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Effect of Zn addition on microstructure and mechanical properties of Mg–9Gd–3Y–0.5Zr alloy

Published online by Cambridge University Press:  29 December 2017

Wendong Cui
Affiliation:
National Engineering Research Center of Light Alloy Net Forming and Key State Laboratory of Metal Matrix Composite, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
Lv Xiao
Affiliation:
Shanghai Spaceflight Precision Machinery Institute, Shanghai 201600, China; and Shanghai Engineering Technology Research Center of Near-Net-Shape Forming for Metallic Materials, Shanghai 201600, China
Wencai Liu*
Affiliation:
National Engineering Research Center of Light Alloy Net Forming and Key State Laboratory of Metal Matrix Composite, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
Guohua Wu*
Affiliation:
National Engineering Research Center of Light Alloy Net Forming and Key State Laboratory of Metal Matrix Composite, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
Xianfei Wang
Affiliation:
Shanghai Spaceflight Precision Machinery Institute, Shanghai 201600, China; and Shanghai Engineering Technology Research Center of Near-Net-Shape Forming for Metallic Materials, Shanghai 201600, China
Zhongquan Li*
Affiliation:
Shanghai Spaceflight Precision Machinery Institute, Shanghai 201600, China; and Shanghai Engineering Technology Research Center of Near-Net-Shape Forming for Metallic Materials, Shanghai 201600, China
*
a)Address all correspondence to these authors. e-mail: liuwc@sjtu.edu.cn
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Abstract

A comparison of microstructure, mechanical properties and fracture behavior of Mg–9Gd–3Y–xZn–0.5Zr (x = 0, 0.2, 0.5, 1.0, and 1.5) (wt%) alloys under different thermal treatment conditions was investigated in this study. The results showed that the as-cast alloys were comprised of Mg matrix, eutectic compounds and cuboid-shaped phases. The eutectics were Mg24(Gd, Y)5 in the alloys of Zn content ≤0.2 wt%, while (Mg, Zn)3RE in the other three alloys. Fine lamellar long period stacking ordered structure formed inside of matrix of the as-cast Zn-containing alloys and its quantity increases with raising Zn content. Mg12(Gd, Y)Zn was observed at grain boundary of Mg matrix after solution treatment in the alloys of Zn content ≥0.5 wt%. Peak-aged Mg–9Gd–3Y–0.5Zn–0.5Zr alloy exhibited a desirable combination of strength and elongation with 244 MPa in yield strength, 371 MPa in ultimate tensile strength and 3.8% in EL. Meanwhile, the fracture behavior of the studied alloys was also investigated.

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Articles
Copyright
Copyright © Materials Research Society 2017 

