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Forsterite reprecipitation and carbon dioxide entrapment in the lithospheric mantle during its interaction with carbonatitic melt: a case study from the Sung Valley ultramafic–alkaline–carbonatite complex, Meghalaya, NE India

Published online by Cambridge University Press:  20 August 2020

Shubham Choudhary ,
Koushik Sen Open the ORCID record for Koushik Sen [Opens in a new window] ,
Santosh Kumar Open the ORCID record for Santosh Kumar [Opens in a new window] ,
Shruti Rana  and
Swakangkha Ghosh
Shubham Choudhary
Affiliation:
Wadia Institute of Himalayan Geology, 33 GMS Road, Dehradun-248001, India
Koushik Sen*
Affiliation:
Wadia Institute of Himalayan Geology, 33 GMS Road, Dehradun-248001, India
Santosh Kumar
Affiliation:
Department of Geology, Centre of Advanced Study, Kumaun University, Nainital, India
Shruti Rana
Affiliation:
Wadia Institute of Himalayan Geology, 33 GMS Road, Dehradun-248001, India
Swakangkha Ghosh
Affiliation:
North Eastern Space Applications Centre, Umiam, Meghalaya, India
*
Author for correspondence: Koushik Sen, Email: koushik.geol@gmail.com
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Abstract

Carbonatite melts derived from the mantle are enriched in CO2- and H2O-bearing fluids. This melt can metasomatize the peridotitic lithosphere and liberate a considerable amount of CO2. Experimental studies have also shown that a CO2–H2O-rich fluid can form Fe- and Mg-rich carbonate by reacting with olivine. The Sung Valley carbonatite of NE India is related to the Kerguelen plume and is characterized by rare occurrences of olivine. Our study shows that this olivine is resorbed forsterite of xenocrystic nature. This olivine bears inclusions of Fe-rich magnesite. Accessory apatite in the host carbonatite contains CO2–H2O fluid inclusions. Carbon and oxygen isotopic analyses indicate that the carbonatites are primary igneous carbonatites and are devoid of any alteration or fractionation. We envisage that the forsterite is a part of the lithospheric mantle that was reprecipitated in a carbonatite reservoir through dissolution–precipitation. Carbonation of this forsterite, during interaction between the lithospheric mantle and carbonatite melt, formed Fe-rich magnesite. CO2–H2O-rich fluid derived from the carbonatite magma and detected within accessory apatite caused this carbonation. Our study suggests that a significant amount of CO2 degassed from the mantle by carbonatitic magma can become entrapped in the lithosphere by forming Fe- and Mg-rich carbonates.

Keywords

Fe-rich magnesitemetasomatismforsteritecarbonatiteRaman spectroscopyKerguelen plume
Type
Original Article
Information
Geological Magazine , Volume 158 , Issue 3 , March 2021 , pp. 475 - 486
Copyright
© The Author(s), 2020. Published by Cambridge University Press

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References

Acharya, SK, Mitra, ND and Nandy, DR (1986) Regional geology and tectonic setting of Northeast India and adjoining region, in geology of Nagaland Ophiolite. Memoirs of the Geological Survey of India 119, 6–12.Google Scholar
Bailey, DK and Hampton, CM (1990) Volatiles in alkaline magmatism. Lithos 26, 157–65.CrossRefGoogle Scholar
