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A Palaeoproterozoic basement beneath the Rangnim Massif revealed by the in situ U–Pb ages and Hf isotopes of xenocrystic zircons from Triassic kimberlites of North Korea

  • Yu-Sheng Zhu (a1) (a2), Jin-Hui Yang (a1) (a2) (a3), Hao Wang (a1) (a2) and Fu-Yuan Wu (a1) (a2) (a3)


In situ U–Pb and Hf analyses were used for crustal zircon xenocrysts from Triassic kimberlites exposed in the Rangnim Massif of North Korea to identify components of the basement hidden in the deep crust of the Rangnim Massif and to clarify the crustal evolution of the massif. The U–Pb age spectrum of the zircons has a prominent population at 1.9–1.8 Ga and a lack of Archaean ages. The data indicate that the deep crust and basement beneath the Rangnim Massif are predominantly of Palaeoproterozoic age, consistent with the ages of widely exposed Palaeoproterozoic granitic rocks. In situ zircon Hf isotope data show that most of the Palaeoproterozoic zircon xenocrysts have negative ϵHf(t) values (−9.7 to +0.7) with an average Hf model age of 2.86 ± 0.02 Ga (2σ), which suggests that the Palaeoproterozoic basement was not juvenile but derived from the reworking of Archaean rocks. Considering the existence of Archaean remanent material in the Rangnim Massif and their juvenile features, a strong crustal reworking event is indicated at 1.9–1.8 Ga, during which time the pre-existing Archaean basement was exhausted and replaced by a newly formed Palaeoproterozoic basement. These features suggest that the Rangnim Massif constitutes the eastern extension of the Palaeoproterozoic Liao–Ji Belt of the North China Craton instead of the Archaean Liaonan Block as previously thought. A huge Palaeoproterozoic orogen may exist in the eastern margin of the Sino-Korean Craton.


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Allsopp, HL, Bristow, JW, Smith, CB, Brown, R, Gleadow, AJW, Kramers, JD and Garvie, OG (1989) A summary of radiometric dating methods applicable to kimberlite and related rocks. In Kimberlite and Related Rocks: Their Composition, Occurence, Origin and Emplacement (ed. Ross, JL), pp. 343–57. Oxford: Blackwell Scientific Publications.
Andersen, T (2002) Correction of common lead in U–Pb analyses that do not report 204Pb. Chemical Geology 192, 5979.
Ashchepkov, IV, Rotman, AY, Somov, SV, Afanasiev, VP, Downes, H, Logvinova, AM, Nossyko, S, Shimupi, J, Palessky, SV, Khmelnikova, OS and Vladykin, NV (2012) Composition and thermal structure of the lithospheric mantle beneath kimberlite pipes from the Catoca cluster, Angola. Tectonophysics 530–1, 128–51.
Bai, J (1993) The Precambrian Geology and Pb-Zn Mineralization in the Norhern Margin of North China Platform. Beijing: Geological Publishing House.
Ballard, JR, Palin, JM, Williams, IS, Campbell, IH and Faunes, A (2001) Two ages of porphyry intrusion resolved for the super-giant Chuquicamata copper deposit of northern Chile by ELA-ICP-MS and SHRIMP. Geology 29, 383–6.
Batumike, JM, O’Reilly, SY, Griffin, WL and Belousova, EA (2007) U–Pb and Hf-isotope analyses of zircon from the Kundelungu Kimberlites, D.R. Congo: implications for crustal evolution. Precambrian Research 156, 195225.
Belousova, EA, Griffin, WL, O’Reilly, SY and Fisher, NI (2002) Igneous zircon: trace element composition as an indicator of source rock type. Contributions to Mineralogy and Petrology 143, 602–22.
Belousova, EA, Griffin, WL and Pearson, NJ (1998) Trace element composition and cathodoluminescence properties of southern African kimberlitic zircons. Mineralogical Magazine 62, 355–66.
Belousova, EA, Griffin, WL, Shee, SR, Jackson, SE and O’Reilly, SY (2001) Two age populations of zircons from the Timber Creek kimberlites, Northern Territory, as determined by laser-ablation ICP-MS analysis. Australian Journal of Earth Sciences 48, 757–65.