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Footnotes

Contributing Editor: Jürgen Eckert

References

REFERENCES

Mordike, B.L. and Ebert, T.: Magnesium: Properties-applications-potential. Mater. Sci. Eng., A 302, 3745 (2001).Google Scholar
Li, D.J., Zeng, X.Q., Dong, J., and Zhai, C.Q.: Influence of heat treatment on microstructure and mechanical properties of Mg–10Gd–3Y–1.2Zn–0.4Zr alloy. Trans. Nonferrous Met. Soc. China 18, 117121 (2008).CrossRefGoogle Scholar
Nakatsugawa, I., Kamado, S., Kojima, Y., Ninomiya, R., and Kubota, K.: Corrosion of magnesium alloys containing rare earth elements. Corros. Rev. 16, 139158 (1998).Google Scholar
Anthony, A.I., Kamado, S., and Kojima, Y.: Aging characteristics and high temperature tensile properties of Mg–Gd–Y–Zr alloys. Mater. Trans. 42, 12061211 (2001).Google Scholar
He, S.M., Zeng, X.Q., Peng, L.M., Gao, X., Nie, J.F., and Ding, W.J.: Precipitation in a Mg–10Gd–3Y–0.4Zr (wt%) alloy during isothermal ageing at 250 °C. J. Alloys Compd. 421, 309313 (2006).CrossRefGoogle Scholar
He, S.M., Zeng, X.Q., Peng, L.M., Gao, X., Nie, J.F., and Ding, W.J.: Microstructure and strengthening mechanism of high strength Mg–10Gd–2Y–0.5Zr alloy. J. Alloys Compd. 427, 316323 (2007).CrossRefGoogle Scholar
Anyanwu, I.A., Kamado, S., and Kojima, Y.: Platform science and technology for advanced magnesium alloys. Creep properties of Mg–Gd–Y–Zr alloys. Mater. Trans. 42, 12121218 (2001).CrossRefGoogle Scholar
Wang, J., Meng, J., Zhang, D., and Tang, D.: Effect of Y for enhanced age hardening response and mechanical properties of Mg–Gd–Y–Zr alloys. Mater. Sci. Eng., A 456, 7884 (2007).Google Scholar
Sun, M., Wu, G., Wang, W., and Ding, W.: Effect of Zr on the microstructure, mechanical properties and corrosion resistance of Mg–10Gd–3Y magnesium alloy. Mater. Sci. Eng., A 523, 145151 (2009).CrossRefGoogle Scholar
Jafari Nodooshan, H.R., Wu, G., Liu, W., Wei, G., Li, Y., and Zhang, S.: Effect of Gd content on high temperature mechanical properties of Mg–Gd–Y–Zr alloy. Mater. Sci. Eng., A 651, 840847 (2016).Google Scholar
Kawabata, T., Matsuda, K., Kamado, S., Kojima, Y., and Ikeno, S.: HRTEM observation of the precipitates in Mg–Gd–Y–Zr alloy. Mater. Sci. Forum 419–422, 303306 (2003).CrossRefGoogle Scholar
Zhang, H., Fan, J., Zhang, L., Wu, G., Liu, W., Cui, W., and Feng, S.: Effect of heat treatment on microstructure, mechanical properties and fracture behaviors of sand-cast Mg–4Y–3Nd–1Gd–0.2Zn–0.5Zr alloy. Mater. Sci. Eng., A 677, 411420 (2016).Google Scholar
Luo, Z., Zhang, S., Tang, Y., and Zhao, D.: Microstructures of Mg–Zn–Zr-RE alloys with high RE and low Zn contents. J. Alloys Compd. 209, 275278 (1994).Google Scholar
Honma, T., Ohkubo, T., Kamado, S., and Hono, K.: Effect of Zn additions on the age-hardening of Mg–2.0Gd–1.2Y–0.2Zr alloys. Acta Mater. 55, 41374150 (2007).Google Scholar
Kawamura, Y., Hayashi, K., Inoue, A., and Masumoto, T.: Rapidly solidified powder metallurgy magnesium alloys with novel mechanical properties. Mater. Sci. Forum 13, 529534 (2002).Google Scholar
Zhang, S., Liu, W., Gu, X., Lu, C., Yuan, G., and Ding, W.: Effect of solid solution and aging treatments on the microstructures evolution and mechanical properties of Mg–14Gd–3Y–1.8Zn–0.5Zr alloy. J. Alloys Compd. 557, 9197 (2013).CrossRefGoogle Scholar
Li, D., Zeng, X., Dong, J., Zhai, C., and Ding, W.: Microstructure evolution of Mg–10Gd–3Y–1.2Zn–0.4Zr alloy during heat-treatment at 773 K. J. Alloys Compd. 468, 164169 (2009).Google Scholar
Zhang, S., Yuan, G.Y., Lu, C., and Ding, W.J.: The relationship between (Mg,Zn)3RE phase and 14H-LPSO phase in Mg–Gd–Y–Zn–Zr alloys solidified at different cooling rates. J. Alloys Compd. 509, 35153521 (2011).CrossRefGoogle Scholar