Basu, S and Murty, SVS (2006) Noble gases in carbonatites of Sung Valley and Ambadongar: implications for trapped components. Chemical Geology 234, 236–50, https://doi.org/10.1016/j.chemgeo.2006.05.004.CrossRefGoogle Scholar
Berkesi, M, Guzmics, T, Szabó, C, Dubessy, J, Bodnar, RJ, Hidas, K and Ratter, K (2012) The role of CO2-rich fluids in trace element transport and metasomatism in the lithospheric mantle beneath the Central Pannonian Basin, Hungary, based on fluid inclusions in mantle xenoliths. Earth and Planetary Science Letters 331, 8–20, https://doi.org/10.1016/j.epsl.2012.03.012.CrossRefGoogle Scholar
Blundy, J and Dalton, J (2000) Experimental comparison of trace element partitioning between clinopyroxene and melt in carbonate and silicate systems, and implications for mantle metasomatism. Contributions to Mineralogy and Petrology 139, 356–71.CrossRefGoogle Scholar
Boyd, FR, Pokhilenko, NP, Pearson, DG, Mertzman, SA, Sobolev, NV and Finger, LW (1997) Composition of the Siberian Cratonic Mantle: evidence from Udachnaya peridotite xenoliths. Contributions to Mineralogy and Petrology 128, 228–46, https://doi.org/10.1007/s004100050.CrossRefGoogle Scholar
Boynton, WV (1984) Cosmochemistry of the rare earth elements: meteorite studies. In Rare Earth Element Geochemistry (ed. P Henderson), pp. 63–114. Amsterdam: Elsevier, Developments in Geochemistry no. 2.CrossRefGoogle Scholar
Brenna, M, Cronin, SJ, Smith, IE, Tollan, PM, Scott, JM, Prior, DJ, Bambery, K and Ukstins, IA (2018) Olivine xenocryst diffusion reveals rapid monogenetic basaltic magma ascent following complex storage at Pupuke Maar, Auckland Volcanic Field, New Zealand. Earth and Planetary Science Letters 499, 13–22, https://doi.org/101016/jepsl201807015.CrossRefGoogle Scholar
Cullers, RL and Graf, JL (1984) Rare earth elements in igneous rocks of the continental crust: predominantly basic and ultrabasic rocks. In Rare Earth Element Geochemistry (ed. Henderson, P), pp. 237–74. Amsterdam: Elsevier, Developments in Geochemistry no. 2 CrossRefGoogle Scholar
Dalton, JA and Wood, BJ (1993) The compositions of primary carbonate melts and their evolution through wallrock reaction in the mantle. Earth and Planetary Science Letters 119, 511–25.CrossRefGoogle Scholar
Dawson, JB, Pinkerton, H, Pyle, DM and Nyamweru, C (1994) June 1993 eruption of Oldoinyo Lengai, Tanzania: exceptionally viscous and large carbonatite lava flows and evidence for coexisting silicate and carbonate magmas. Geology 22, 799–802.2.3.CO;2>CrossRefGoogle Scholar
Deines, P (1989) Stable isotope variations in carbonatites. In Carbonatites: Genesis and Evolution (ed. Bell, K), pp. 301–50. Boston: Unwin Hyman.Google Scholar
Deines, P and Gold, DP (1973) The isotope composition of carbonatites and kimberlite carbonate and their bearing on the isotopic composition of deep seated carbon. Geochimica et Cosmochimica Acta 37, 1709–33.CrossRefGoogle Scholar
Desikachar, SV (1974) A review of the tectonic and geologic history of Eastern India in terms of plate tectonics theory. Journal of Geological Society of India 15, 137–49.Google Scholar
Dixon, J, Clague, DA, Cousens, B, Monsalve, ML and Uhl, J (2008) Carbonatite and silicate melt metasomatism of the mantle surrounding the Hawaiian plume: evidence from volatiles, trace elements, and radiogenic isotopes in rejuvenated-stage lavas from Niihau, Hawaii. Geochemistry, Geophysics, Geosystems 9, 1–34, https://doi.org/10.1029/2008GC002076.CrossRefGoogle Scholar