Chang, EZ (1996) Collisional orogene between north and south China and its eastern extension in the Korean Peninsula. Journal of Southeast Asian Earth Sciences 13, 267–77.
Chang, KH and Park, SO (2001) Paleozoic Yellow Sea transform fault: its role in the tectonic history of Korea and adjacent regions. Gondwana Research 4, 588–9.
Cherniak, DJ, Hanchar, JM and Watson, EB (1997a) Diffusion of tetravalent cations in zircon. Contributions to Mineralogy and Petrology 127, 383–90.
Cherniak, DJ, Hanchar, JM and Watson, EB (1997b) Rare-earth diffusion in zircon. Chemical Geology 134, 289301.
Cluzel, D, Lee, BJ and Cadet, JP (1991) Indosinian dextral ductile fault system and synkinematic plutonism in the southwest of the Ogcheon belt (South Korea). Tectonophysics 194, 131–51.
Corfu, F, Hanchar, JMHoskin, PWO and Kinny, P (2003) Atlas of zircon textures. Reviews in Mineralogy and Geochemistry 53, 469500.
Donatti-Filho, JP, Oliveira, EP and McNaughton, NJ (2013) Provenance of zircon xenocrysts in the Neoproterozoic Brauna Kimberlite Field, São Francisco Craton, Brazil: evidence for a thick Palaeoproterozoic lithosphere beneath the Serrinha block. Journal of South American Earth Sciences 45, 8396.
Elhlou, S, Belousova, E, Griffin, WL, Pearson, NJ and O’Reilly, SY (2006) Trace element and isotopic composition of GJ-red zircon standard by laser ablation. Geochimica et Cosmochimica Acta 70, A158.
Ernst, WG and Liou, JG (1995) Contrasting plate-tectonic styles of the Qinling-Dabie-Sulu and Franciscan metamorphic belts. Geology 23, 353–6.
Faure, M, Lin, W, Monié, P and Bruguier, O (2004) Palaeoproterozoic arc magmatism and collision in Liaodong Peninsula (north-east China). Terra Nova 16, 7580.
Griffin, WL, O’Reilly, SY and Ryan, CG (1999) The composition and origin of sub-continental lithospheric mantle. In Mantle Petrology: Field Observations and High-pressure Experimentation: A tribute to Francis R. (Joe) Boyd (eds Fei, Y, Bertka, CM and Mysen, BO), pp. 1345. Houston: The Geochemical Society, Special Publication 6.
Griffin, WL, Pearson, NJ, Belousova, E, Jackson, SE, Van Achterbergh, E, O’Reilly, SY and Shee, SR (2000) The Hf isotope composition of cratonic mantle: LAM-MC-ICPMS analysis of zircon megacrysts in kimberlites. Geochimica et Cosmochimica Acta 64, 133–47.
Grimes, CB, John, BE, Kelemen, PB, Mazdab, FK, Wooden, JL, Cheadle, MJ, Hanghøj, K and Schwartz, JJ (2007) Trace element chemistry of zircons from oceanic crust: a method for distinguishing detrital zircon provenance. Geology 35, 643–6.
Hoskin, PWO and Black, LP (2000) Metamorphic zircon formation by solid-state recrystallization of protolith igneous zircon. Journal of Metamorphic Geology 18, 423–39.
Hu, B, Zhai, M, Li, T, Li, Z, Peng, P, Guo, J and Kusky, TM (2012) Mesoproterozoic magmatic events in the eastern North China Craton and their tectonic implications: geochronological evidence from detrital zircons in the Shandong Peninsula and North Korea. Gondwana Research 22, 828–42.
Huang, JQ (1977) Basic outline of China tectonics. Acta Geologica Sinica 52, 117–35 (in Chinese).
Jackson, SE, Pearson, NJ, Griffin, WL and Belousova, EA (2004) The application of laser ablation-inductively coupled plasma-mass spectrometry to in situ U-Pb zircon geochronology. Chemical Geology 211, 4769.
Kelley, SP and Wartho, JA (2000) Rapid kimberlite ascent and the significance of Ar-Ar ages in xenolith phlogopites. Science 289, 609–11.
