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Application of novel ionic liquids for reverse atom transfer radical polymerization of methacrylonitrile without any additional ligand

Published online by Cambridge University Press:  31 January 2011

Hou Chen ,
Yanfeng Meng ,
Ying Liang ,
Zixuan Lu  and
Pingli Lv
Hou Chen*
Affiliation:
School of Chemistry and Materials Science, Ludong University, Yantai 264025, People’s Republic of China
Pingli Lv
Affiliation:
School of Chemistry and Materials Science, Ludong University, Yantai 264025, People’s Republic of China
*
a) Address all correspondence to this author. e-mail: sdchenhou@hotmail.com
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Abstract

Reverse atom transfer radical polymerization of methacrylonitrile (MAN) initiated by azobisisobutyronitrile (AIBN) was approached for the first time in the absence of any ligand in four novel ionic liquids, 1-methylimidazolium acetate ([mim][AT]), 1-methylimidazolium butyrate ([mim][BT]), 1-methylimidazolium caproate ([mim][CT]), and 1-methylimidazolium heptylate ([mim][HT]). The polymerization in [mim][AT] not only showed the best control of molecular weight and its distribution but also provided a more rapid reaction rate with the ratio of [MAN]:[FeCl3]:[AIBN] at 300:2:1. The block copolymer PMAN-b-PSt was obtained via a conventional ATRP process in [mim][AT] by using the resulting PMAN as a macroinitiator. After simple purification, [mim][AT] and FeCl3 could be easily recycled and reused and had no effect on the living nature of reverse atom transfer radical polymerization of MAN.

Keywords

KineticsPolymerPolymerization
Type
Articles
Information
Journal of Materials Research , Volume 24 , Issue 5 , May 2009 , pp. 1880 - 1885
Copyright
Copyright © Materials Research Society 2009

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