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Microstructure and Optical Properties of Au–Y2O3-stabilized ZrO2 Nanocomposite Films

Published online by Cambridge University Press:  03 March 2011

George Sirinakis ,
Rezina Siddique ,
Christos Monokroussos ,
Michael A. Carpenter  and
Alain E. Kaloyeros
George Sirinakis
Affiliation:
College of Nanoscale Science and Engineering, The University at Albany—State Universityof New York, Albany, New York 12203
Rezina Siddique
Affiliation:
College of Nanoscale Science and Engineering, The University at Albany—State Universityof New York, Albany, New York 12203
Christos Monokroussos
Affiliation:
College of Nanoscale Science and Engineering, The University at Albany—State Universityof New York, Albany, New York 12203
Alain E. Kaloyeros*
Affiliation:
College of Nanoscale Science and Engineering, The University at Albany—State Universityof New York, Albany, New York 12203
*
b) Address all correspondence to this author. e-mail: mcarpenter@uamail.albany.edu
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Abstract

Nanocomposite films consisting of gold nanoparticles embedded in an yttria stabilized zirconia (YSZ) matrix were synthesized at room temperature by radio-frequency co-sputtering from YSZ and Au targets at a 5 mTorr working pressure. The films were subsequently annealed for 2 h in 1 atm argon, with the annealing temperature varied from 600 to 1000 °C in steps of 100 °C. The composition, microstructure, and optical properties of the films were characterized as a function of annealing temperature by Rutherford backscattering spectrometry, scanning electron microscopy, Auger electron spectroscopy, x-ray diffraction, and absorption spectroscopy. An optical absorption band due to the surface plasmon resonance (SPR) of the Au nanoparticles was observed around a wavelength of 600 nm. Furthermore, the SPR band full width at half-maximum exhibited an inverse linear dependence on the radius of the Au nanoparticle, with a slope parameter A = 0.18, indicating a weak interaction between the YSZ matrix and the Au nanoparticles. The experimentally observed SPR dependence on nanoparticle size is discussed within the context of the Mie theory and its size-dependent optical constants.

Keywords

Grain growthNanoparticleOptical properties
Type
Articles
Information
Journal of Materials Research , Volume 20 , Issue 9 , September 2005 , pp. 2516 - 2522
Copyright
Copyright © Materials Research Society 2005

