Hostname: page-component-77c89778f8-vpsfw Total loading time: 0 Render date: 2024-07-18T01:06:05.707Z Has data issue: false hasContentIssue false

In situ fabrication and mechanical properties of Al–AlN composite by hot extrusion of partially nitrided AA6061 powder

Published online by Cambridge University Press:  14 July 2011

Peng Yu*
Affiliation:
The University of Queensland, School of Mechanical and Mining Engineering, ARC Centre of Excellence for Design in Light Metals, Queensland 4072, Australia
M. Balog
Affiliation:
Institute of Materials and Machine Mechanics, SAS, Bratislava, Slovak Republic
M. Yan
Affiliation:
The University of Queensland, School of Mechanical and Mining Engineering, ARC Centre of Excellence for Design in Light Metals, Queensland 4072, Australia
G.B. Schaffer
Affiliation:
The University of Queensland, School of Mechanical and Mining Engineering, ARC Centre of Excellence for Design in Light Metals, Queensland 4072, Australia
M. Qian*
Affiliation:
The University of Queensland, School of Mechanical and Mining Engineering, ARC Centre of Excellence for Design in Light Metals, Queensland 4072, Australia
*
a)Address all correspondence to these authors. e-mail: yp1975@gmail.com
Get access

Abstract

Al–AlN composite powders containing 9–55 vol%AlN were fabricated in situ by nitriding a powder mixture of AA6061–2% Mg–1% Sn at 560 °C. Transmission electron microscopy (TEM) revealed that the in situ formed AlN reinforcements are present as nanoscale AlN whiskers on each powder particle. The composite powder was consolidated by hot extrusion at 450 °C with an extrusion ratio of 11:1. This produced an AlN-free and an AlN-containing lamellar structure along the extrusion direction. The nanoscale AlN is dispersed in the AlN-containing lamella and shows excellent bonding with the Al matrix, free of decohesion and voids. The lamellar composite containing 9 vol%AlN has an ultimate tensile strength of 332 MPa and tensile elongation of 3%. Composites containing ≥17.5 vol%AlN achieve much higher tensile strengths (538 MPa) but zero tensile elongation. However, they show a low coefficient of thermal expansion up to 450 °C and may therefore have potential for selected elevated temperature applications.

