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PAHs and the Chemistry of the ISM

Published online by Cambridge University Press:  30 March 2011

C. Joblin ,
A.G.G.M. Tielens ,
V.M. Bierbaum ,
V. Le Page  and
T.P. Snow
V.M. Bierbaum
Affiliation:
Department of Chemistry & Biochemistry; University of Colorado, Boulder, CO 80309, USA
V. Le Page
Affiliation:
Department of Chemistry & Biochemistry; University of Colorado, Boulder, CO 80309, USA
T.P. Snow
Affiliation:
Department of Astrophysical & Planetary Science; University of Colorado, Boulder, CO 80309, USA

Abstract

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This review describes five categories of the reactions of polycyclic aromatic hydrocarbons, including photochemistry, electron attachment/detachment, recombination processes, radical reactions, and ion-neutral chemistry. For each class of reaction, an overview of the studies and their general results are presented, as well as references to the literature. The thermochemistry of PAHs and relevant species is described, including bond dissociation energies, ionization energies, electron affinities, basicities, acidities, and the interrelationships of these quantities. Modeling of the chemistry of PAHs and their ions is discussed for both diffuse and dark clouds. The role of PAH cations in the catalytic formation of molecular hydrogen is considered. Finally, this review concludes with a discussion of current challenges in the chemical characterization of PAHs, and a perspective for future studies.

Type
Research Article
Information
European Astronomical Society Publications Series , Volume 46: PAHs and the Universe: A Symposium to Celebrate the 25th Anniversary of the PAH Hypothesis , 2011 , pp. 427 - 440
Copyright
© EAS, EDP Sciences 2011