Dixon, JE, Clague, DA, Wallace, P and Poreda, R (1997) Volatiles in alkalic basalts form the North Arch volcanic field, Hawaii: extensive degassing of deep submarine-erupted alkalic series lavas. Journal of Petrology 38, 911–39.CrossRefGoogle Scholar
Dobson, DP, Jones, AP, Rabe, R, Sekine, T, Kurita, K, Taniguchi, T, Kondo, T, Kato, T, Shimomura, O and Urakawa, S (1996) In-situ measurement of viscosity and density of carbonate melts at high pressure. Earth and Planetary Science Letters 143, 207–15.CrossRefGoogle Scholar
Doucet, LS, Peslier, AH, Ionov, DA, Brandon, AD, Golovin, AV, Goncharov, AG and Ashchepkov, IV (2014) High water contents in the siberian cratonic mantle linked to metasomatism: an FTIR study of Udachnaya peridotite xenoliths. Geochimica et Cosmochimica Acta 137, 159–87, https://doi.org/10.1016/j.gca.2014.04.011.CrossRefGoogle Scholar
Evans, P (1964) The tectonic framework of Assam. Journal of Geological Society of India 5, 80–96.Google Scholar
Frezzotti, ML, Tecce, F and Casagli, A (2012) Raman spectroscopy for fluid inclusion analysis. Journal of Geochemical Exploration 112, 1–20, https://doi.org/10.1016/j.gexplo.2011.09.009.CrossRefGoogle Scholar
Gervasoni, F, Klemme, S, Rohrbach, A, Grützner, T and Berndt, J (2017) Experimental constraints on mantle metasomatism caused by silicate and carbonate melts. Lithos 282, 173–86.CrossRefGoogle Scholar
Grassi, D and Schmidt, MW (2011) The melting of carbonated pelites from 70 to 700 km depth. Journal of Petrology 52, 765–89.CrossRefGoogle Scholar
Green, DH and Wallace, ME (1988) Mantle metasomatism by ephemeral carbonatite melts. Nature 336, 459.CrossRefGoogle Scholar
Gupta, RP and Sen, AK (1988) Imprints of the Ninety-East Ridge in the Shillong Plateau, Indian Shield. Tectonophysics 154, 335–41, https://doi.org/10.1016/0040-1951(88)90111-4.CrossRefGoogle Scholar
Hammouda, T and Laporte, D (2000) Ultrafast mantle impregnation by carbonatite melts. Geology 28, 283–5.2.0.CO;2>CrossRefGoogle Scholar
Harmer, RE (1999) The petrogenetic association of carbonatite and alkaline magmatism: constraints from the Spitskop Complex, South Africa. Journal of Petrology 40, 525–48, https://doi.org/10.1093/petroj/40.4.525.CrossRefGoogle Scholar
Hauri, EH, Shimizu, N, Dieu, JJ and Hart, SR (1993) Evidence for hotspot-related carbonatite metasomatism in the oceanic upper mantle. Nature 365, 221.CrossRefGoogle Scholar
Ionov, DA, Dupuy, C, O’Reilly, SY, Kopylova, MG and Genshaft, YS (1993) Carbonated peridotite xenoliths from Spitsbergen: implications for trace element signature of mantle carbonate metasomatism. Earth and Planetary Science Letters 119, 283–97, https://doi.org/10.1016/0012-821X(93)90139-Z.CrossRefGoogle Scholar
Jones, AP, Genge, M and Carmody, L (2013) Carbonate melts and carbonatites. Reviews in Mineralogy and Geochemistry 75, 289–322.CrossRefGoogle Scholar
Kelemen, PB and Matter, J (2008) In situ carbonation of peridotite for CO2 storage. Proceedings of the National Academy of Sciences 105, 17295–300, https://doi.org/10.1073/pnas.0805794105.CrossRefGoogle Scholar