Type
Articles
Copyright
Copyright © Materials Research Society 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Sercombe, T.B. and Schaffer, G.B.: On the role of magnesium and nitrogen in the infiltration of aluminium by aluminium for rapid prototyping applications. Acta Mater. 52, 3019 (2004).CrossRefGoogle Scholar
2.Prin, G.R., Baffie, T., Jeymond, M., and Eustathopoulos, N.: Contact angles and spreading kinetics of Al and Al–Cu alloys on sintered AlN. Mater. Sci. Eng., A 298, 34 (2001).CrossRefGoogle Scholar
3.Kida, M., Bahraini, M., Molina, J.M., Weber, L., and Mortensen, A.: High-temperature wettability of aluminum nitride during liquid metal infiltration. Mater. Sci. Eng., A 495, 197 (2008).CrossRefGoogle Scholar
4.Qian, M., Kondoh, K., Kent, D., Umeda, J., Yu, P., and Schaffer, G.B.: The in situ fabrication of Al-AlN composites from metal powders and their resistance to wear and cavitation. Mater. Sci. Forum 618/619, 617 (2009).CrossRefGoogle Scholar
5.Yu, P., Deng, C.J., Ma, N.G., Yau, M.Y., and Ng, D.H.L.: Formation of nanostructured eutectic network in α-Al2O3 reinforced Al–Cu alloy matrix composite. Acta Mater. 51, 3445 (2003).CrossRefGoogle Scholar
6.Yu, P., Deng, C.J., Ma, N.G., and Ng, D.H.L.: Formation of Al3Ni nanofibers in an Al-based metal matrix composite fabricated by reaction sintering. J. Mater. Res. 19, 1187 (2004).Google Scholar
7.Yu, P., Mei, Z., and Tjong, S.C.: Structure, thermal and mechanical properties of in situ Al-based metal matrix composite reinforced with Al2O3 and TiC submicron particles. Mater. Chem. Phys. 93, 109 (2005).CrossRefGoogle Scholar
8.Feng, C.F. and Froyen, L.: In situ P/M Al/(ZrB2+Al2O3) MMCs: Processing, microstructure and mechanical characterization. Acta Mater. 47, 4571 (1999).CrossRefGoogle Scholar
9.Huang, L.J., Geng, L., Li, A.B., Yang, F.Y., and Peng, H.X.: In situ TiBw/Ti-6Al-4V composites with novel reinforcement architecture fabricated by reaction hot pressing. Scr. Mater. 60, 996 (2000).CrossRefGoogle Scholar
10.Fu, H.M., Wang, H., Zhang, H.F., and Hu, Z.Q.: In situ TiB-reinforced Cu-based bulk metallic glass composites. Scr. Mater. 54, 1961 (2006).CrossRefGoogle Scholar
11.Sudarshan, M.K., Surappa, D.A., and Raj, R.: Nanoceramic-metal matrix composites by in situ pyrolysis of organic precursors in a liquid melt. Metall. Mater. Trans. A 39, 3291 (2008).CrossRefGoogle Scholar
12.Kondoh, K. and Takada, Y.: Tribological property of in situ directly nitrided and sintered Al/AlN composite. Powder Metall. 44, 253 (2000).CrossRefGoogle Scholar
13.Lumley, R.N., Sercombe, T.B., and Schaffer, G.B.: Surface oxide and the role of magnesium during the sintering of aluminium. Metall. Mater. Trans. A 30, 457 (1999).CrossRefGoogle Scholar
14.Qian, M. and Schaffer, G.B.: Sintering of aluminium and its alloys, in Sintering of Advanced Materials, edited by Fang, Z.K. (Woodhead Publishing, Cambridge, 2010), pp. 289322.Google Scholar
15.Sercombe, T.B. and Schaffer, G.B.: On the role of tin in the nitridation of aluminium powder. Scr. Mater. 55, 323 (2006).CrossRefGoogle Scholar
16.Kondoh, K. and Kimura, A.: Surface reaction analysis by X-ray photoelectron spectroscopy using synchrotron radiation and microstructure analysis of AlN layer produced by in situ direct nitriding process. J. Jpn. Soc. Powder Powder Metall. 46, 801 (1999).CrossRefGoogle Scholar
17.Kondoh, K., Umeda, J., and Watanabe, R.: Cavitation resistance of powder metallurgy aluminum matrix composite with AlN dispersoids. Mater. Sci. Eng., A 499, 440 (2009).CrossRefGoogle Scholar
18.Kondoh, K. and Takeda, Y.: Tribological property of in situ directly nitrided and sintered Al/AlN composite. Powder Metall. 43, 69 (2000).CrossRefGoogle Scholar
19.Yu, P., Yan, M., Schaffer, G.B., and Qian, M.: Pressureless infiltration and resulting mechanical properties of Al-AlN preforms fabricated by selective laser sintering and partial nitridation. Metall. Mater. Trans. A 41, 2417 (2010).CrossRefGoogle Scholar
20.Kent, D., Qian, M., and Schaffer, G.B.: Formation of aluminium nitride during sintering of powder injection moulded aluminium. Powder Metall. 53, 118 (2010).CrossRefGoogle Scholar
21.Leyens, C. and Peters, M.: Titanium and Titanium Alloys (Wiley VCH, Darmstadt, 2003).CrossRefGoogle Scholar
22.Cahn, R.W. and Haasen, P.: Physical Metallurgy, 4th ed., Vol. 3 (North-Holland, Amsterdam, 1996), p. 2114.Google Scholar
23.Gustafson, T.W., Panda, P.C., Song, G., and Raj, R.: Influence of microstructural scale on plastic flow behaviour of metal matrix composites. Acta Mater. 45, 1663 (1997).CrossRefGoogle Scholar
24.Ashby, M.F. and Jones, D.R.H.: Engineering Materials, 2nd ed., Vol. 1 (Butterworth, Oxford, 1996), p. 105.Google Scholar