References

Allamandola, L.J., Tielens, A.G.G.M., & Barker, J.R., 1985, ApJ, 290, L25 CrossRef
Allamandola, L.J., Tielens, A.G.G.M., & Barker, J.R., 1989, ApJS, 71, 733 CrossRef
Ausloos, P., Lias, S.G., Buckley, T.J., & Rogers, E.E., 1989, Int. J. Mass Spectrom. Ion Proc., 92, 65 CrossRef
Banisaukas, J., Szczepanski, J., Eyler, J., & Vala, M., 2004, J. Phys. Chem. A, 108, 3723 CrossRef
Bauschlicher, C.W., 1998, ApJ, 509, L125 CrossRef
Betts, N.B., Stepanovic, M., Snow, T.P., & Bierbaum, V.M., 2006, ApJ, 651, L129 CrossRef
Biennier, L., Alsayed-Ali, M., Foutel-Richard, A., et al., 2006, Discuss. Faraday Soc., 133, 289 CrossRef
Bohme, D.K., 2000, Int. J. Mass Spectrom., 200, 97 CrossRef
Bohme, D.K., 2009, Mass Spectrom. Rev., 28, 672 CrossRef
Bruhns, H., Kreckel, H., Miller, K., et al., 2010, Rev. Sci. Instr., 81, 013112 CrossRef
Canosa, A., Parent, D.C., Pasquerault, D., et al., 1994, Chem. Phys. Lett., 228, 26 CrossRef
Eichelberger, B.R., Snow, T.P., Barckholtz, C., & Bierbaum, V.M., 2007, ApJ, 667, 1283 CrossRef
Ekern, S., Gomez, L., Szczepanski, J., & Vala, M., 2007, Chem. Phys., 331, 219 CrossRef
Ervin, K.M., 2001, Chem. Rev., 101, 391 CrossRef
Fenn, J.B., Mann, M., Meng, C.K., Wong, S.F., & Whitehouse, C.M., 1990, MassSpectrom. Rev., 9, 37
Gerlich, D., & Smith, M., 2006, Phys. Scr., 73, C25 CrossRef
Gotkis, Y., Oleinikova, M., Naor, M., & Lifshitz, C., 1993, J. Phys. Chem., 97, 12282 CrossRef
Goulay, F., Rebrion-Rowe, C., Garrec, J.L.L., et al., 2005, J. Chem. Phys., 122, 104308 CrossRef
Goulay, F., Rebrion-Rowe, C., Biennier, L., et al., 2006a, J. Phys. Chem. A, 110, 3132 CrossRef
Goulay, F., & Leone, S.R., 2006b, J. Phys. Chem. A, 110, 1875 CrossRef
Gronert, S., 2005, Mass Spectrom. Rev., 24, 100 CrossRef
Herbst, E., 2001, Chem. Soc. Rev., 30, 168 CrossRef
Hirama, M., Ishida, T., & Aihara, J.-I., 2003, J. Comput. Chem., 24, 1378 CrossRef
Jochims, H.W., Baumgartel, H., & Leach, S., 1996, A&A, 314, 1003
Jochims, H.W., Baumgartel, H., & Leach, S., 1999, ApJ, 512, 500 CrossRef
Knorke, H., Langer, J., Oomens, J., & Dopfer, O., 2009, ApJ, 706, L66 CrossRef
Larsson, M., & Orel, A.E., 2008, Dissociative Recombination of Molecular Ions(Cambridge University Press: Cambridge)
Le Page, V., Keheyan, Y., Snow, T.P., & Bierbaum, V.M., 1999a, J. Am. Chem. Soc., 121, 9435 CrossRef
Le Page, V., Keheyan, Y., Snow, T.P., & Bierbaum, V.M., 1999b, Int. J. Mass Spectrom., 185/186/187, 949
Le Page, V., Snow, T.P., & Bierbaum, V.M., 2001, ApJS, 132, 233 CrossRef
Le Page, V., Snow, T.P., & Bierbaum, V.M., 2003, ApJ, 584, 316 CrossRef
Le Page, V., Snow, T.P., & Bierbaum, V.M., 2009, ApJ, 704, 274 CrossRef
Léger, A., & Puget, J.L., 1984, A&A, 137, L5 PubMed
Linstrom, P.J., & Mallard, W.G. (eds.), NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg, MD 20899, http://webbook.nist.gov
Luca, A., Borodi, G., & Gerlich, D., 2006, in “Interactions of Ions with Hydrogen Atoms. In Progress report in XXIV ICPEAC 2005”, ed. Colavecchia, F.D., Fainstein, P.D., Fiol, J., Lima, M.A.P., Miraglia, J.E., Montenegro, E.C.. Rivarola, R.D. (Rosario, Argentina), 29
Nibbering, N.M.M., 2006, Mass Spectrom. Rev., 25, 962 CrossRef
Omont, A., 1986, A&A, 164, 159
Schiedt, J., & Weinkauf, R., 1997a, Chem. Phys. Lett., 266, 201 CrossRef
Schiedt, J., & Weinkauf, R., 1997b, Chem. Phys. Lett., 274, 18 CrossRef
Schmidt, H.T., Johansson, H.A.B., Thomas, R.D., et al., 2008, Int. J. Astrobiology, 7, 205 CrossRef
Sebree, J.A., Kislov, V.V., Mebel, A.M., & Zwier, T.S., 2010, J. Phys. Chem. A, 114, 6255 CrossRef
Shea, R.C., Habicht, S.C., Vaughn, W.E., & Kenttamaa, H.I., 2007, Anal. Chem., 79, 2688 CrossRef
Shukla, B., Miyoshi, A., & Koshi, M., 2010, J. Am. Soc. Mass Spectrom., 21, 534 CrossRef
Smith, D., & Adams, N.G., 1988, Adv. At. Mol. Phys., 24, 1 CrossRef
Smith, D., 1992, Chem. Rev., 92, 1473 CrossRef
Smith, D., & Spanel, P., 1996, J. Phys. B: At. Mol. Opt. Phys., 29, 5199 CrossRef
Smith, I.W.M., 2006, Angew. Chem. Int. Ed., 45, 2842 CrossRef
Snow, T.P., Page, V.L., Keheyan, Y., & Bierbaum, V.M., 1998, Nature, 391, 259 CrossRef
Snow, T.P., & Bierbaum, V.M., 2008, Annu. Rev. Anal. Chem., 1, 229 CrossRef
Tielens, A.G.G.M., 2005, “The Physics and Chemistry of the Interstellar Medium”(Cambridge Univ. Press: Cambridge, UK)
Tielens, A.G.G.M., 2008, ARA&A, 46, 289 CrossRef
Tobita, S., Meinke, M., Illenberger, E., et al., 1992, Chem. Phys., 161, 501 CrossRef
Tschurl, M., & Boesl, U., 2006, Int. J. Mass Spectrom., 249, 364 CrossRef
Turro, N.J., Ramamurthy, V., & Scaiano, J.C., 2010, “Modern Molecular Photochemistry of Organic Molecules” (University Science Books: Sausalito, CA)
Uggerud, E., 2003, Top. Curr. Chem., 225, 3 CrossRef
Useli-Bacchitta, F., Bonnamy, A., Mulas, G., et al., 2010, Chem. Phys., 371, 16 CrossRef
Vala, M., Szczepanski, J., Oomens, J., & Steill, J.D., 2009, J. Am. Chem. Soc., 131, 5784 CrossRef
Verstraete, L., Léger, A., d’Hendecourt, L., Dutuit, O., & Defourneau, D., 1990, Astron. Astrophys., 237, 436
Vestal, M.L., 2001, Chem. Rev., 101, 361 CrossRef
Wakelam, V., & Herbst, E., 2008, ApJ, 680, 371 CrossRef
Yang, Z., Eichelberger, B., Carpenter, M., et al., 2010, submitted
Zhao, D., Langer, J., Oomens, J., & Dopfer, O., 2009, J. Chem. Phys., 131, 184307 CrossRef