Keller, J and Hoefs, J (1995) Stable isotope characteristics of recent natrocarbonatite from Oldoiyno Lengai. In Carbonatite Volcanism: Oldoinyo Lengai and Petrogenesis of Natrocarbonatite (eds Bell, K and Keller, J), pp. 113–23. Berlin: Springer.CrossRefGoogle Scholar
Kogarko, L, Kurat, G and Ntaflos, T (2001) Carbonate metasomatism of the oceanic mantle beneath Fernando de Noronha Island, Brazil. Contributions to Mineralogy and Petrology 140, 577–87, https://doi.org/10.1007/s004100000201.CrossRefGoogle Scholar
Kwak, JH, Hu, JZ, Turcu, RV, Rosso, KM, Ilton, ES, Wang, C, Sears, JA, Engelhard, MH, Felmy, AR and Hoyt, DW (2011) The role of H2O in the carbonation of forsterite in supercritical CO2 . International Journal of Greenhouse Gas Control 5, 1081–92, https://doi.org/10.1016/j.ijggc.2011.05.013.Google Scholar
Kyser, TK (1990) Stable isotopes in the continental lithospheric mantle. In The Continental Lithosphere (ed. Menzies, M), pp. 127–56. Oxford: Oxford University Press.Google Scholar
Lee, WJ and Wyllie, PJ (1998) Petrogenesis of carbonatite magmas from mantle to crust, constrained by the system CaO–(MgO+ FeO*)–(Na2O+ K2O)–(SiO2+ Al2O3+ TiO2)-CO2. Journal of Petrology 39, 495–517.CrossRefGoogle Scholar
Loring, JS, Chen, J, Bénézeth, P, Qafoku, O, Ilton, ES, Washton, NM, Thompson, CJ, Martin, PF, McGrail, BP, Rosso, KM and Felmy, AR (2015) Evidence for carbonate surface complexation during forsterite carbonation in wet supercritical carbon dioxide. Langmuir 31, 7533–43, https://doi.org/10.1021/acs.langmuir.5b01052.CrossRefGoogle ScholarPubMed
Melluso, L, Srivastava, RK, Guarino, V, Zanetti, A and Sinha, AK (2010) Mineral compositions and petrogenetic evolution of the Ultramafic-Alkaline-Carbonatite complex of Sung Valley, Northeastern India. The Canadian Mineralogist 48, 205–29. https://doi.org/10.3749/canmin.48.1.205.Google Scholar
Mitchell, RH (2005) Carbonatites and carbonatites and carbonatites. The Canadian Mineralogist 43, 2049–68.CrossRefGoogle Scholar
Nandy, DR (1980) Tectonic pattern in Northeastern India. Indian Journal of Earth Science 7, 103–7.Google Scholar
O’Reilly, SY and Griffin, WL (2013) Mantle metasomatism. In Metasomatism and the Chemical Transformation of Rock (eds Harlov, DE and Austrheim, H), pp. 471–533. Berlin, Heidelberg: Springer.CrossRefGoogle Scholar
Pearson, DG and Wittig, N (2014) The formation and evolution of cratonic mantle lithosphere evidence from mantle xenoliths. In Reference Module in Earth Systems and Environmental Sciences (eds Holland, HD and Turekian, KK), pp. 255–92. Amsterdam: Elsevier, Treatise on Geochemistry.Google Scholar
Pokhilenko, NP, Agashev, AM, Litasov, KD and Pokhilenko, LN (2015) Carbonatite metasomatism of peridotite lithospheric mantle: implications for diamond formation and carbonatite-kimberlite magmatism. Russian Geology and Geophysics 56, 280–95, http://dx.doi.org/10.1016/j.rgg.201.0.020.CrossRefGoogle Scholar
Ray, JS and Pande, K (2001) 40Ar-39Ar age of carbonatite-alkaline magmatism in Sung Valley, Meghalaya, India. Journal of Earth System Science 110, 185–90, https://doi.org/10.1007/BF02702233.CrossRefGoogle Scholar
Ray, JS and Ramesh, R (2000) Rayleigh fractionation of stable isotopes from a multicomponent source. Geochimica et Cosmochimica Acta 64, 299–306.CrossRefGoogle Scholar
