Hostname: page-component-76fb5796d-2lccl Total loading time: 0 Render date: 2024-04-26T10:42:26.143Z Has data issue: false hasContentIssue false
  • English
  • Français

Effect of iron and cobalt addition on TiC combustion synthesis

Published online by Cambridge University Press:  03 March 2011

Yoon Choi  and
Shi-Woo Rhee
Yoon Choi
Affiliation:
Laboratory for Advanced Materials Processing, Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 790-600, Korea
Shi-Woo Rhee
Affiliation:
Laboratory for Advanced Materials Processing, Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 790-600, Korea
Get access

Abstract

Fe and Co metals were incorporated into a Ti and C mixture with a molar ratio of 1.0 over the range of 0 to 40 wt. % to study their effect on TiC combustion synthesis. The addition brought about the grain size decrease, change of grain shape (angular to spherical), and different distribution (agglomerated to isolated) of TiC grains. Both Fe and Co additives were distributed around TiC grains and served as a binder. It was observed that reaction between Ti and C was kinetically more favorable than any other reactions in the Ti–C–Fe or Ti–C–Co system. Based on the activation energy from an Arrhenius plot of In[(1−w)1/2u/Tc] vs 1/Tc, which was obtained by combustion temperature and wave velocity measurements, the reaction mechanism in combustion synthesis of TiC with the addition of 20 wt. % Fe and Co was suggested.

Type
Articles
Information
Journal of Materials Research , Volume 8 , Issue 12 , December 1993 , pp. 3202 - 3209
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Miller, D. J. and Pask, J. A., J. Am. Ceram. Soc. 66, 841 (1983).CrossRefGoogle Scholar
2Nakanishi, H., Tanaka, I., Okamoto, T., Miyamoto, Y., and Yamada, O., J. Jpn. Soc. Powder and Powder Metall. 37, 105 (1990).CrossRefGoogle Scholar
3Holt, J. B. and Munir, J. A., J. Mater. Sci. 21, 251 (1986).CrossRefGoogle Scholar
4Hoke, D. A., Meyers, M. A., Meyer, L. W., and Gray, G. T. III, Metall. Trans. 23A, 77 (1992).CrossRefGoogle Scholar
5Kudo, H. and Odawara, O., J. Mater. Sci. 24, 4030 (1989).CrossRefGoogle Scholar
6Grami, M. E. and Munir, Z. A., J. Am. Ceram. Soc. 73, 1235 (1990).CrossRefGoogle Scholar
7Krueger, B. R., Mutz, A. H., and Vreeland, T., Jr., Metall. Trans. 23A, 55 (1992).CrossRefGoogle Scholar
8Philpot, K. A., Munir, Z. A., and Holt, J. B., J. Mater. Sci. 22, 159 (1987).CrossRefGoogle Scholar
9Zhang, S. and Munir, Z. A., J. Mater. Sci. 26, 3685 (1991).CrossRefGoogle Scholar
10Merzhanov, A. G., presented at The International Symposium on Combustion and Plasma Synthesis of High-Temperature Materials, San Francisco, CA, October 23–26 (1988), pp. 1–91.Google Scholar
11Nakanishi, H., Tanaka, I., Okamoto, T., Miyamoto, Y., and Yamada, O., J. Jpn. Soc. Powder and Powder Metall. 36, 82 (1989).Google Scholar
12Tabchenko, A. N., Panteleeva, T. A., and Itin, V. I., Combust. Explos. Shock Waves (Engl. Transl.) 20, 387 (1984).CrossRefGoogle Scholar
13Dunmead, S. D., Readey, D. W., Semler, C. E., and Holt, J. B., J. Am. Ceram. Soc. 72, 2318 (1989).CrossRefGoogle Scholar
14Dunmead, S. D., Munir, Z. A., Holt, J. B., and Kingman, D. D., J. Mater. Sci. 26, 2410 (1991).CrossRefGoogle Scholar
15Rabin, B. H., J. Am. Ceram. Soc. 75, 131 (1992).CrossRefGoogle Scholar
16Gabriel, K. A., Lin, S. S., McCauley, J. W., Alexander, J. R., Resetar, T. M., and Lowder, L., presented at Proceedings of the DARPA/Army Symposium on Self-Propagating High-Temperature Synthesis, Daytona Beach, FL, October 21–23 (1985), pp. 313–338.Google Scholar
17Lograsso, B. K. and German, R. M., presented at Progress in Powder Metallurgy, Metal Powder Industries Federation and American Powder Metallurgy Institute, Princeton, NJ (1987), pp. 415–439.Google Scholar
18Toth, L. E., Transition Metal Carbides and Nitrides (Academic Press, New York and London, 1971), p. 10.Google Scholar
19Dunmead, S. D., Munir, Z. A., and Holt, J. B., J. Am. Ceram. Soc. 75, 180 (1992).CrossRefGoogle Scholar
20Choi, Y. and Rhee, S., J. Mater. Sci. (in press).Google Scholar
21Ho, C. Y., Powell, R. W., and Liley, P. E., CRC Handbook of Chemistry and Physics, edited by Weast, R. C., Lide, D. R., Astle, M. J., and Beyer, W. H. (CRC Press, Inc., Boca Raton, FL, 1990), p. E-14.Google Scholar
22Adelsberg, L. and Cadoff, L., Trans. AIME 24, 933 (1967).Google Scholar
23Quinn, C. J. and Kohlstedt, D. L., J. Am. Ceram. Soc. 67, 305 (1984).CrossRefGoogle Scholar
24Sarin, S., J. Appl. Phys. 40, 3515 (1969).CrossRefGoogle Scholar
25Massalski, T. B., Murray, J. L., Bennett, L. H., and Baker, H., Binary Alloy Phase Diagrams (American Society for Metals, Metals Park, OH, 1986), pp. 556, 562.Google Scholar
26Massalski, T. B., Murray, J. L., Bennett, L. H., and Baker, H., Binary Alloy Phase Diagrams (American Society for Metals, Metals Park, OH, 1986), pp. 809, 1118.Google Scholar
27Dufour, L. C., Monty, C., and Ervas, G. P., Surfaces and Interfaces of Ceramic Materials (Kluwer Academic Publishers, Dordrecht, Boston, and London, 1988), p. 173.Google Scholar