Kemp, AIS, Hawkesworth, CJ, Paterson, BA and Kinny, PD (2006) Episodic growth of the Gondwana supercontinent from hafnium and oxygen isotopes in zircon. Nature 439, 580–83.
Kim, JN, Han, RY, Zhao, L, Li, QL and Kim, S (2016) Study on the petrographic and SIMS zircon U-Pb geochronological characteristics of the magmatic rocks and associated with the Jongju and Cholsan REE deposits in northern Korean Peninsula. Acta Petrologica Sinica 32, 3123–38 (in Chinese with English abstract).
Kim, SW, Oh, CW, Williams, IS, Rubatto, D, Ryu, I-C, Rajesh, VJ, Kim, CB, Guo, J and Zhai, M (2006) Phanerozoic high-pressure eclogite and intermediate-pressure granulite facies metamorphism in the Gyeonggi Massif, South Korea: implications for the eastward extension of the Dabie–Sulu continental collision zone. Lithos 92, 357–77.
Kinny, PD and Maas, R (2003) Lu-Hf and Sm-Nd isotope systems in zircon. In Zircon (eds Hanchar, JM and Hoskin, PWO), pp. 327–39. Washington: Reviews in Mineralogy and Geochemistry.
Kostrovitsky, SI, Skuzovatov, SY, Yakovlev, DA, Sun, J, Nasdala, L and Wu, F-Y (2016) Age of the Siberian craton crust beneath the northern kimberlite fields: insights to the craton evolution. Gondwana Research 39, 365–85.
Krasnobayev, AA (1980) Mineralogical-geochemical features of zircons from kimberlites and problems of their origin. International Geology Review 22, 1199–209.
Kresten, P, Fels, P and Berggren, G (1975) Kimberlitic zircons — A possible aid in prospecting for kimberlites. Mineralium Deposita 10, 4756.
Kwon, S, Sajeev, K, Mitra, G, Park, Y, Kim, SW and Ryu, IC (2009) Evidence for Permo-Triassic collision in Far East Asia: the Korean collisional orogen. Earth and Planetary Science Letters 279, 340–9.
LBGMR (Liaoning Bureau of Geology and Mineral Resources). (1989) Regional Geology of Liaoning Province. Beijing: Geological Publishing House, pp. 856.
Li, QL, Wu, FY, Li, XH, Qiu, ZL, Liu, Y, Yang, YH and Tang, GQ (2011) Precisely dating Paleozoic kimberlites in the North China Craton and Hf isotopic constraints on the evolution of the subcontinental lithospheric mantle. Lithos 126, 127–34.
Li, SZ and Zhao, GC (2007) SHRIMP U–Pb zircon geochronology of the Liaoji granitoids: constraints on the evolution of the Paleoproterozoic Jiao-Liao-Ji belt in the Eastern Block of the North China Craton. Precambrian Research 158, 1–16.
Li, Z, Ni, LM and Xu, JQ (2016) The upper Proterozoic-Paleozoic records of sedimentary sequences and detrital zircon geochronology in Korean Peninsula and North China. Acta Petrologica Sinica 32, 3139–54 (in Chinese with English abstract).
Liu, FL, Liu, PH, Wang, F, Liu, CH and Cai, J (2015) Progresses and overviews of voluminous meta-sedimentary series within the Paleoproterozoic Jiao-Liao-Ji oeogenic/mobile belt, North China Craton. Acta Petrologica Sinica 31, 2816–46 (in Chinese with English abstract).
Lu, XP, Wu, FY, Guo, JH, Wilde, SA, Yang, JH, Liu, XM and Zhang, XO (2006) Zircon U–Pb geochronological constraints on the Paleoproterozoic crustal evolution of the Eastern block in the North China Craton. Precambrian Research 146, 138–64.
Ludwig, KR (2003) ISOPLOT 3.0: a Geochronological Toolkit for Microsoft Excel. Berkeley: Berkeley Geochronology Center, Special Publications 4.
Luo, Y, Sun, M, Zhao, GC, Li, SZ, Xu, P, Ye, K and Xia, XP (2004) LA-ICP-MS U–Pb zircon ages of the Liaohe Group in the Eastern Block of the North China Craton: constraints on the evolution of the Jiao-Liao-Ji Belt. Precambrian Research 134, 349–71.
