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Hard DLC coating deposited over nitrided martensitic stainless steel: analysis of adhesion and corrosion resistance

Published online by Cambridge University Press:  20 October 2016

Eugenia L. Dalibon ,
Sonia P. Brühl ,
Vladimir J. Trava-Airoldi ,
Lisandro Escalada  and
Silvia N. Simison
Eugenia L. Dalibon*
Affiliation:
Surface Engineering Group, Universidad Tecnológica Nacional (UTN-FRCU), E3264BTD Concepción del Uruguay, Argentina
Sonia P. Brühl
Affiliation:
Surface Engineering Group, Universidad Tecnológica Nacional (UTN-FRCU), E3264BTD Concepción del Uruguay, Argentina
Vladimir J. Trava-Airoldi
Affiliation:
Instituto Nacional de Pesquisas Espaciáis (INPE), 12.227-010 São José dos Campos–SP, Brazil
Lisandro Escalada
Affiliation:
Surface and Bioprocess Engineering Group, INTEMA, Faculty of Engineering, University of Mar del Plata, Mar del Plata, Argentina
Silvia N. Simison
Affiliation:
Surface and Bioprocess Engineering Group, INTEMA, Faculty of Engineering, University of Mar del Plata, Mar del Plata, Argentina
*
a)Address all correspondence to this author. e-mail: dalibone@frcu.utn.edu.ar
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Abstract

Surface modification treatments, such as the plasma nitriding improve the tribological properties of AISI 420 stainless steel; however, the corrosion resistance is deteriorated. The DLC (Diamond-Like Carbon) coatings were not only having a low friction coefficient but also good wear and corrosion resistance. In this work, both the corrosion behavior and the adhesion of the DLC hard coating, deposited on nitrided and non-nitrided AISI 420 stainless steel substrates, were studied. The coatings were characterized by means of EDS and Raman. In addition, nitrided layer microstructure and the coatings were analyzed by SEM-FIB and XRD. Corrosion behavior was evaluated by the salt spray fog test and cyclic potentiodynamic polarization tests in NaCl solution. The adhesion was assessed using Rockwell indentation and scratch tests. The a-C:H film and nitrided layer thicknesses were about 2.5 μm and 11 μm respectively. The nitrided layer improved adhesion in both tests. The coated AISI 420 stainless steel proved to have excellent atmospheric corrosion resistance and a passive behavior over 1 V (versus SCE) in the electrochemical tests. The adhesion and the corrosion performance were improved when the coating was deposited after the plasma nitriding treatment.

Keywords

DLC coatingadhesionAISI 420plasma nitridingcorrosion
Type
Articles
Information
Journal of Materials Research , Volume 31 , Issue 22 , 28 November 2016 , pp. 3549 - 3556
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Copyright
Copyright © Materials Research Society 2016 