Ray, JS and Ramesh, R (2006) Stable carbon and oxygen isotopic compositions of Indian Carbonatites. International Geology Review 48, 17–45.CrossRefGoogle Scholar
Ray, JS, Ramesh, R and Pande, K (1999) Carbon isotopes in Kerguelen Plume-derived carbonatites: evidence for recycled inorganic carbon. Earth and Planetary Science Letters 170, 205–14.Google Scholar
Ray, JS, Trivedi, JR and Dayal, AM (2000) Strontium isotope systematics of Amba Dongar and Sung Valley carbonatite-alkaline complexes, India: evidence for liquid immiscibility, crustal contamination and long-lived Rb/Sr enriched mantle sources. Journal of Asian Earth Sciences 18, 585–94.CrossRefGoogle Scholar
Roedder, E (1984) Fluid inclusions, reviews in mineralogy. Geochimica et Cosmochimica Acta 49(6), 1491, https://doi.org/10.1016/0016-7037(85)90299-6.Google Scholar
Rudnick, RL, McDonough, WF and Chappell, BW (1993) Carbonatite metasomatism in the Northern Tanzanian mantle: petrographic and geochemical characteristics. Earth and Planetary Science Letters 114, 463–75, https://doi.org/10.1016/0012-821X(93)90076-L.CrossRefGoogle Scholar
Sadik, M, Ranjith, A and Umrao, AK (2014) REE mineralization in the carbonatites of the Sung Valley ultramafic-alkaline-carbonatite complex, Meghalaya, India. Open Geosciences 6, 457–75, https://doi.org/10.2478/s13533-012-0191-y.Google Scholar
Sai, VS and Sengupta, SK (2017) Resorbed forsterite in the carbonatite from the Cretaceous Sung Valley Complex, Meghalaya, NE India–Implications for crystal-melt interaction from textural studies. Journal of Indian Geophysical Union 21, 292–7.Google Scholar
Santrock, J, Studley, SA and Hayes, J (1985) Isotopic analyses based on the mass spectra of carbon dioxide. Analytical Chemistry 57, 1444–8.CrossRefGoogle Scholar
Sheppard, SME and Dawon, JB (1973) 13C/12C and D/H isotope variations in primary igneous carbonatites, Fortschr. Mineral 50, 128–9.Google Scholar
Sokol, AG, Kruk, AN, Chebotarev, DA and Palyanov, YN (2016) Carbonatite melt-peridotite interaction at 5.5–7.0 GPa: implications for metasomatism in lithospheric mantle. Lithos 248–51, 66–79.CrossRefGoogle Scholar
Spargo, SRW (2007) The Pupuke Volcanic Centre, Polygenetic Magmas in a Mono-genetic Field. Auckland: University of Auckland, 141 p.Google Scholar
Srivastava, RK (1997) Petrology, geochemistry and genesis of rift-related carbonatites of Ambadungar, India. Mineralogy and Petrology 61, 47–66.CrossRefGoogle Scholar
Srivastava, RK (2020) Early Cretaceous alkaline/ultra-alkaline silicate and carbonatite magmatism in the Indian Shield–a review: implications for a possible remnant of the Greater Kerguelen Large Igneous Province. Episodes Journal of International Geoscience 43, 300–11.Google Scholar
Srivastava, RK, Guarino, V, Wu, FY, Melluso, L and Sinha, AK (2019) Evidence of sub-continental lithospheric mantle sources and open-system crystallization processes from in-situ U–Pb ages and Nd–Sr–Hf isotope geochemistry of the Cretaceous ultramafic-alkaline (carbonatite) intrusions from the Shillong Plateau, North-Eastern India. Lithos 330, 108–19, https://doi.org/10.1016/j.lithos.2019.02.009.CrossRefGoogle Scholar