Luo, Y, Sun, M, Zhao, G, Li, S, Ayers, JC, Xia, X and Zhang, J (2008) A comparison of U–Pb and Hf isotopic compositions of detrital zircons from the North and South Liaohe Groups: constraints on the evolution of the Jiao-Liao-Ji Belt, North China Craton. Precambrian Research 163, 279306.
Metcalfe, I (2006) Palaeozoic and Mesozoic tectonic evolution and palaeogeography of East Asian crustal fragments: the Korean Peninsula in context. Gondwana Research 9, 2446.
Mitchell, RH (1986) Kimberlites: Minerology, Geochemistry, and Petrology. New York: Plenum Press, pp. 442.
Oh, CW (2006) A new concept on tectonic correlation between Korea, China and Japan: histories from the late Proterozoic to Cretaceous. Gondwana Research 9, 4761.
Oh, CW, Imayama, T, Lee, SY, Yi, S-B, Yi, K and Lee, BC (2015) Permo-Triassic and Paleoproterozoic metamorphism related to continental collision in Yangpyeong, South Korea. Lithos 216–7, 264–84.
Paek, RJ, Kang, HG and Jon, GP (1996) Geology of Korea. Pyongyang: Foreign Languages Books Publishing House, 619 p.
Parrish, RR and Reichenbach, I (1991) Age of xenocrystic zircon from diatremes of western Canada. Canadian Journal of Earth Sciences 28, 1232–8.
Peng, P, Wang, C, Yang, JH and Kim, JN (2016) A preliminary study on the rock series and tectonic environment of the ~1.9 Ga plutonic rocks in DPR Korea. Acta Petrologica Sinica 32, 29933018 (in Chinese with English abstract).
Peng, P, Zhai, MG, Li, Q, Wu, F, Hou, Q, Li, Z, Li, T and Zhang, Y (2011) Neoproterozoic (~900Ma) Sariwon sills in North Korea: geochronology, geochemistry and implications for the evolution of the south-eastern margin of the North China Craton. Gondwana Research 20, 243–54.
Qiao, XF and Zhang, AD (2002) North China block, Jiao-Liao-Korea block and Tanlu fault. Geology in China 29, 337–45 (in Chinese with English abstract).
Ree, JH, Cho, M, Kwon, ST and Nakamura, E (1996) Possible eastward extension of Chinese collision belt in South Korea: the Imjingang belt. Geology 24, 1071–4.
Robles-Cruz, SE, Escayola, M, Jackson, S, Galí, S, Pervov, V, Watangua, M, Gonçalves, A and Melgarejo, JC (2012) U–Pb SHRIMP geochronology of zircon from the Catoca kimberlite, Angola: implications for diamond exploration. Chemical Geology 310–11, 137–47.
Rollinson, H. 1997. Eclogite xenoliths in west African kimberlites as residues from Archaean granitoid crust formation. Nature 389, 173–76.
Rubatto, D (2002) Zircon trace element geochemistry: distribution coefficents and the link between U-Pb ages and meramorphism. Chemical Geology 184, 123–38.
Smith, CB (1983) Pb, Sr and Nd isotopic evidence for sources of southern African Cretaceous kimberlites. Nature 304, 51–4.
Sparks, RSJ (2013) Kimberlite Volcanism. Annual Review of Earth and Planetary Sciences 41, 497528.
Sun, J, Liu, CZTappe, S, Kostrovitsky, SI, Wu, FY, Yakovlev, D, Yang, YH and Yang, JH (2014) Repeated kimberlite magmatism beneath Yakutia and its relationship to Siberian flood volcanism: insights from in situ U–Pb and Sr–Nd perovskite isotope analysis. Earth and Planetary Science Letters 404, 283–95.
Sun, J, Tappe, S, Kostrovitsky, SI, Liu, CZ, Skuzovatov, SY and Wu, FY (2018) Mantle sources of kimberlites through time: A U-Pb and Lu-Hf isotope study of zircon megacrysts from the Siberian diamond fields. Chemical Geology 479, 228–40.
