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The effect of undercooling and Nd422 phase content on the nucleation of large Nd–Ba–Cu–O grains fabricated by top-seeded melt processing

Published online by Cambridge University Press:  31 January 2011

N. Hari Babu
Affiliation:
Interdisciplinary Research Centre in Superconductivity, University of Cambridge, Madingley Road, Cambridge CB3 0HE, United Kingdom
W. Lo
Affiliation:
Interdisciplinary Research Centre in Superconductivity, University of Cambridge, Madingley Road, Cambridge CB3 0HE, United Kingdom
D. A. Cardwell
Affiliation:
Interdisciplinary Research Centre in Superconductivity, University of Cambridge, Madingley Road, Cambridge CB3 0HE, United Kingdom
Y. Shi
Affiliation:
Interdisciplinary Research Centre in Superconductivity, University of Cambridge, Madingley Road, Cambridge CB3 0HE, United Kingdom
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Abstract

The nucleation and growth of NdBa2Cu3O7–δ (Nd123)–Nd4Ba2Cu2O10 (Nd422) single-grain composites in a controlled 1% O2 in N2 atmosphere were investigated in detail as a function of solidification temperature and Nd422 phase content using a top-seeded melt growth technique. A schematic process phase diagram in the peritectic solidification region of Nd–Ba–Cu–O (NdBCO) was constructed primarily from constant isothermal growth experiments at various temperatures for several compositions and used to fabricate large single-grain material by both isothermal and continuous slow cooling over a limited temperature range. The nucleation at the seed surface and subsequent growth of uniform grains was observed to depend critically on the controlled rate of grain growth and the temperature range over which solidification occurred.

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Articles
Copyright
Copyright © Materials Research Society 1999

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References

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