Hostname: page-component-8448b6f56d-dnltx Total loading time: 0 Render date: 2024-04-24T11:03:13.515Z Has data issue: false hasContentIssue false
  • English
  • Français

Effect of MnS precipitation on solute equilibrium partition coefficients in high sulfur steel during solidification

Published online by Cambridge University Press:  05 June 2018

Lintao Gui ,
Mujun Long ,
Huabiao Chen ,
Dengfu Chen ,
Huamei Duan ,
Yunwei Huang  and
Tao Liu
Lintao Gui
Affiliation:
College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China
Mujun Long*
Affiliation:
College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China
Huabiao Chen*
Affiliation:
College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China
Dengfu Chen*
Affiliation:
College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China
Huamei Duan
Affiliation:
College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China
Yunwei Huang
Affiliation:
College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China
Tao Liu
Affiliation:
College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China
*
a)Address all correspondence to these authors. e-mail: longmujun@cqu.edu.cn
b)e-mail: chendfu@cqu.edu.cn
Get access

Abstract

The solute equilibrium partition coefficients (ki) of C, Si, Mn, P, and S in high sulfur steel during the solidification process were investigated by the thermodynamic calculation. The effect of MnS precipitation on ki was explored. The results showed that the precipitation of MnS inclusion would influence the concentrations of solutes Mn and S, leading to the changing of ki. Due to the precipitation of MnS, the kC and kS decreased first and then increased with temperature decreasing, while kSi, kMn, and kP changed monotonously. The impacts of solidification temperature on kSi and kMn were greater than that on kC, kS, and kP. With the increase of S content, kC, kSi, and kP increased while kMn and kS decreased. Whereas, an opposite effect was found with the increase of Mn content. The order of influence extent by S and Mn contents was kSi > kS > kMn > kC > kP.

