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Effects of process variables on properties and composition of a-Si:C:H films

Published online by Cambridge University Press:  31 January 2011

I. L. Moskowitz*
Affiliation:
Center for Advanced Materials Processing, Box 5705, Clarkson University, Potsdam, New York 13699
W. A. Lanford
Affiliation:
Department of Physics, State University of New York at Albany, Albany, New York 12222
S. V. Babu
Affiliation:
Center for Advanced Materials Processing, Box 5705, Clarkson University, Potsdam, New York 13699
*
a) Address all correspondence to this author. e-mail: reach illa@yahoo.com
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Abstract

Physical properties of a-Si:C:H films, including composition, optical constants, microhardness, and surface energy, were investigated. A factorial experimental design was employed to establish the effects of plasma-assisted chemical vapor deposition parameters on the physical properties of the films. The dynamics of the plasma deposition process are discussed in relation to the interactions observed among the process variables and the effects of the variables on the physical properties of the films.

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Articles
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCES

1.Robertson, J., Phys. Rev. Lett. 68, 220 (1992).CrossRefGoogle Scholar
2.Collins, C.B., Davanloo, B., Jander, D.R., Lee, T.J., Park, H., You, J.H., J. Appl. Phys. 69, 7862 (1991).CrossRefGoogle Scholar
3.Angus, J.C. and Wang, Y., in Diamond and Diamond-like Films and Coatings, edited by Clausing, R.E., Horton, L.L., Angus, J.C., and Koidl, P. (Plenum Press, New York, 1991), p. 273.Google Scholar
4.Tsai, H., in Properties and Characterization of Amorphous Carbon Films, edited by Pouch, J.J., Alterovitz, S.A. (Trans. Tech. Publications, Brookfield, MA, 1990).Google Scholar
5.Angus, J.C., Hayman, C.C., and Hoffman, R.W., in Diamond Optics, Proceedings of SPIE (SPIE, Bellingham, WA, 1988), Vol. 969, p. 2.CrossRefGoogle Scholar
6.Kaplan, S., Jansen, F., and Manochkin, M., Appl. Phys. Lett. 47, 750 (1985).CrossRefGoogle Scholar
7.Bedell, S.W. and Lanford, W.A., in Hydrogen in Semiconduction and Metals, edited by Nickel, N.H., Jackson, W.B., Bowman, R.C., and Leisure, R.G. (Mater. Res. Soc. Symp. Proc., Warrendale, PA, 1988), p. 369.Google Scholar
8.Sjostrom, H., Lanford, W., Hjorvarson, B., Xing, K., and Sundgren, J.E., J. Mater. Res. 11, 981 (1996).CrossRefGoogle Scholar
9.Lanford, W.A., in Handbook of Modern Ion Beam Materials Analysis, edited by Tesmer, J.R., Nastasi, M. (MRS, Pittsburgh, PA, 1995), Chap. 8.Google Scholar
10.Musumeci, P., Reitano, R., Calcagno, L., Roccaforte, F., Makhtari, A., and Grimaldi, M.G., Philos. Mag. B 76, 323 (1997).CrossRefGoogle Scholar
11.He, J.L., Hon, M.H., and Chang, L.C., Mater. Chem. Phys. 45, 43 (1996).CrossRefGoogle Scholar
12.Wro´bel, A.M., Wickramanayaka, S., Nakanishi, Y., Hatanaka, Y., Pawowski, S., and Olejniczack, W., Diamond Relat. Mater. 6, 1081 (1997).CrossRefGoogle Scholar
13.Pascual, E., Andu´jar, J.L., Ferna´ndez, J.L., Bertran, E., Diamond Relat. Mater. 4, 702 (1995).CrossRefGoogle Scholar