Sun, SS and McDonough, WF (1989) Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. In Magmatisn in the Ocean Basins (eds Saunders, AD and Norry, MJ), pp. 313–45. London: Geological Society, Special Publication no. 42.
Valley, JW, Kinny, PD, Schulze, DJ and Spicuzza, MJ (1998) Zircon megacrysts from kimberlite: oxygen isotope variability among mantle melts. Contributions to Mineralogy and Petrology 133, 111.
Wang, HC, Ren, YW, Lu, SN, Kang, JL, Chu, H and Yu, HB (2015) Stratigraphic units and tectonic setting of the Paleoproterozoic Liao-Ji Orogen. Acta Geologica Sinica 36, 583–98 (in Chinese with English abstract).
Woodhead, J, Hergt, J, Shelley, M, Eggins, S and Kemp, R (2004) Zircon Hf-isotope analysis with an excimer laser, depth profiling, ablation of complex geometries, and concomitant age estimation. Chemical Geology 209, 121–35.
Wu, FY, Han, RH, Yang, JH, Wilde, SA, Zhai, MG and Park, SC (2007a) Initial constraints on the timing of granitic magmatism in North Korea using U–Pb zircon geochronology. Chemical Geology 238, 232–48.
Wu, FY, Li, QL, Yang, JH, Kim, JN and Han, RH (2016) Crustal growth and evolution of the Rrannim Massif, northern Korean Peninsula. Acta Petrologica Sinica 32, 2933–47 (in Chinese with English abstract).
Wu, FY, Yang, JH, Wilde, SA, Liu, XM, Guo, JH and Zhai, MG (2007b) Detrital zircon U–Pb and Hf isotopic constraints on the crustal evolution of North Korea. Precambrian Research 159, 155–77.
Wu, FY, Yang, YH, Xie, LW, Yang, JH and Xu, P (2006) Hf isotopic compositions of the standard zircons and baddeleyites used in U-Pb geochronology. Chemical Geology 234, 105–26.
Wyllie, PJ (1980) The origin of kimberlite. Journal of Geophysical Research: Solid Earth 85, 6902–10.
Xie, LW, Yang, JH, Wu, FY, Yang, YH and Wilde, SA (2011) PbSL dating of garnet and staurolite: constraints on the Paleoproterozoic crustal evolution of the Eastern Block, North China Craton. Journal of Asian Earth Sciences 42, 142–54.
Yang, JH, O’Reilly, S, Walker, RJ, Griffin, W, Wu, FY, Zhang, M and Pearson, N (2010) Diachronous decratonization of the Sino-Korean craton: geochemistry of mantle xenoliths from North Korea. Geology 38, 799802.
Yang, JH, Peng, P, Jong, CS, Park, U, Mun, JG, Kim, CH and Ku, HC (2016) Comparison on ages of detrital zircons from the Paleoproterozoic to Lower Paleoproterozoic sedimentary rocks in the Pyongnam Basin, Korea. Acta Petrologica Sinica 32, 3155–79.
Yang, JH, Wu, FY, Xie, LW and Liu, XM (2007) Petrogenesis and tectonic implications of Kuangdonggou syenites in the Liaodong Peninsula, east North China Craton: constraints from in-situ zircon U-Pb ages and Hf isotopes. Acta Petrologica Sinica 23, 263–76.
Yin, A and Nie, S (1993) An indentation model for the North and South China collision and the development of the Tan-Lu and Honam Fault Systems, eastern Asia. Tectonics 12, 801–13.
Zhai, MG, Guo, JH, Li, Z, Chen, DZ, Peng, P, Li, TS, Hou, QL and Fan, QC (2007b) Linking the Sulu UHP belt to the Korean Peninsula: evidence from eclogite, Precambrian basement, and Paleozoic sedimentary basins. Gondwana Research 12, 388403.
Zhai, MG, Guo, JH, Li, Z, Chen, DZ, Peng, P, Li, TS, Zhang, YB, Hou, QL, Fan, QC and Hu, B (2007c) Extension of the Sulu UHP belt to the Korean Peninsula: evidence from orogenic belts, Precambrian basements, and Paleozoic sedimentary basins. Geological Journal of China Universities 13, 415–28 (in Chinese with English abstract).
