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Preparation of copper compounds of different compositions and particle morphologies

Published online by Cambridge University Press:  31 January 2011

Stanka Kratohvil  and
Egon Matijević
Stanka Kratohvil
Affiliation:
Department of Chemistry, Clarkson University, Potsdam, New York 13699
Egon Matijević
Affiliation:
Department of Chemistry, Clarkson University, Potsdam, New York 13699
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Abstract

Copper compounds of different chemical compositions and particle shapes were prepared by homogeneous precipitation from copper salt solutions in the presence of urea. It was demonstrated that the nature of the anions played an essential role in the properties of the generated solid phase. Thus, Cu(II)-nitrate solutions yielded spherical amorphous particles which had the composition of malachite [Cu2(OH)2CO3], the Cu(II)-chloride solutions gave bipyramidal particles of atacamite [CuCl2 · 3Cu(OH)2], and in Cu(II)-sulfate solutions needle-shaped brochantite [3Cu(OH)2 · CuSO4] or platelets of posnjakite [3Cu(OH)2 · CuSO4 · H2O] were formed. The addition of NaOH to prepared dispersions resulted in a rapid phase transformation of all above solids into needle-like Cu(OH)2. Calcination of various copper basic compounds at 700–800 °C temperature produced CuO, while the particle morphology was retained.

Type
Articles
Information
Journal of Materials Research , Volume 6 , Issue 4 , April 1991 , pp. 766 - 777
Copyright
Copyright © Materials Research Society 1991

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References

1Matijević, E., Annu. Rev. Mater. Sci. 15, 483 (1985).Google Scholar
2Sugimoto, T., Adv. Colloid Interface Sci. 28, 65 (1987).CrossRefGoogle Scholar
3Haruta, M. and Delmon, B., J. Chim. Phys. 83, 859 (1986).CrossRefGoogle Scholar
4Bulletin, MRS, “Fine Particles”, Part I, 14 (1989) December issue; Part II, 15 (1990) January issue.Google Scholar
5Matijević, E. and Scheiner, P., J. Colloid Interface Sci. 63, 509 (1978).Google Scholar
6Chittofrati, A. and Matijević, E., Colloids Surf. 48, 65 (1990).CrossRefGoogle Scholar
7Livage, J., Henry, M., and Sanchez, C., Prog. Solid State Chem. 18 (4), 259 (1988).CrossRefGoogle Scholar
8Powder Diffraction File, Card No. 18–439, Joint Committee on Powder Diffraction Standards, Swarthmore, PA, 1981.Google Scholar
9Powder Diffraction File, Card No. 13–398, Joint Committee on Powder Diffraction Standards, Swarthmore, PA, 1981.Google Scholar
10Powder Diffraction File, Card No. 20–364, Joint Committee on Powder Diffraction Standards, Swarthmore, PA, 1981.Google Scholar
11Ramamurthy, P. and Secco, E. A., Can. J. Chem. 47, 2185 (1969).Google Scholar
12Markov, L., Chr. Dobrev, and R. Ionchev, Russ. J. Inorg. Chem. 32 (3), 385 (1987).Google Scholar
13Labanukrom, T., Kolloid-Chem. Beihefte 29, 80 (1929).Google Scholar
14Balarew, Chr., Markov, L., and Dobrev, Chr., Izv. Khim. 12 (4), 524 (1979) (Ger.).Google Scholar
15Gyunner, E. A., Yakhkind, N. D., and Tsareva, A. I., Russ. J. Inorg. Chem. 33 (2), 279 (1988).Google Scholar
16Gyunner, E. A., Yakhkind, N. D., and Melnichenko, L. M., Russ. J. Inorg. Chem. 30 (5), 742 (1985).Google Scholar
17McFadyen, P. and Matijević, E., J. Colloid Interface Sci. 44, 95 (1973).CrossRefGoogle Scholar
18Keklikian-Durand, L. and Matijević, E., Colloid Polymer Sci. 268, 1151 (1990).Google Scholar
19Ribot, F., Kratohvil, S., and Matijević, E., J. Mater. Res. 4, 1123 (1989).Google Scholar
20Feitknecht, W. and Studer, H., Kolloid-Z. 115 (1–3), 13 (1949).CrossRefGoogle Scholar