Hostname: page-component-76fb5796d-vvkck Total loading time: 0 Render date: 2024-04-26T12:40:25.689Z Has data issue: false hasContentIssue false

The ‘easily reducible’ manganese of soils

Published online by Cambridge University Press:  27 March 2009

H. G. Dion
Affiliation:
A.R.C. Unit of Soil Metabolism and Chemistry Department, Rothamsted Experimental Station, Harpenden, Herts
P. J. G. Mann
Affiliation:
A.R.C. Unit of Soil Metabolism and Chemistry Department, Rothamsted Experimental Station, Harpenden, Herts
S. G. Heintze
Affiliation:
A.R.C. Unit of Soil Metabolism and Chemistry Department, Rothamsted Experimental Station, Harpenden, Herts

Extract

1. In studying the factors influencing the ‘easily reducible’ manganese in soils, results were obtained to indicate that the estimation is dependent on the pH of the system, the nature of the salt solution, the nature of the reducing agent and the time of contact, in addition to the amount and nature of the higher oxides of manganese present.

2. Pyrolusite (MnO2) and a synthetic preparation of manganite hydroxide are ‘easily reducible’ oxides, while manganite (MnO(OH)) and naturally occurring hausmannite (Mn Mn2O4) are apparently ‘difficultly reducible’ forms.

3. Since pyrolusite occurs in the easily reducible fraction, those deficient soils which contain only a small proportion of their manganese in the easily reducible form must contain the larger part in a form less reactive than pyrolusite.

Type
Research Article
Copyright
Copyright © Cambridge University Press 1947

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Dion, H. G. & Mann, P. J. G. (1946). J. Agric. Sci. 36, 239.CrossRefGoogle Scholar
Heintze, S. G. (1938). J. Agric. Sci. 28, 175.CrossRefGoogle Scholar
Heintze, S. G. (1946). J. Agric. Sci. 36, 227.CrossRefGoogle Scholar
Leeper, G. W. (1935). Proc. Roy. Soc. Vict. 47 (n.s.), 225.Google Scholar
Leeper, G. W. (1939). Proc. Roy. Soc. Vict. 52 (n.s.), 138.Google Scholar
Mann, P. J. G. & Quastel, J. H. (1946). Nature, Lond., 158, 154.Google Scholar
Meyer, J. & Nehrlich, R. (1921). Z. anorg. Chem. 116, 117.CrossRefGoogle Scholar
Naftel, J. A. (1934). Soil Res. 4, 41.Google Scholar
Sherman, G. D. & Harmer, P. M. (1942). Soil Sci. Soc. Amer. Proc. 7, 398.CrossRefGoogle Scholar
Willard, H. H. & Greathouse, L. H. (1917). J. Amer. Chem. Soc. 39, 2366.CrossRefGoogle Scholar