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Formation and structure of carbon nanocage structures produced by polymer pyrolysis and electron-beam irradiation

Published online by Cambridge University Press:  31 January 2011

Takeo Oku ,
Takanori Hirano ,
Katsuaki Suganuma  and
Satoru Nakajima
Takeo Oku*
Affiliation:
Institute of Scientific and Industrial Research, Osaka University, Mihogaoka 8–1, Ibaraki, Osaka 567–0047, Japan
Takanori Hirano
Affiliation:
Institute of Scientific and Industrial Research, Osaka University, Mihogaoka 8–1, Ibaraki, Osaka 567–0047, Japan
Katsuaki Suganuma
Affiliation:
Institute of Scientific and Industrial Research, Osaka University, Mihogaoka 8–1, Ibaraki, Osaka 567–0047, Japan
Satoru Nakajima
Affiliation:
Department of Chemistry, Tohoku University, Aramaki, Aoba-ku, Sendai 980–8578, Japan
*
a)Address all correspondence to this author. e-mail: Oku@sanken.osaka-u.ac.jp
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Abstract

Carbon nanocapsules with SiC and Au nanoparticles were produced by thermal decomposition of polyvinyl alcohol at about 500 °C in Ar gas atmosphere. The formation mechanism of nanocapsules and a structural model for the nanocapsule/SiC interface were proposed. In addition, carbon clusters were formed at the surface of carbon nanocapsules, and carbon onions were produced by electron irradiation of amorphous carbon produced from polyvinyl alcohol. The present work indicates that the pyrolysis of polymer materials with clusters is a useful fabrication method for the mass production of carbon nanocapsules and onions at low temperatures compared to the ordinary arc discharge method.

Type
Articles
Information
Journal of Materials Research , Volume 14 , Issue 11 , November 1999 , pp. 4266 - 4273
Copyright
Copyright © Materials Research Society 1999

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