Srivastava, RK and Hall, RP (1995) Tectonic setting of Indian carbonatites. In Magmatism in Relation to Diverse Tectonic Setting (eds Srivastava, RK and Chandra, R), pp. 134–54. Rotterdam: AA Balkema.Google Scholar
Srivastava, RK, Heaman, LM, Sinha, AK and Shihua, S (2005) Emplacement age and isotope geochemistry of Sung Valley alkaline-carbonatite complex, Shillong Plateau, Northeastern India: implications for primary carbonate melt and genesis of the associated silicate rocks. Lithos 81, 33–54.CrossRefGoogle Scholar
Srivastava, RK and Sinha, AK (2004) Early Cretaceous Sung Valley ultramafic-alkaline-carbonatite complex, Shillong Plateau, Northeastern India: petrological and genetic significance. Mineralogy and Petrology 80, 241–63.CrossRefGoogle Scholar
Stopic, S, Dertmann, C, Modolo, G, Kegler, P, Neumeier, S, Kremer, D, Wotruba, H, Etzold, S, Telle, R, Rosani, D and Knops, P (2018) Synthesis of magnesium carbonate via carbonation under high pressure in an autoclave. Metals 8, 993.CrossRefGoogle Scholar
Su, B, Chen, Y, Guo, S, Chu, ZY, Liu, JB and Gao, YJ (2016) Carbonatitic metasomatism in orogenic dunites from Lijiatun in the Sulu UHP Terrane, Eastern China. Lithos 262, 266–84.CrossRefGoogle Scholar
Taylor, HP, Frechen, J and Degens, ET (1967) Oxygen and carbon isotopes studies of carbonatites from the Laacher Sea district, West Germany and the Alno districts, Sweden. Geochimica et Cosmochimica Acta 31, 407–30.CrossRefGoogle Scholar
Todd Schaef, H, McGrail, BP, Loring, JL, Bowden, ME, Arey, BW and Rosso, KM (2013) Forsterite [Mg2SiO4] carbonation in wet supercritical CO2: an in situ high-pressure X-ray diffraction study. Environmental Science & Technology 47, 174–81.CrossRefGoogle Scholar
Veena, K, Pandey, BK, Krishnamurthy, P and Gupta, JN (1998) Pb, Sr and Nd isotopic systematics of the carbonatites of Sung Valley, Meghalaya, Northeast India: implications for contemporary plume-related mantle source characteristics. Journal of Petrology 39, 1875–84, https://doi.org/10.1093/petroj/39.11-12.1875.CrossRefGoogle Scholar
Woolley, AR and Kemp, DRC (1989) Carbonatites: nomenclature, average chemical compositions and element distribution. In Carbonatites Genesis and Evolution (ed Bell, K), pp. 1–14. London: Unwin Hyman.Google Scholar
Woolley, AR, Barr, MWC, Din, VK, Jones, GC, Wall, F and Williams, CT (1991) Extrusive carbonatites from the Uyaynah Area, United Arab Emirates. Journal of Petrology 32, 1143–67, https://doi.org/10.1093/petrology/32.6.1143.CrossRefGoogle Scholar
Xiong, W and Giammar, D (2014) Forsterite carbonation in zones with transport limited by diffusion. Environmental Science & Technology Letters 1, 333–8, https://doi.org/10.1021/ez500182s.CrossRefGoogle Scholar
Yaxley, GM (1993) Carbonatite metasomatism in the mantle: sources and roles of carbonate in metasomatic enrichment processes in the lithosphere. Ph.D. thesis, University of Tasmania. Published thesis.Google Scholar
Yaxley, GM, Crawford, AJ and Green, DH (1991) Evidence for carbonatite metasomatism in spinel peridotite xenoliths from Western Victoria, Australia. Earth and Planetary Science Letters 107, 305–17, https://doi.org/10.1016/0012-821X(91)90078-V.CrossRefGoogle Scholar
Yaxley, GM, Green, DH and Kamenetsky, V (1998) Carbonatite metasomatism in the southeastern Australian lithosphere. Journal of Petrology 39, 1917–30.CrossRefGoogle Scholar