Hostname: page-component-77c89778f8-9q27g Total loading time: 0 Render date: 2024-07-19T07:07:09.138Z Has data issue: false hasContentIssue false
  • English
  • Français

Effect of FeCl4– intercalation on the transport properties of a graphitized polyimide film

Published online by Cambridge University Press:  03 March 2011

B. Nysten ,
J-P. Issi ,
H. Shioyama ,
M. Crespin ,
R. Setton ,
F. Béguin  and
M. Inagaki
B. Nysten
Affiliation:
Unité de Physico-Chimie et de Physique des Matériaux, Université Catholique de Louvain, place Croix du Sud, 1, B-1348 Louvain-la-Neuve, Belgique
J-P. Issi*
Affiliation:
Unité de Physico-Chimie et de Physique des Matériaux, Université Catholique de Louvain, place Croix du Sud, 1, B-1348 Louvain-la-Neuve, Belgique
H. Shioyama
Affiliation:
Centre de Recherche sur la Matière Divisée, CNRS-Université d'Orléans, 1B, rue de la Férollerie, F-45071 Orléans Cedex 2, France
M. Crespin
Affiliation:
Centre de Recherche sur la Matière Divisée, CNRS-Université d'Orléans, 1B, rue de la Férollerie, F-45071 Orléans Cedex 2, France
R. Setton
Affiliation:
Centre de Recherche sur la Matière Divisée, CNRS-Université d'Orléans, 1B, rue de la Férollerie, F-45071 Orléans Cedex 2, France
F. Béguin
Affiliation:
Centre de Recherche sur la Matière Divisée, CNRS-Université d'Orléans, 1B, rue de la Férollerie, F-45071 Orléans Cedex 2, France
M. Inagaki
Affiliation:
Faculty of Engineering, Hokkaido University, Kita-ku, Sapporo, 060 Japan
*
a)Author to whom correspondence should be addressed.
Get access

Abstract

The temperature variation of the thermal conductivity, the electrical resistivity, and the thermoelectric power of a graphitized polyimide film have been measured in the temperature range 2 < T < 300 K. The effect of the electrochemical intercalation with FeCl4− ions has also been studied. The thermal conductivity measurements confirm the high degree of graphitization that may be obtained with polyimide films. They show how intercalation increases the structural disorder and how the intercalate substantially contributes to the thermal conductivity at low temperatures. The electrical-resistivity and thermoelectric-power measurements reveal that the density of free carriers is about three times lower in stage-2 FeCl4− solvated intercalation compounds obtained by an electrochemical way than in stage-2 FeCl3 compounds obtained by a classical synthesis method.

