Pfitzner, Arno 2015. Li17Sb13S28: A New Lithium Ion Conductor and addition to the Phase Diagram Li2S-Sb2S3. Chemistry - A European Journal, Vol. 21, Issue. 39, p. 13683.
Qiu, WuJie Ke, XueZhi Xi, LiLi Wu, LiHua Yang, Jiong and Zhang, WenQing 2016. “Phonon” scattering beyond perturbation theory. Science China Physics, Mechanics & Astronomy, Vol. 59, Issue. 2,
Liu, Rui Ren, Guangkun Tan, Xing Lin, Yuanhua and Nan, Cewen 2016. Enhanced Thermoelectric Properties of Cu3SbSe3-Based Composites with Inclusion Phases. Energies, Vol. 9, Issue. 10, p. 816.
Vaqueiro, Paz Guélou, Gabin Kaltzoglou, Andreas Smith, Ronald I. Barbier, Tristan Guilmeau, Emmanuel and Powell, Anthony V. 2017. The Influence of Mobile Copper Ions on the Glass-Like Thermal Conductivity of Copper-Rich Tetrahedrites. Chemistry of Materials, Vol. 29, Issue. 9, p. 4080.
Said, Suhana Mohd Sahamir, Shahrir Razey Sabri, Mohd Faizul Mohd Kamarudin, Muhammad Akmal Hayashi, Kei Zulkifli, Ahmad Zulazlan Shah Nakajo, Takaki Kubouchi, Masataka and Miyazaki, Yuzuru 2017. Polymer electrolyte liquid crystal mixtures as phase-dependent thermoelectric materials. Molecular Crystals and Liquid Crystals, Vol. 642, Issue. 1, p. 9.
Li, JingFeng Pan, Yu Wu, ChaoFeng Sun, FuHua and Wei, TianRan 2017. Processing of advanced thermoelectric materials. Science China Technological Sciences, Vol. 60, Issue. 9, p. 1347.
Peccerillo, Enzo and Durose, Ken 2018. Copper–antimony and copper–bismuth chalcogenides—Research opportunities and review for solar photovoltaics. MRS Energy & Sustainability, Vol. 5, Issue. ,
Wei, Tian-Ran Wu, Chao-Feng Li, Fu and Li, Jing-Feng 2018. Low-cost and environmentally benign selenides as promising thermoelectric materials. Journal of Materiomics, Vol. 4, Issue. 4, p. 304.
Check if you have access via personal or institutional login
- Volume 26, Issue 15 (Focus Issue: Advances in Thermoelectric Materials)
- 14 August 2011 , pp. 2001-2005
We report the results of an investigation on the structural evolution of a potential new thermoelectric material, Cu3SbSe3, as a function of temperature from 25 to 390 °C. From high-temperature x-ray diffraction data, the refined lattice parameters were seen to change nonlinearly, but continuously, with temperature, with an increased rate of thermal expansion in the a and b lattice parameters from around 125 °C to 175 °C and negative thermal expansion in the c axis from around 100 °C to 175 °C. Crystallographic charge flipping analysis indicated an increase in the disorder of the copper cations with temperature. This reversible order/disorder phase transition in Cu3SbSe3 affects the transport properties, as evidenced by thermal conductivity measurements, which change from negative to positive slope at the transition temperature. This structural change in Cu3SbSe3 has implications for its potential use in thermoelectric generators.
Hide All1.Yang, J.: Potential applications of thermoelectric waste heat recovery in the automotive industry, in Proceedings of the Twenty-fourth International Conference on Thermoelectrics, edited by Tritt, T.M. (Clemson, SC, 2005), p. 170–174.2.Bell, L.E.: Cooling, heating, generating power, and recovering waste heat with thermoelectric systems. Science 321, 1457 (2008).3.Tritt, T.M., Böttner, H., and Chen, L.: Thermoelectrics: Direct solar thermal energy conversion. MRS Bull. 33, 366 (2008).4.Skoug, E.J., Cain, J.D., and Morelli, D.T.: Structural effects on the lattice thermal conductivity of ternary antimony- and bismuth-containing chalcogenide semiconductors. Appl. Phys. Lett. 96, 181905 (2010).5.Pfitzner, A.: Cu3SbSe3: Syntheses und Kristallstruktur. Z. Anorg. Allg. Chem. 621, 685 (1995).6.Palatinus, L. and Chapuis, G.: Superflip—a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions. J. Appl. Cryst. 40, 786 (2007).7.Pfitzner, A.: Disorder of Cu+ in Cu3SbS3: Structural investigation of the high- and low-temperature modification. Z. Kristallogr. 213, 228 (1998).8.Makovicky, E.: Polymorphism in Cu3SbS3 and Cu3BiS3—the ordering schemes for copper atoms and electron-microscope observations. Neues Jahrb. Mineral Abh. 168, 185 (1994).9.Makovicky, E.: The phase transformation and thermal expansion of the solid electrolyte Cu3BiS3 between 25 and 300 °C. J. Solid State Chem. 49, 85 (1983).
Email your librarian or administrator to recommend adding this journal to your organisation's collection.
- ISSN: 0884-2914
- EISSN: 2044-5326
- URL: /core/journals/journal-of-materials-research
* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.
Usage data cannot currently be displayed