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References

REFERENCES

Alphonsa, I., Chainani, A., Raole, P.M., Ganguli, B., and John, P.I.: A study of martensitic stainless steel AISI 420 modified using plasma nitriding. Surf. Coat. Technol. 150, 263 (2002).CrossRefGoogle Scholar
Corengia, P., Ybarra, G., Moina, C., Cabo, A., and Broitman, E.: Microstructure and corrosion behaviour of DC-pulsed plasma nitrided AISI 410 martensitic stainless steel. Surf. Coat. Technol. 187, 63 (2004).CrossRefGoogle Scholar
Li, C.X. and Bell, T.: Corrosion properties of plasma nitrided AISI 410 martensitic stainless steel in 3.5% NaCl and 1% HCl aqueous solutions. Corros. Sci. 48, 2036 (2006).CrossRefGoogle Scholar
Robertson, J.: Diamond-like amorphous carbon. Mater. Sci. Eng., R 37, 129 (2002).CrossRefGoogle Scholar
Grill, A.: Diamond-like carbon: State of the art. Diamond Relat. Mater. 8, 428 (1999).CrossRefGoogle Scholar
Erdemir, A. and Donnet, C.: Tribology of diamond-like carbon films: Recent progress and future prospects. J. Phys. D: Appl. Phys. 39, R311 (2006).CrossRefGoogle Scholar
Sun, Y. and Bell, T.: Plasma Surface engineering of low alloy steel. Mater. Sci. Eng., A 140, 419 (1991).CrossRefGoogle Scholar
Snyders, R., Bousser, E., Amireault, P., Klemberg-Sapieha, J.E., Park, E., Taylor, K., Casey, K., and Martinu, L.: Tribo-mechanical properties of DLC coatings deposited on nitrided biomedical stainless steel. Plasma Processes Polym. 4, S640 (2007).CrossRefGoogle Scholar
Qi, F., Leng, Y.X., Huang, N., Bai, B., and Zhang, P.C.: Surface modification of 17-4PH stainless steel by DC plasma nitriding and titanium nitride film duplex treatment. Nucl. Instrum. Methods Phys. Res., Sect. B 257, 416 (2007).CrossRefGoogle Scholar
Azzi, M., Benkahoul, M., Klemberg-Sapieha, J.E., and Martinu, L.: Corrosion and mechanical properties of duplex-treated 301 stainless steel. Surf. Coat. Technol. 205, 1557 (2010).CrossRefGoogle Scholar
Forsich, C., Dipolt, C., Heim, D., Mueller, T., Gebeshuber, A., Holecek, R., and Lungmair, C.: Potential of thick a-C:H:Si films as substitute for chromium plating. Surf. Coat. Technol. 241, 86 (2013).CrossRefGoogle Scholar
Hadinata, S.S., Lee, M.T., Pan, S.J., Tsai, W.T., Tai, C.Y., and Shih, C.F.: Electrochemical performances of diamond-like carbon coatings on carbon steel, stainless steel, and brass. Thin Solid Films 529, 412 (2013).CrossRefGoogle Scholar
Chandler, H.: Heat Treater's Guide, Practices and Procedures for Irons and Steels (ASM International, Materials Park, 1995); pp. 775, 776.Google Scholar
Capote, G., Bonetti, L.F., Santos, L.V., Trava-airoldi, V.J., and Corat, E.J.: Adherent amorphous hydrogenated carbon films on metals deposited by plasma enhanced chemical vapor deposition. Thin Solid Films 516, 4011 (2008).CrossRefGoogle Scholar
Escalada, L., Lutz, J., Brühl, S.P., Fazio, M., Márquez, A., Mändl, S., Manova, D., and Simison, S.N.: Microstructure and corrosion behaviour of AISI 316L duplex treated by means of ion nitriding and plasma based ion implantation and deposition. Surf. Coat. Technol. 223, 41 (2013).CrossRefGoogle Scholar
Ferrari, A.C. and Robertson, J.: Interpretation of Raman spectra of disordered and amorphous carbon. Phys. Rev. B: Condens. Matter Mater. Phys. 61, 14095 (2000).CrossRefGoogle Scholar
Casiraghi, C., Ferrari, A.C., and Robertson, J.: Raman spectroscopy of hydrogenated amorphous carbons. Phys. Rev. B: Condens. Matter Mater. Phys. 72, 1 (2005).CrossRefGoogle Scholar
Brühl, S.P., Charadia, R., Simison, S., Lamas, D.G., and Cabo, A.: Corrosion behavior of martensitic and precipitation hardening stainless steels treated by plasma nitriding. Surf. Coat. Technol. 204, 3280 (2010).CrossRefGoogle Scholar
Kwietniewski, C., Fontana, W., Moraes, C., Rocha, A.da S., Hirsch, T., and Reguly, A.: Nitrided layer embrittlement due to edge effect on duplex treated AISI M2 high-speed steel. Surf. Coat. Technol. 179, 27 (2004).CrossRefGoogle Scholar
Wen, X.Q. and Wang, J.: Deposition of diamond-like carbon films on the inner surface of narrow stainless steel tubes. Vacuum 85, 34 (2010).CrossRefGoogle Scholar
Sharma, R., Barhai, P.K., and Kumari, N.: Corrosion resistant behaviour of DLC films. Thin Solid Films 516, 5397 (2008).CrossRefGoogle Scholar
Azzi, M., Amirault, P., Paquette, M., Klemberg-Sapieha, J.E., and Martinu, L.: Corrosion performance and mechanical stability of 316L/DLC coating system: Role of interlayers. Surf. Coat. Technol. 204, 3986 (2010).CrossRefGoogle Scholar
Chen, C.W., Huanga, C.C., Lina, Y.Y., Chen, L.C., and Chen, K.H.: The affinity of Si–N and Si–C bonding in amorphous silicon carbon nitride (a-SiCN) thin film. Diamond Relat. Mater. 14, 1126 (2005).CrossRefGoogle Scholar
Vidakis, N., Antoniadis, A., and Bilalis, N.: The VDI 3198 indentation test evaluation of a reliable qualitative control for layered compounds. J. Mater. Process. Technol. 143–144, 481 (2003).CrossRefGoogle Scholar
ASTM C-1624-05 (Reapproved 2010) Standard Test Method for Adhesion Strength and Mechanical Failure Modes of Ceramic Coatings by Quantitative Single Point Scratch Testing, ASTM International, 2011.Google Scholar
Bull, S.J.: Failure mode maps in the thin film scratch adhesion test. Tribol. Int. 30, 491 (1997).CrossRefGoogle Scholar
Choi, J., Soejima, K., Kato, T., Kawaguchi, M., and Lee, W.: Nitriding of high speed steel by bipolar PBII for improvement in adhesion strength of DLC films. Nucl. Instrum. Methods Phys. Res., Sect. B 272, 357 (2012).CrossRefGoogle Scholar
Kim, K., Kim, H., La, J., and Lee, S.: Effects of interlayer thickness and the substrate material on the adhesion properties of CrZrN coatings. Jpn. J. Appl. Phys. 55, 01AA02 (2016).CrossRefGoogle Scholar