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Gold nanoshell arrays-based visualized sensors of pH: Facile fabrication and high diffraction intensity

Published online by Cambridge University Press:  08 February 2017

D.D. Men ,
F. Zhou ,
H.L. Li ,
L.F. Hang ,
X.Y. Li ,
D.L. Liu ,
W.P. Cai ,
L.M. Qi ,
L.B. Li  and
Y. Li Open the ORCID record for Y. Li [Opens in a new window]
D.D. Men
Affiliation:
Key Lab of Materials Physics, Anhui Key Lab of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People’s Republic of China; and College of Chemistry Chemical Engineering and Materials Science, HanDan University, Hadan 056005, People’s Republic of China
F. Zhou
Affiliation:
Key Lab of Materials Physics, Anhui Key Lab of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People’s Republic of China
H.L. Li
Affiliation:
Key Lab of Materials Physics, Anhui Key Lab of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People’s Republic of China
L.F. Hang
Affiliation:
Key Lab of Materials Physics, Anhui Key Lab of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People’s Republic of China
X.Y. Li
Affiliation:
Key Lab of Materials Physics, Anhui Key Lab of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People’s Republic of China
D.L. Liu
Affiliation:
Key Lab of Materials Physics, Anhui Key Lab of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People’s Republic of China
W.P. Cai
Affiliation:
Key Lab of Materials Physics, Anhui Key Lab of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People’s Republic of China
L.M. Qi
Affiliation:
College of Chemistry, Peking University, Beijing 100871, People’s Republic of China
L.B. Li
Affiliation:
National Synchrotron Radiation Lab and College of Nuclear Science and Technology, CAS Key Lab of Soft Matter Chemistry, University of Science and Technology of China, Hefei 230026, People’s Republic of China
Y. Li*
Affiliation:
Key Lab of Materials Physics, Anhui Key Lab of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People’s Republic of China
*
a) Address all correspondence to this author. e-mail: yueli@issp.ac.cn
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Abstract

A free standing 2D PS colloidal crystal with Au nanoshells/hydrogel composite film (CAuHCF) was fabricated by embedding a 2D PS colloidal crystal with Au nanoshells into a polyacrylic acid (PAA) hydrogel film. This CAuHCF can act as a visualized sensor with high diffraction intensity. The 2D PS colloidal crystal with Au nanoshells was prepared by depositing an Au layer on PS colloidal crystal obtained by interfacial self-assembly. The diffraction intensity of the CAuHCF was increased by about 30-fold than that of traditional 2D PS colloidal crystal/hydrogel composite film on transparent substrate due to large scattering cross section of Au shell. Such sensors based Au nanoshells array with the simple preparation process and the strong diffraction signal are promising ones for practical applications in visual detection. Additionally, with the simple preparation process and high diffraction intensity, other visualized sensors based different hydrogel matrix and the 2D PS colloidal crystal with Au nanoshells could be synthesized for monitoring various analysts.

Keywords

2D colloidal crystalAu nanoshellhydrogeldiffraction intensityvisualized sensor
Type
Article
Information
Journal of Materials Research , Volume 32 , Issue 4 , 28 February 2017 , pp. 717 - 725
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Copyright
Copyright © Materials Research Society 2017 

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Footnotes

Contributing Editor: Edson Roberto Leite

References

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