Hostname: page-component-8448b6f56d-42gr6 Total loading time: 0 Render date: 2024-04-19T18:41:25.126Z Has data issue: false hasContentIssue false
  • English
  • Français

Advanced mechanical properties of powder metallurgy commercially pure titanium with a high oxygen concentration

Published online by Cambridge University Press:  22 August 2017

Biao Chen ,
Jianghua Shen Open the ORCID record for Jianghua Shen [Opens in a new window] ,
Xiaoxin Ye ,
Junko Umeda  and
Katsuyoshi Kondoh
Biao Chen*
Affiliation:
Joining and Welding Research Institute, Osaka University, Ibaraki City, Osaka 567-0047, Japan
Jianghua Shen*
Affiliation:
Joining and Welding Research Institute, Osaka University, Ibaraki City, Osaka 567-0047, Japan
Xiaoxin Ye
Affiliation:
Joining and Welding Research Institute, Osaka University, Ibaraki City, Osaka 567-0047, Japan
Junko Umeda
Affiliation:
Joining and Welding Research Institute, Osaka University, Ibaraki City, Osaka 567-0047, Japan
Katsuyoshi Kondoh
Affiliation:
Joining and Welding Research Institute, Osaka University, Ibaraki City, Osaka 567-0047, Japan
*
a) Address all correspondence to this author. e-mail: shen-j@jwri.osaka-u.ac.jp, j_shen@live.cn
Get access

Abstract

Oxygen is known to have a significant impact on the strength of Ti alloys, whereas it can also reduce the ductility substantially. Thus, the usage of oxygen to strengthen Ti is restricted in the industry. In this study, we rekindled the research of oxygen behavior in Ti with the purpose of developing Ti alloys with high strength and suitable ductility by using no expensive and poisonous element. To this end, experiments of producing high performance commercially pure Ti using only oxygen solid solution were carried out. The oxygen element was introduced into the Ti by two different powder metallurgy methods. The microstructural examination and mechanical test were performed for the samples, which indicated a strong hardening effect of oxygen in spite of the processing routes. Most importantly, the results suggested that a high elongation to failure of over 20% can still be obtained in the samples having yield stress over 800 MPa, up to an oxygen content of 0.8 wt%, which is far beyond the previously recognized limit.

Keywords

pure Tioxygenpowder metallurgymechanical properties
Type
Invited Paper
Information
Journal of Materials Research , Volume 32 , Issue 19 , 16 October 2017 , pp. 3769 - 3776
Check for updates
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

b)

These authors contributed equally to this work.

