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C60 fullerene tubes as removable templates

Published online by Cambridge University Press:  01 February 2006

Jun-ichi Minato  and
Kun'ichi Miyazawa
Jun-ichi Minato*
Affiliation:
Ecomaterials Center, National Institute for Materials Science, Tsukuba 305-0044, Japan
Kun'ichi Miyazawa*
Affiliation:
Ecomaterials Center, National Institute for Materials Science, Tsukuba 305-0044, Japan
*
a)Address all correspondence to these authors. e-mail: MINATO.Junchi@nims.go.jp
b)Address all correspondence to these authors. e-mail: MIYAZAWA.Kunichi@nims.go.jp
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Abstract

Crystalline microtubes (inner diameter 240–2100 nm) consisting of C60 fullerene molecules were prepared in the mixture of C60-saturated pyridine and isopropyl alcohol kept at 0 °C. Characterization by transmission electron microscopy showed a linear relationship between the outer diameter and the inner diameter for the C60 fullerene tubes. Optical observations suggested that the specimens already had tubular structure when they were grown in the solution. Deposition of guest crystals inside the C60 fullerene tubes was performed by the following procedure: (i) ultrasonic pulverization to obtain the C60 fullerene tubes with open ends, (ii) absorption of methyl alcohol solution of KBr into the tubes by the capillary attraction, and (iii) evaporation of methyl alcohol to precipitate KBr inside the tubes. Columnar KBr crystals were then obtained by dissolving the fullerene tube walls in toluene.

Keywords

NanostructureSolution depositionTransmission electron microscopy (TEM)
Type
Articles
Information
Journal of Materials Research , Volume 21 , Issue 2 , February 2006 , pp. 529 - 534
Copyright
Copyright © Materials Research Society 2006

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References

REFERENCES

1.Krätschmer, W., Lamb, L.D., Fostiropoulos, K. and Huffman, D.R.: Solid C60: A new form of carbon. Nature 347, 354 (1990).CrossRefGoogle Scholar
2.Obeng, Y.S. and Bard, A.J.: Langmuir films of C60 at the air-water interface. J. Am. Chem. Soc. 113, 6279 (1991).CrossRefGoogle Scholar
3.Nakamura, T., Tachimbana, H., Yumura, M., Matsumoto, M., Azumi, R., Tanaka, M. and Kawabata, Y.: Formation of Langmuir– Blodgett films of a fullerene. Langmuir 8, 4 (1992).CrossRefGoogle Scholar
4.Yosida, Y.: Scanning electron-microscope images of C60 whiskers. Jpn. J. Appl. Phys. 31, L505 (1992).CrossRefGoogle Scholar
5.Miyazawa, K., Kuwasaki, Y., Obayashi, A. and Kuwabara, M.: C60 nanowhiskers formed by the liquid-liquid interfacial precipitation method. J. Mater. Res. 17, 83 (2002).CrossRefGoogle Scholar
6.Liu, H., Li, Y., Jiang, L., Luo, H., Xiao, S., Fang, H., Li, H., Zhu, D., Yu, D., Xu, J. and Xiang, B.: Imaging as-grown [60]fullerene nanotubes by template technique. J. Am. Chem. Soc. 124, 13370 (2002).CrossRefGoogle ScholarPubMed
7.Gan, H., Liu, H., Li, Y., Gan, L., Jiang, L., Jiu, T., Wang, N., He, X. and Zhu, D.: Fabrication of fullerene nanotube arrays using a template technique. Carbon 43, 205 (2005).CrossRefGoogle Scholar
8.Miyazawa, K. and Suga, T.: Transmission electron microscopy investigation of fullerene nanowhiskers and needle-like precipitates formed by using C60 and (η2–C60)Pt(PPh3)2. J. Mater. Res. 19, 2410 (2004).CrossRefGoogle Scholar
9.Miyazawa, K., Minato, J., Yoshii, T., Fujino, M. and Suga, T.: Structural characterization of the fullerene nanotubes prepared by the liquid–liquid interfacial precipitation method. J. Mater. Res. 20, 688 (2005).CrossRefGoogle Scholar
10.Minato, J., Miyazawa, K. and Suga, T.: Morphology of C60 nanotubes fabricated by the liquid–liquid interfacial precipitation method. Sci. Technol. Adv. Mater. 6, 272 (2005).CrossRefGoogle Scholar
11.Iijima, S.: Helical microtubles of graphitic carbon. Nature 354, 56 (1991).CrossRefGoogle Scholar
12.Cheng, J., Fang, Y., Huang, Q., Yan, Y. and Li, X.: Blue-green photoluminescence from pyridine-C60 adduct. Chem. Phys. Lett. 330, 262 (2000).CrossRefGoogle Scholar
13.Minato, J. and Miyazawa, K.: Structural characterization of C60 nanowhiskers and C60 nanotubes fabricated by the liquid–liquid interfacial precipitation method. Diamond Relat. Mater. (in press).Google Scholar
14.Heiney, P.A., Fischer, J.E., McGhie, A.R., Romanow, W.J., Denenstein, A.M., McCauley, J.P. Jr. and III, A.B. Smith: Orientational ordering transition in solid C60. Phys. Rev. Lett. 64, 2911 (1991).CrossRefGoogle Scholar
15.Miyazawa, K., Minato, J., Fujino, M., and Suga, T.: Structural investigation of heat-treated fullerene nanotubes and nanowhiskers. Diamond Relat. Mater. (in press).Google Scholar
16.Ajayan, P.M. and Iijima, S.: Capillary-induced filling of carbon nanotubes. Nature 361, 333 (1993).CrossRefGoogle Scholar
17.Meyer, R.R., Sloan, J., Dunin-Borkowski, R.E., Kirkland, A.I., Novotny, M.C., Bailey, S.R., Hutchison, J.L. and Green, M.L.H.: Discrete atom imaging of one-dimensional crystals formed within single-walled carbon nanotubes. Science 289, 1324 (2000).CrossRefGoogle ScholarPubMed
18.Sloan, J., Novotny, M.C., Bailey, S.R., Brown, G., Xu, C., Williams, V.C., Friedrichs, S., Flahaut, E., Callender, R.L., York, A.P.E., Coleman, K.S., Green, M.L.H., Dunin-Borkowski, R.E. and Hutchison, J.L.: Two layer 4:4 co-ordinated KI crystals grown within single walled carbon nanotubes. Chem. Phys. Lett. 329, 61 (2000).CrossRefGoogle Scholar
19.Kim, B.M., Sinha, S. and Bau, H.H.: Optical microscope study of liquid transport in carbon nanotubes. Nano Lett. 4, 2203 (2004).CrossRefGoogle Scholar
20.Rossi, M.P., Ye, H., Gogotsi, Y., Babu, S., Ndungu, P. and Bradley, J-C.: Environmental scanning electron microscopy study of water in carbon nanopipes. Nano Lett. 4, 989 (2004).CrossRefGoogle Scholar
21.Wilson, M. and Madden, P.A.: Growth of ionic crystals in carbon nanotubes. J. Am. Chem. Soc. 123, 2101 (2001).CrossRefGoogle ScholarPubMed