Keywords

equilibrium partition coefficientMnS precipitationhigh sulfur steelsolidification
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 20 , 29 October 2018 , pp. 3490 - 3500
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Bazhenov, V.E., Pikunov, M.V., and Cheverikin, V.V.: The partition coefficients of components in Cu–Ni–Mn alloys. Metall. Mater. Trans. A 46, 843 (2015).CrossRefGoogle Scholar
Gui, L.T., Long, M.J., Chen, D.F., Huang, Y.W., Liu, T., Chen, H.B., and Duan, H.M.: Modeling on solute enrichment and inclusion precipitation during the solidification process of high sulfur steel slab. J. Mater. Res. 32, 3854 (2017).CrossRefGoogle Scholar
Hobbs, R.A., Tin, S., and Rae, C.M.F.: A castability model based on elemental solid-liquid partitioning in advanced nickel-base single-crystal superalloys. Metall. Mater. Trans. A 36, 2761 (2005).CrossRefGoogle Scholar
Sung, P.K. and Poirier, D.R.: Liquid-solid partition ratios in nickel-base alloys. Metall. Mater. Trans. A 30, 2173 (1999).CrossRefGoogle Scholar
Battle, T.P. and Pehlke, R.D.: Equilibrium partition-coefficients in iron-based alloys. Metall. Trans. B 20, 149 (1989).CrossRefGoogle Scholar
Kagawa, A., Iwata, K., Nofal, A.A., and Okamoto, T.: Theoretical evaluation of equilibrium partition coefficients of solute elements in Fe–C-base quaternary and muIticomponent systems. Met. Sci. J. 1, 678 (1985).Google Scholar
Okamoto, T., Morita, Z., Kagawa, A., and Tanaka, T.: Partition of carbon between solid and liquid in Fe–C binary-system. Trans. Iron Steel Inst. Jpn. 23, 266 (1983).CrossRefGoogle Scholar
Kagawa, A. and Okamoto, T.: Partition of silicon during eutectic solidification of iron–carbon–silicon alloy. Met. Sci. 14, 519 (1980).CrossRefGoogle Scholar
Heckl, A., Rettig, R., and Singer, R.F.: Solidification characteristics and segregation behavior of nickel-base superalloys in dependence on different rhenium and ruthenium contents. Metall. Mater. Trans. A 41, 202 (2010).CrossRefGoogle Scholar
Wang, H.F., Su, H.J., Zhang, J., Huang, T.W., Liu, L., and Fu, H.Z.: Influence of melt superheating treatment temperature on solute distribution behavior of a new Ni-based single crystal superalloys. Acta Metall. Sin. 52, 419 (2016).Google Scholar
Imai, N., Tanaka, T., Yuki, T., Iida, T., and Morita, Z.: Equilibrium distribution of Sn between solid and liquid-phases in Fe–Sn and Fe–C–Sn alloys. Tetsu to Hagane 77, 224 (1991).CrossRefGoogle Scholar
Kagawa, A., Okamoto, T., and Goda, S.: Partition of nitrogen in solidifying iron carbon silicon alloys. J. Mater. Sci. 23, 649 (1988).CrossRefGoogle Scholar
Min, Z., Shen, J., Feng, Z., Wang, L., and Liu, L.: Study on partition ratio and segregation behavior of DZ125 alloy during directional solidification. Acta Metall. Sin. 46, 1543 (2010).Google Scholar
Ocansey, P.M.N. and Pourier, D.R.: Equilibrium partition ratios of C, Mn, and Si in a high carbon steel. Mater. Sci. Eng., A 211, 10 (1996).CrossRefGoogle Scholar
Kagawa, A., Hirata, M., and Sakamoto, Y.: Solute partitioning on solidification of nickel-base ternary alloys. J. Mater. Sci. 25, 5063 (1990).CrossRefGoogle Scholar
Kagawa, A. and Okamoto, T.: Coefficients for equilibrium partition of a third element between solid and liquid in iron-carbon base ternary alloys and their relation to graphitization during iron-carbon eutectic solidification. J. Mater. Sci. 19, 2306 (1984).CrossRefGoogle Scholar
Morita, Z. and Tanaka, T.: Distribution of solute elements between solid and liquid phases in iron-carbon base ternary alloys. Tetsu to Hagane 70, 1575 (2009).CrossRefGoogle Scholar
Sun, H.B. and Zhang, J.Q.: Study on the macrosegregation behavior for the bloom continuous casting: Model development and validation. Metall. Mater. Trans. B 45, 1133 (2014).CrossRefGoogle Scholar
Chen, H.B., Long, M.J., Cao, J.S., Chen, D.F., Liu, T., and Dong, Z.H.: Phase transition of peritectic steel Q345 and its effect on the equilibrium partition coefficients of solutes. Metals 7, 288 (2017).CrossRefGoogle Scholar
Xu, J.Y., Liu, Z.Q., Guo, G.Q., and Chen, M.: An investigation on wear mechanism of high-speed turning of free-cutting steel AISI 1215 using uncoated and multi-layer coated tools. Int. J. Adv. Manuf. Technol. 67, 517 (2013).CrossRefGoogle Scholar
You, D.L., Michelic, S.K., Bernhard, C., Loder, D., and Wieser, G.: Modeling of inclusion formation during the solidification of steel. ISIJ Int. 56, 1770 (2016).CrossRefGoogle Scholar
Huang, Y.W., Long, M.J., Liu, P., Chen, D.F., Chen, H.B., Gui, L.T., Liu, T., and Yu, S.: Effects of partition coefficients, diffusion coefficients, and solidification paths on microsegregation in Fe-based multinary alloy. Metall. Mater. Trans. B 48, 2504 (2017).CrossRefGoogle Scholar
Bale, C.W., Bélisle, E., Chartrand, P., Decterov, S.A., Eriksson, G., Gheribi, A.E., Hack, K., Jung, I.H., Kang, Y.B., Melançon, J., Pelton, A.D., Petersen, S., Robelin, C., Sangster, J., Spencer, P., and Van Ende, M.A.: FactSage thermochemical software and databases, 2010–2016. Calphad 54, 35 (2016).CrossRefGoogle Scholar