Contributing Editor: Jürgen Eckert

References

REFERENCES

Banerjee, D. and Williams, J.C.: Perspectives on titanium science and technology. Acta Mater. 61, 844–879 (2013).CrossRefGoogle Scholar
Geetha, M., Singh, A.K., Asokamani, R., and Gogia, A.K.: Ti based biomaterials, the ultimate choice for orthopaedic implants—A review. Prog. Mater. Sci. 54, 397–425 (2009).Google Scholar
Bewlay, B.P., Weimer, M., Kelly, T., Suzuki, A., and Subramanian, P.R.: The science, technology, and implementation of TiAl alloys in commercial aircraft engines. MRS Online Proc. Libr. 1516, 49–58 (2013).CrossRefGoogle Scholar
Chen, G., Peng, Y., Zheng, G., Qi, Z., Wang, M., Yu, H., Dong, C., and Liu, C.T.: Polysynthetic twinned TiAl single crystals for high-temperature applications. Nat. Mater. 15, 876–881 (2016).CrossRefGoogle ScholarPubMed
Khorasani, A.M., Goldberg, M., Doeven, E.H., and Littlefair, G.: Titanium in biomedical applications-properties and fabrication: A review. J. Biomater. Tissue Eng. 5, 593–619 (2015).Google Scholar
Özcan, M. and Hämmerle, C.: Titanium as a reconstruction and implant material in dentistry: Advantages and pitfalls. Materials 5, 1528 (2012).Google Scholar
Kuroda, D., Niinomi, M., Morinaga, M., Kato, Y., and Yashiro, T.: Design and mechanical properties of new β type titanium alloys for implant materials. Mater. Sci. Eng., A 243, 244–249 (1998).Google Scholar
Kang, L.M., Yang, C., Wang, F., Li, X.X., Zhu, D.Z., Zhang, W.W., Chen, W.P., and Huan, Y.: Designing ultrafine lamellar eutectic structure in bimodal titanium alloys by semi-solid sintering. J. Alloys Compd. 702, 51–59 (2017).CrossRefGoogle Scholar
Boyer, R.R.: An overview on the use of titanium in the aerospace industry. Mater. Sci. Eng., A 213, 103–114 (1996).Google Scholar
Williams, J.C. and Starke, E.A. Jr.: Progress in structural materials for aerospace systems. Acta Mater. 51, 5775–5799 (2003).Google Scholar
Williams, J.C., Sommer, A.W., and Tung, P.P.: The influence of oxygen concentration on the internal stress and dislocation arrangements in α titanium. Metall. Trans. 3, 2979–2984 (1972).Google Scholar
Conrad, H.: Effect of interstitial solutes on the strength and ductility of titanium. Prog. Mater. Sci. 26, 123–403 (1981).Google Scholar
Ouchi, C., Iizumi, H., and Mitao, S.: Effects of ultra-high purification and addition of interstitial elements on properties of pure titanium and titanium alloy. Mater. Sci. Eng., A 243, 186–195 (1998).Google Scholar
Lefebvre, L-P., Baril, E., and de Camaret, L.: The effect of oxygen, nitrogen and carbon on the microstructure and compression properties of titanium foams. J. Mater. Res. 28, 2453–2460 (2013).Google Scholar
Yu, Q., Qi, L., Tsuru, T., Traylor, R., Rugg, D., Morris, J.W., Asta, M., Chrzan, D.C., and Minor, A.M.: Origin of dramatic oxygen solute strengthening effect in titanium. Science 347, 635–639 (2015).Google Scholar
Jaffee, R.I., Ogden, H.R., and Maykuth, D.J.: Alloys of titanium with carbon, oxygen and nitrogen. Trans. AIME 188, 1261–1266 (1950).Google Scholar
Yan, M., Xu, W., Dargusch, M.S., Tang, H.P., Brandt, M., and Qian, M.: Review of effect of oxygen on room temperature ductility of titanium and titanium alloys. Powder Metall. 57, 251–257 (2014).Google Scholar
Yan, M., Dargusch, M.S., Ebel, T., and Qian, M.: A transmission electron microscopy and three-dimensional atom probe study of the oxygen-induced fine microstructural features in as-sintered Ti–6Al–4V and their impacts on ductility. Acta Mater. 68, 196–206 (2014).Google Scholar
Sun, B., Li, S., Imai, H., Mimoto, T., Umeda, J., and Kondoh, K.: Fabrication of high-strength Ti materials by in-process solid solution strengthening of oxygen via P/M methods. Mater. Sci. Eng., A 563, 95–100 (2013).CrossRefGoogle Scholar
Katsuyoshi, K., Sun, B., Li, S., Hisashi, I., and Junko, U.: Experimental and theoretical analysis of nitrogen solid-solution strengthening of PM titanium. Anglais 50, 35–40 (2014).Google Scholar
Mimoto, T., Umeda, J., and Kondoh, K.: Titanium powders via gas-solid direct reaction process and mechanical properties of their extruded materials. Mater. Trans. 56, 1153–1158 (2015).CrossRefGoogle Scholar
Joost, W.J., Ankem, S., and Kuklja, M.M.: Interaction between oxygen interstitials and deformation twins in alpha-titanium. Acta Mater. 105, 44–51 (2016).Google Scholar
Lederich, R.J., Sastry, S.M.L., O’Neal, J.E., and Rath, B.B.: The effect of grain size on yield stress and work hardening of polycrystalline titanium at 295 and 575 K. Mater. Sci. Eng. 33, 183–188 (1978).Google Scholar
Li, Y.K., Liu, F., Zheng, G.P., Pan, D., Zhao, Y.H., and Wang, Y.M.: Strength scaling law, deformation kinetics and mechanisms of nanostructured Ti. Mater. Sci. Eng., A 573, 141–147 (2013).Google Scholar
Supplementary material: Image

Chen supplementary material 1

Supplementary Figure

Download Chen supplementary material 1(Image)
Image 9.5 MB
Supplementary material: Image

Chen supplementary material 2

Supplementary Figure

Download Chen supplementary material 2(Image)
Image 9.5 MB