14.Tawada, Y., Okamoto, H., and Hamakawa, Y., Appl. Phys. Lett. 39, 237 (1981).CrossRefGoogle Scholar
15.McKenzie, D.R., Savvides, N., Hills, D.R., McPhedran, R.C., and Bottun, L.C., Sol. Energy Mater. 9, 113 (1983).CrossRefGoogle Scholar
16.Moskowitz, I. and Babu, S.V., Thin Solid Films 385, 48 (2001).CrossRefGoogle Scholar
17.Tabata, A., Kamijo, H., Suzuoki, Y., and Mizutani, T., J. Non-Cryst. Solids 227–230, 456 (1998).CrossRefGoogle Scholar
18.Wang, L., Xu, J., Ma, T., Li, W., Huang, X., and Chen, K., J. Alloys Compd. 290, 273 (1999).CrossRefGoogle Scholar
19.Han, S.Z., Lee, H.M., Kwon, H-S., J. Non-Cryst. Solids 170, 199 (1994).CrossRefGoogle Scholar
20.Box, G.E.P., Hunter, W.G., and Hunter, J.S., Statistics for Experimenters—An Introduction to Design, Data Analysis and Model Building (John Wiley, New York, 1978), Chap. 10.Google Scholar
21.Rickey, F.A., in Handbook of Modern Ion Beam Materials Analysis, edited by Tesmer, J.R., Nastasi, M. (MRS, Pittsburgh, PA, 1995).Google Scholar
22.Oliver, W.C. and Pharr, G.M., J. Mater. Sci. 7, 1564 (1992).Google Scholar
23.Handbook of Micro/Nanotribology (Mechanics and Materials Science), 2nd ed., edited by Bhushan, B. (CRC, Boca Raton, FL, 1998).Google Scholar
24.Kaelble, D.H., Physical Chemistry of Adhesion (Wiley Interscience, New York, 1971), Chap. 5.Google Scholar
25.Angermann, H., Henrion, W., Ro¨seler, A., Rebien, M., Mater. Sci. Eng. B 73, 178 (2000).CrossRefGoogle Scholar
26.Ling, L. and Shimura, F., J. Appl. Phys. 71, 1237 (1992).CrossRefGoogle Scholar
27.Jellison, G.E. and Modine, F.A., Appl. Phys. Lett. 69, 371 (1996).CrossRefGoogle Scholar
28.Press, W.H., Flannery, B.P., Teukolsky, S.A., and Vetterling, W.T., Numerical Recipies: The Art of Scientific Computing (Cambridge University Press, New York, 1992).Google Scholar
29.Seth, J. and Babu, S.V., Thin Solid Films Lett. 230, 90 (1993).CrossRefGoogle Scholar
30.Basner, R., Foest, R., Schmidt, M., Sigeneger, F., Kurunczi, P., Becker, K., and Deutsch, H., Int. J. Mass Spectrom. Ion Process. 153, 65 (1996).CrossRefGoogle Scholar
31.Chapman, B.N., Glow Discharge Processes (John Wiley, New York 1980).Google Scholar
32.Deutsch, H., Kersten, H., Klagge, S., and Rutscher, A., Contrib. Plasma Phys. 28, 149 (1988).CrossRefGoogle Scholar
33.Kerten, H. and Kroesen, G.M.W., J. Vac. Sci. Technol., A 8, 38 (1990).CrossRefGoogle Scholar
34.Reinke, P., Jacob, W., and Müller, W., J. Appl. Phys. 74, 1354 (1993).CrossRefGoogle Scholar
35.Keudell, A. von and Jacob, W., J. Appl. Phys. 79, 1092 (1996).CrossRefGoogle Scholar
36.DeMartino, C., Demichelis, F., Fusco, G., and Tagliaferro, A., Diamond Relat. Mater. 5, 461 (1996).CrossRefGoogle Scholar
37.Wei, Q., Sharma, A.K., Sankar, J., and Narayan, J., Composites B 30, 675 (1999).CrossRefGoogle Scholar
38.Wei, Q., Narayan, R.J., Narayan, J., Sankar, J., and Sharma, A.K., Mater. Sci. Eng. B 53, 262 (1998).CrossRefGoogle Scholar
39.Memming, R., Thin Solid Films 143, 279 (1986).CrossRefGoogle Scholar
40.Angus, J.C. and Wang, Y., in Diamond and Diamond-like Films and Coatings, edited by Clausing, R.E., Horton, L.L., Angus, J.C., and Koidl, P. (Plenum Press, New York, 1991), p. 273.Google Scholar
41.Paul, S. and , F.J.Clough (MRS Symp. Proc., Warrendale, PA, 1999), p. 149.Google Scholar