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Hydrothermal synthesis of PbTiO3 films

Published online by Cambridge University Press:  31 January 2011

Woo-Seok Cho  and
Masahiro Yoshimura
Woo-Seok Cho
Affiliation:
Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226, Japan
Masahiro Yoshimura
Affiliation:
Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226, Japan
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Abstract

Well-crystallized polycrystalline films of tetragonal PbTiO3 have been synthesized on Ti metal substrates in concentrated alkaline solutions of Pb(OH)2 containing KOH by the hydrothermal method under saturated vapor pressure (2.0 MPa) at 200 °C. The film microstructure depended strongly on the Pb(OH)2 and KOH concentration. The grain size became larger from approximately 0.6 to 6 μm with an increase of KOH concentration from 1 to 4 M at 0.07 M Pb(OH)2, whereas the grains decreased in size with an increase of Pb(OH)2 concentration at 1 M KOH concentration. PbTiO3 film prepared in the aqueous solution of 0.07 M Pb(OH)2 containing 2 M KOH showed a relative dielectric constant of about 215 and loss of about 5% at 1 kHz.

Type
Articles
Information
Journal of Materials Research , Volume 12 , Issue 3 , March 1997 , pp. 833 - 839
Copyright
Copyright © Materials Research Society 1997

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