Hostname: page-component-848d4c4894-x5gtn Total loading time: 0 Render date: 2024-05-21T01:33:03.879Z Has data issue: false hasContentIssue false
  • English
  • Français

Study of Nanocomposites Obtained by Carbonization of Different Organic Precursors within Taeniolite Matrices

Published online by Cambridge University Press:  28 February 2024

Teresa J. Bandosz ,
Karol Putyera ,
Jacek Jagiełło  and
James A. Schwarz
Teresa J. Bandosz
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, New York 13244-1190
Karol Putyera*
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, New York 13244-1190
Jacek Jagiełło*
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, New York 13244-1190
James A. Schwarz
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, New York 13244-1190
*
†Permanent address: Institute of Inorganic Chemistry, Slovak Academy of Sciences, 842 36 Bratislava, Slovakia
‡Permanent address: Faculty of Fuels and Energy, University of Mining and Metallurgy, 30-059 Krakow, Poland.
Get access Rights & Permissions [Opens in a new window]

Abstract

The lithium form of taeniolite served as the molecular template for carbon nanocomposites. It was intercalated with hydroxy aluminum and hydroxy aluminum-zirconium cations. Aliquots of the inorganic matrices were saturated by furfuryl alcohol followed by its interlayer polymerization. The structures were heated at 973 K in nitrogen to carbonize the polymeric precursor. Additional materials were mixed with polypropylene glycol which was then carbonized within the mineral layers. The surface properties of the nanocomposites were studied by X-ray diffraction (XRD), DTA, SEM and sorption experiments (sorption of nitrogen). The results showed that structural properties of the derived materials depend on the inorganic matrix and organic precursor. The carbon-taeniolite nanocomposites derived from polyfurfuryl alcohol as a precursor were characterized by high carbon content and a high percentage of its surface area in micropores. A broad spectrum of surface characteristics of the final products were found, depending on the history of the sample.

Keywords

Furfuryl AlcoholPolypropylene GlycolTaeniolite IntercalationTaeniolite-carbon Nanocomposites
Type
Research Article
Information
Clays and Clay Minerals , Volume 44 , Issue 2 , April 1996 , pp. 237 - 243
Copyright
Copyright © 1996, The Clay Minerals Society

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Baksh, M.S.A. and Yang, R.T.. 1992. Unique adsorption properties and potential energy profiles of microporous pillared clays. AIChE J 38: 1357–1368.CrossRefGoogle Scholar
Bandosz, T.J., Jagiełło, J., Amankwah, K.A.G. and Schwarz, J.A.. 1992. Chemical and structural properties of clay minerals modified by inorganic and organic material. Clay Miner 27: 435–444.CrossRefGoogle Scholar
Bandosz, T.J., Putyera, K., Jagiełło, J. and Schwarz, J.A.. 1993. Application of inverse gas chromatography to the study of surface properties of modified layered materials. Microporous Materials 1: 73–79.CrossRefGoogle Scholar
Bandosz, T.J., Gomez-Salazar, S., Putyera, K. and Schwarz, J.A.. 1994a. Pore structures of carbon-smectite nanocomposites. Microporous Materials 3: 177–184.CrossRefGoogle Scholar
Bandosz, T.J., Putyera, K., Jagiełło, J. and Schwarz, J.A.. 1994b. Study of carbon-smectite composites and carbons obtained by in situ carbonization of polyfurfuryl alcohol. Carbon 32: 659–664.CrossRefGoogle Scholar
Bandosz, T.J., Putyera, K., Jagiełło, J., Schwarz, J.A., Rouzaud, J.-N., Beguin, F. and Ben-Maimoun, I.. 1995. Structural and adsorption properties of carbons synthesized within taeniolite matrices. J Chem Soc Faraday Trans 91: 493–497.CrossRefGoogle Scholar
Bandosz, T.J., Jagiełło, J., Andersen, B. and Schwarz, J.A.. 1992. Inverse gas chromatography study of modified smectite surface. Clays & Clay Miner 40: 306–310.CrossRefGoogle Scholar
Barrett, E.P., Joyner, L.G. and Halenda, P.P.. 1951. The determination of pore volume and area distributions in porous substances. I. computations from nitrogen isotherms. J Am Chem Soc 73: 373–380.CrossRefGoogle Scholar
Gil, A. and Montes, M.. 1994. Analysis of the microporosity in pillared clays. Langmuir 10: 291–297.CrossRefGoogle Scholar
Kyotani, T., Yamada, H., Sonobe, N. and Tomita, A.. 1994. Heat treatment of Polyfurfuryl alcohol prepared between taeniolite lamellae. Carbon 32: 627–635.CrossRefGoogle Scholar
Lippens, B.C., Linsen, B.G. and de Boer, J.H.. 1964. Studies on pore systems in catalysts I. The adsorption of nitrogen; apparatus and calculation. J Catal 3: 32–37.CrossRefGoogle Scholar
Occelli, M.L. and Tindwa, P.M.. 1983. Physicochemical properties of montmorillonite interlayered with cationic oxyaluminium pillars. Clays & Clay Miner 31: 22–28.CrossRefGoogle Scholar
Oya, A., Yasuda, H., Otani, S. and Yamada, Y.. 1986. Effects of oxidation on the structure of porous material prepared from a montmorillonite-oi-naphthylamine complex. J Mat Sci 21: 4481–4484.CrossRefGoogle Scholar
Oya, A., Sato, A., Hanaoka, H. and Otani, S.. 1990. Properties of taeniolite/acriflavine complex film before and after carbonization: effect of acriflavine content. J Am Ceram Soc 73: 689–693.CrossRefGoogle Scholar
Pinnavaia, T.J.. 1983. Intercalated clay catalysts. Science 220: 365–371.CrossRefGoogle ScholarPubMed
Seron, A., Ben-Maimoun, I., Crispin, M. and Beguin, F.. 1993. Production of β′-SiAlONs through carbon/oxide nanocomposites obtained from montmorillonite/aromatic-ammonium complexes. Mat Sci and Eng A168: 239–243.Google Scholar
Sonobe, N., Kyotani, T. and Tomita, A.. 1990. Carbonization of polyfurfuryl alcohol and polyvinyl acetate between the lamellae of montmorillonite. Carbon 28: 483–488.CrossRefGoogle Scholar
Zyła, M. and Bandosz, T.. 1987. Montmorillonite from Milowice intercalated with hydroxy-aluminum oligocations as vapor and gas adsorbent. Min Polon 18: 39–50.Google Scholar