Type
Articles
Information
Journal of Materials Research , Volume 8 , Issue 9 , September 1993 , pp. 2299 - 2304
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1J-P. Issi, Heremans, J., and Dresselhaus, M. S., Phys. Rev. B 27, 1333 (1983).Google Scholar
2Issi, J-P., Piraux, L., and Nysten, B., J. Phys. D: Appl. Phys. 20, 257 (1987).CrossRefGoogle Scholar
3Nysten, B., Issi, J-P., Barton, R., Boyington, D. R., and Lavin, J. G., Phys. Rev. B 44, 2142 (1991).CrossRefGoogle Scholar
4Burger, A., Fitzer, E., Heim, M., and Terwiesch, B., Carbon 13, 149 (1975); Inagaki, M., Harada, S., Sato, T., Nakajima, T., Horino, Y., and Morita, K., Carbon 27, 253 (1989).CrossRefGoogle Scholar
5Hishiyama, Y., Yasadu, S., Yoshida, A., and Inagaki, M., J. Mater. Sci. 23, 3272 (1988); Hishiyama, Y., Yoshida, A., Kaburagi, Y., and Inagaki, M., Carbon 30, 333 (1992); Hatori, H., Yamada, Y., and Shiraishi, M., Carbon 30, 763 (1992).CrossRefGoogle Scholar
6Inagaki, M., Meng, L-J., Ibuki, T., Sakai, M., and Hishiyama, Y., Carbon 29, 1239 (1991).CrossRefGoogle Scholar
7Bourgerette, C., Oberlin, A., and Inagaki, M., J. Mater. Res. 7, 1158 (1992).CrossRefGoogle Scholar
8Shioyama, H., Crespin, M., Setton, R., and Béguin, F., Carbon 29, 1055 (1991); Shioyama, H., Crespin, M., Seron, A., Setton, R., Bonnin, D., and Beguin, F., Carbon 31, 223 (1993).CrossRefGoogle Scholar
9Piraux, L., Issi, J-P., and Coopmans, P., Measurement 5, 2 (1987).CrossRefGoogle Scholar
10Klein, C. A., StrauB, W. D., and Diefendorf, R. J., Phys. Rev. 125, 468 (1962).CrossRefGoogle Scholar
11Piraux, L., Nysten, B., Haquenne, A., Issi, J-P., Dresselhaus, M. S., and Endo, M., Solid State Commun. 50, 697 (1984).CrossRefGoogle Scholar
12Nysten, B., Microstructure and Transport Properties: Carbon Fibres, Ph.D. Thesis, Unité PCPM, Universite Catholique de Louvain, Louvain-la-Neuve, Belgium, 1991 (in French).Google Scholar
13Nysten, B., Piraux, L., and Issi, J-P., Synth. Metals 12, 505 (1985).CrossRefGoogle Scholar
14Piraux, L., Issi, J-P., Marêché, J-F., and McRae, E., Synth. Metals 30, 245 (1989).CrossRefGoogle Scholar
15Marêché, J-F., McRae, E., Nadi, N. E., and Vangelisti, R., Synth. Metals 8, 163 (1983); Nadi, N. E., McRae, E., Marêché, J-F., Lelaurain, M., and Hérold, A., Carbon 24, 695 (1986).CrossRefGoogle Scholar
16Issi, J-P. and Piraux, L., Annales Phys. 11, 165 (1986).Google Scholar
17Takezawa, T., Tsuzuku, T., Ono, A., and Hishiyama, Y., Philos. Mag. 19, 623 (1969); Jay-Gerin, J. P. and Maynard, R., J. Low Temp. Phys. 3, 377 (1970).CrossRefGoogle Scholar
18Klein, C. A., J. Appl. Phys. 35, 2947 (1964).CrossRefGoogle Scholar
19Issi, J-P., Boxus, J., Poulaert, B., Mazurek, H., and Dresselhaus, M. S., J. Phys. C: Solid State Phys. 14, L307 (1981); Elzinga, M., Morelli, D. T., and Uher, C., Phys. Rev. B 26, 3312 (1982); Issi, J-P., Kinany-Alaoui, M., Michenaud, J-P., and Piraux, L., in Extended Abstracts No. 16, Graphite Intercalation Compounds: Science and Applications, edited by Endo, M., Dresselhaus, M. S., and Dresselhaus, G. (Materials Research Society, Pittsburgh, PA, 1988), p. 117; Issi, J-P., in Graphite Intercalation Compounds II: Transport and Electronic Properties, Springer Series in Materials Science, edited by Zabel, H. and Solin, S. A. (Springer, Berlin, 1992), Vol. 18, pp. 195–245.CrossRefGoogle Scholar
20Ziman, J. M., Electrons and Phonons (Clarendon, Oxford, 1960).Google Scholar
21Blinowski, J., Han, Nguyen Hy, Rigaux, C., Vieren, J-P., Le Toullec, R., Furdin, G., Hérold, A., and Mélin, J., J. Physique 41, 47 (1980).CrossRefGoogle Scholar
22Piraux, L., Kinany-Alaoui, M., Issi, J-P., Perignon, A., Pernot, P., and Vangelisti, R., Phys. Rev. B 38, 4329 (1988).CrossRefGoogle Scholar
23Piraux, L., Conduction, Interaction and Weak Localization in Graphite Intercalation Compounds, Ph.D. Thesis, Unité PCPM, Université Catholique de Louvain, Louvain-la-Neuve, Belgium, 1987 (in French).Google Scholar