Gao, Y., Wang, Q., Gu, J., Zhao, Y., Tong, Y., and Yin, D.: Comparison of microstructure in Mg–10Y–5Gd–0.5Zr and Mg–10Y–5Gd–2Zn–0.5Zr alloys by conventional casting. J. Alloys Compd. 477, 374378 (2009).Google Scholar
Liu, K., Zhang, J., Su, G., Tang, D., Rokhlin, L.L., Elkin, F.M., and Meng, J.: Influence of Zn content on the microstructure and mechanical properties of extruded Mg–5Y–4Gd–0.4Zr alloy. J. Alloys Compd. 481, 811818 (2009).Google Scholar
Zhu, Y.M., Morton, A.J., and Nie, J.F.: Growth and transformation mechanisms of 18R and 14H in Mg–Y–Zn alloys. Acta Mater. 60, 65626572 (2012).Google Scholar
Chino, Y., Mabuchi, M., Hagiwara, S., Iwasaki, H., Yamamoto, A., and Tsubakino, H.: Novel equilibrium two phase Mg alloy with the long-period ordered structure. Scr. Mater. 51, 711714 (2004).Google Scholar
Suzuki, M., Kimura, T., Koike, J., and Maruyama, K.: Strengthening effect of Zn in heat resistant Mg–Y–Zn solid solution alloys. Scr. Mater. 48, 9971002 (2003).Google Scholar
Yamada, K., Okubo, Y., Shiono, M., Watanabe, H., Kamado, S., and Kojima, Y.: Alloy development of high toughness Mg–Gd–Y–Zn–Zr alloys. Mater. Trans. 47, 10661070 (2006).Google Scholar
Huang, S., Wang, J., Hou, F., Huang, X., and Pan, F.: Effect of Gd and Y contents on the microstructural evolution of long period stacking ordered phase and the corresponding mechanical properties in Mg–Gd–Y–Zn–Mn alloys. Mater. Sci. Eng., A 612, 363370 (2014).CrossRefGoogle Scholar
Lee, J.Y., Kim, D.H., Lim, H.K., and Kim, D.H.: Effects of Zn/Y ratio on microstructure and mechanical properties of Mg–Zn–Y alloys. Mater. Lett. 59, 38013805 (2005).Google Scholar
Liu, Y., Yuan, G., Zhang, S., Zhang, X., Lu, C., and Ding, W.: Effects of Zn/Gd ratio and content of Zn, Gd on phase constitutions of Mg alloys. Mater. Trans. 49, 941944 (2008).Google Scholar
Su, Z., Liu, C., and Wan, Y.: Microstructures and mechanical properties of high performance Mg–4Y–2.4Nd–0.2Zn–0.4Zr alloy. Mater. Des. 45, 466472 (2013).Google Scholar
Kang, Y.H., Wu, D., Chen, R.S., and Han, E.H.: Microstructures and mechanical properties of the age hardened Mg–4.2Y–2.5Nd–1Gd–0.6Zr (WE43) microalloyed with Zn. J. Magnesium Alloys 2, 109115 (2014).Google Scholar
Liu, X.B., Chen, R.S., and Han, E.H.: Effects of ageing treatment on microstructures and properties of Mg–Gd–Y–Zr alloys with and without Zn additions. J. Alloys Compd. 465, 232238 (2008).Google Scholar
Shao, X.H., Yang, Z.Q., and Ma, X.L.: Strengthening and toughening mechanisms in Mg–Zn–Y alloy with a long period stacking ordered structure. Acta Mater. 58, 47604771 (2010).Google Scholar
Ding, W.J., Wu, Y.J., Peng, L.M., Zeng, X.Q., Yuan, G.Y., and Lin, D.L.: Formation of 14H-type long period stacking ordered structure in the as-cast and solid solution treated Mg–Gd–Zn–Zr alloys. J. Mater. Res. 24, 18421854 (2011).Google Scholar
Gao, X., Muddle, B.C., and Nie, J.F.: Transmission electron microscopy of Zr–Zn precipitate rods in magnesium alloys containing Zr and Zn. Philos. Mag. Lett. 89, 3343 (2009).CrossRefGoogle Scholar
Sha, G., Zhu, H.M., Liu, J.W., Luo, C.P., Liu, Z.W., and Ringer, S.P.: Hydrogen-induced decomposition of Zr-rich cores in an Mg–6Zn–0.6Zr–0.5Cu alloy. Acta Mater. 60, 56155625 (2012).Google Scholar
Wu, Y.J., Peng, L.M., Zeng, X.Q., Lin, D.L., and Ding, W.J.: Formation of a novel X Phase in Mg–Gd–Zn–Zr alloy. Mater. Sci. Forum 654–656, 623626 (2010).Google Scholar
Datta, A., Waghmare, U.V., and Ramamurty, U.: Structure and stacking faults in layered Mg–Zn–Y alloys: A first-principles study. Acta Mater. 56, 25312539 (2008).Google Scholar
Suzuki, M., Kimura, T., Koike, J., and Maruyama, K.: Effects of zinc on creep strength and deformation substructures in Mg–Y alloy. Mater. Sci. Eng., A 387–389, 706709 (2004).Google Scholar
Gao, L., Chen, R.s., and Han, E.h.: Fracture behavior of high strength Mg–Gd–Y–Zr magnesium alloy. Trans. Nonferrous Met. Soc. China 20, 12171221 (2010).CrossRefGoogle Scholar