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Controlling the particle size of amorphous iron nanoparticles

Published online by Cambridge University Press:  03 March 2011

X. Cao ,
Yu Koltypin ,
G. Kataby ,
R. Prozorov  and
A. Gedanken
X. Cao
Affiliation:
Department of Chemistry, Bax-llan University, Ramat-Gan, Israel 52900
Yu Koltypin
Affiliation:
Department of Chemistry, Bax-llan University, Ramat-Gan, Israel 52900
G. Kataby
Affiliation:
Department of Chemistry, Bax-llan University, Ramat-Gan, Israel 52900
R. Prozorov
Affiliation:
Department of Physics, Bar-llan University, Ramat-Gan, Israel 52900
A. Gedanken*
Affiliation:
Department of Chemistry, Bar-llan University, Ramat-Gan, Israel 52900
*
a)Author to whom all correspondence should be addressed.
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Abstract

A method for controlling the particle size of amorphous iron, which was prepared by the sonication of iron pentacarbonyl [Fe(CO)5], is reported in this paper. The sonolysis was performed on neat Fe(CO)5 and its solutions in decane whose concentrations were 4 M, 1 M, and 0.25 M. The iron nanoparticles were subjected to TEM (Transmission Electron Micrograph), ESR (Electron Spin Resonance), TGA (Thermogravimetric Analysis), DSC (Differential Scanning Calorimctry), and Quantum Design SQUID magnetization measurement. The measured properties demonstrated a strong dependence on the concentration of the solution, e.g., particle size.

Type
Articles
Information
Journal of Materials Research , Volume 10 , Issue 11 , November 1995 , pp. 2952 - 2957
Copyright
Copyright © Materials Research Society 1995

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References

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