Zhai, MG, Guo, JH, Peng, P and Hu, B (2007a) U–Pb zircon age dating of a rapakivi granite batholith in Rangnim massif, North Korea. Geological Magazine 144, 547–52.
Zhai, MG, Zhang, YB, Zhang, XH, Wu, FY, Peng, P, Li, QL, Hou, QL, Li, TS and Zhao, L (2016) Renewed profile of the Mesozoic magmatism in Korean Peninsula: regional correlation and broader implication for cratonic destruction in the North China Craton. Science China Earth Sciences 59, 2355–88.
Zhang, XH, Zhang, YB, Zhai, MG, Wu, FY, Hou, QL and Yuan, LL (2016) Decoding Neoarchaean to Palaeoproterozoic tectonothermal events in the Rangnim Massif, North Korea: regional correlation and broader implications. International Geology Review 59, 1628.
Zhao, GC, Cao, L, Wilde, SA, Sun, M, Choe, WJ and Li, SZ (2006) Implications based on the first SHRIMP U–Pb zircon dating on Precambrian granitoid rocks in North Korea. Earth and Planetary Science Letters 251, 365–79.
Zhao, GC, Sun, M, Wilde, SA and Li, SZ (2005) Late Archean to Paleoproterozoic evolution of the North China Craton: key issues revisited. Precambrian Research 136, 177202.
Zhao, GC, Wilde, SA, Cawood, PA and Lu, L (1998) Thermal evolution of Archean basement rocks from the eastern part of the North China Craton and its bearing on tectonic setting. International Geology Review 40, 706–21.
Zhao, GC, Wilde, SA, Cawood, PA and Sun, M (2001) Archean blocks and their boundaries in the North China Craton: lithological, geochemical, structural and PT path constraints and tectonic evolution. Precambrian Research 107, 4573.
Zhao, GC and Zhai, MG (2013) Lithotectonic elements of Precambrian basement in the North China Craton: review and tectonic implications. Gondwana Research 23, 1207–40.
Zhao, L, Zhang, YB, Yang, JH, Han, RH and Kim, JN (2016a) Archean rocks at the southeastern margin of the Rangnim massif, northern Korean, and their reponse to Paleoproterozoic tectonothermal event. Acta Petrologica Sinica 32, 2948–64 (in Chinese with English abstract).
Zhao, L, Zhang, YB, Wu, FY, Li, QL, Yang, JH, Kim, JN and Chou, WJ (2016b) Paleoproterozoic high temperature metamorphism and antexis in the northern Korean Peninsula: connstraints from petrology and zircon U-Pb geochrnology. Acta Petrologica Sinica 32, 3045–69 (in Chinese with Engligh abstract).
Zheng, JP, Griffin, WL, O’Reilly, SY, Yu, CM, Zhang, HF, Pearson, N and Zhang, M (2007) Mechanism and timing of lithospheric modification and replacement beneath the eastern North China Craton: peridotitic xenoliths from the 100 Ma Fuxin basalts and a regional synthesis. Geochimica et Cosmochimica Acta 71, 5203–25.
Zheng, JP, Griffin, WL, O’Reilly, SY, Zhang, M, Pearson, N and Pan, Y (2006) Widespread Archean basement beneath the Yangtze craton. Geology 34, 417–20.
Zheng, JP, Griffin, WL, O’Reilly, SY, Zhao, JH, Wu, YB, Liu, GL, Pearson, N, Zhang, M, Ma, CQ, Zhang, ZH, Yu, CM, Su, YP and Tang, HY (2009) Neoarchean (2.7–2.8 Ga) accretion beneath the North China Craton: U–Pb age, trace elements and Hf isotopes of zircons in diamondiferous kimberlites. Lithos 112, 188202.


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A Palaeoproterozoic basement beneath the Rangnim Massif revealed by the in situ U–Pb ages and Hf isotopes of xenocrystic zircons from Triassic kimberlites of North Korea

  • Yu-Sheng Zhu (a1) (a2), Jin-Hui Yang (a1) (a2) (a3), Hao Wang (a1) (a2) and Fu-Yuan Wu (a1) (a2) (a3)


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