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References

REFERENCES

1Murray, C.B., Kegar, C.R. and Bawendi, M.G.: Synthesis and characterization of monodisperse nanocrystals and close-packed nanocrystal assemblies. Annu. Rev. Mater. Sci. 30, 545 (2000).CrossRefGoogle Scholar
2Link, S. and El-Sayed, M.A.: Optical properties and ultrafast dynamics of metallic nanocrystals. Annu. Rev. Phys. Chem. 54, 331 (2003).CrossRefGoogle ScholarPubMed
3MacFarland, A.D. and Van Duyne, R.P.: Single silver nanoparticles as real-time optical sensors with zeptomole sensitivity. Nano Lett. 3, 1057 (2003).CrossRefGoogle Scholar
4Ando, M., Kobayashi, T., Iijima, S. and Haruta, M.: Optical CO sensitivity of Au–CuO composite film by use of the plasmon absorption change. Sens. Actuators B 96, 589 (2003).CrossRefGoogle Scholar
5Fukumi, K., Chayahara, A., Kadono, K., Sakaguchi, T., Horino, Y., Miya, M., Fujii, K., Hayakawa, J. and Satou, M.: Gold nanoparticles ion implanted in glass with enhanced nonlinear optical properties. J. Appl. Phys. 75, 3075 (1994).CrossRefGoogle Scholar
6Tanahashi, I., Manabe, Y., Tohda, T., Sasaki, S. and Nakamura, A.: Optical nonlinearities of Au/SiO2 composite thin films prepared by a sputtering method. J. Appl. Phys. 79, 1244 (1996).CrossRefGoogle Scholar
7Hosoya, Y., Suga, T., Yanagawa, T. and Kurokawa, Y.: Linear and nonlinear optical properties of sol-gel-derived Au nanometer-particle-doped alumina. J. Appl. Phys. 81, 1475 (1997).CrossRefGoogle Scholar
8Boulouz, M., Boulouz, A., Giani, A. and Boyer, A.: Influence of substrate temperature and target composition on the properties of yttria-stabilized zirconia thin films grown by r.f. reactive magnetron sputtering. Thin Solid Films 323, 85 (1998).CrossRefGoogle Scholar
9Johner, G. and Schweitzer, J.K.: Thermal-barrier coatings for jet engine improvement. Thin Solid Films 119, 301 (1984).CrossRefGoogle Scholar
10Singhal, S.C.: Advances in solid oxide fuel cell technology. Solid State Ionics 135, 305 (2000).CrossRefGoogle Scholar
11Bohren, C.F. and Huffman, D.R.: Absorption and Scattering of Light by Small Particles (Wiley, New York, 1983), p. 82.Google Scholar
12Cullity, B.D. and Stock, S.R.: Elements of X-ray Diffraction, 3rd ed. (Prentice-Hall, Upper Saddle River, NJ, 2001), p. 388.Google Scholar
13Thermo, A.R.L. (private communication, 2003).Google Scholar
14Lide, D.R.: Handbook of Chemistry and Physics, 83rd ed. (CRC Press LLC, Boca Raton, FL, 2002).Google Scholar
15Allen, G.L., Bayles, R.A., Gile, W.W. and Jesser, W.A.: Small particle melting of pure metals. Thin Solid Films 144, 297 (1986).CrossRefGoogle Scholar
16Dick, K., Dhanasekaran, T., Zhang, Z. and Meisel, D.: Size-dependent melting of silica- encapsulated gold nanoparticles. J. Am. Chem. Soc. 124, 2312 (2002).CrossRefGoogle ScholarPubMed
17De Marchi, G., Mattei, G., Mazzoldi, P., Sada, C. and Miotello, A.: Two stages in the kinetics of gold cluster growth in ion-implanted silica during isothermal annealing in oxidizing atmosphere. J. Appl. Phys. 92, 4249 (2002).CrossRefGoogle Scholar
18Christensen, N.E. and Seraphin, B.O.: Relativistic band calculation and the optical properties of gold. Phys. Rev. B 4, 3321 (1971).CrossRefGoogle Scholar
19Hövel, H., Fritz, S., Hilger, A., Kreibig, U. and Vollmer, M.: Width of cluster plasmon resonances: Bulk dielectric functions and chemical interface damping. Phys. Rev. B 48, 18178 (1993).CrossRefGoogle ScholarPubMed
20Persson, B.N.J.: Polarizability of small spherical metal particles: Influence of the matrix environment. Surf. Sci. 281, 153 (1993).CrossRefGoogle Scholar
21Kreibig, U. and Vollmer, M.: Optical Properties of Metal Clusters (Springer, New York, 1995).CrossRefGoogle Scholar
22Ashcroft, N.W. and Mermin, N.D.: Solid State Physics (Saunders College Publishing, New York, NY, 1976), pp.10.Google Scholar
23Zafeiratos, S. and Kennou, S.: A study of gold ultrathin film growth on yttria-stabilized ZrO2(100). Surf. Sci. 443, 238 (1999).CrossRefGoogle Scholar
24Zafeiratos, S., Neophytides, S. and Kennou, S.: A photoelectron spectroscopy study of Au thin films on ZrO2 (100). Thin Solid Films 386, 53 (2001).CrossRefGoogle Scholar
25Kresin, V.: Collective resonances in silver clusters: Role of d electrons and the polarization-free surface layer. Phys. Rev. B 51, 1844 (1995).CrossRefGoogle ScholarPubMed
26Palpant, B., Prével, B., Lermé, J., Cottancin, E., Pellarin, M., Treilleux, M., Perez, A., Vialle, J.L. and Broyer, M.: Optical properties of gold clusters in the size range 2–4 nm. Phys. Rev. B 57, 1963 (1998).CrossRefGoogle Scholar
27Ferdigo, S., Harbich, W. and Buttet, J.: Collective dipole oscillations in small silver clusters embedded in rare-gas matrices. Phys. Rev. B 47, 10706 (1993).Google Scholar
28Johnson, P.B. and Christy, R.W.: Optical constants of the noble metals. Phys. Rev. B 6, 4370 (1972).CrossRefGoogle Scholar
29Dalacu, D. and Martinu, L.: Spectroellipsometric characterization of plasma-deposited Au/SiO2 nanocomposite films. J. Appl. Phys. 87, 228 (2000).CrossRefGoogle Scholar