Hostname: page-component-848d4c4894-r5zm4 Total loading time: 0 Render date: 2024-06-23T15:24:50.056Z Has data issue: false hasContentIssue false

Scanning Electron Microscopic and X-ray Powder Diffraction Study of Manganiferous Bauxite, Kincsesbánya, Hungary

Published online by Cambridge University Press:  02 April 2024

György Bárdossy
Affiliation:
Hungarian Aluminium Corporation, Budapest, Hungary
Anna Csordás-Toth
Affiliation:
HUNGALU Engineering and Development Centre, Budapest, Hungary
Annamária Klug
Affiliation:
HUNGALU Engineering and Development Centre, Budapest, Hungary

Abstract

Manganiferous karst bauxites are rare on a worldwide scale. One such body, recently mined at Kincsesbánya, Hungary, has been studied by chemical, petrographic, X-ray powder diffraction, scanning electron microscopic, and energy dispersive X-ray analytical techniques. The bauxite deposits of Kinesesbánya are of Paleocene to Lower Eocene age; however, the enrichment of manganese in them was a much later, epigenetic process. Lithiophorite is the main Mn mineral in this bauxite and occurs chiefly in dusters of < 1-μm size crystallites. Well-developed crystallites, however, 5–10 μm in size, line the walls of many microfissures and voids.

The oxidation of pyritic bauxite and lignitic clays in the overlying beds apparently mobilized finely disseminated Mn and Fe. Downward-migrating acidic solutions were gradually neutralized, and Mn and Fe minerals precipitated. The manganiferous bauxite was found only along the eastern rim of heavily eroded Middle Eocene sedimentary rocks. Here, epigenetic oxidation and mobilization were optimum. Farther to the east, pyrite-rich overburden and bauxite were apparently eroded away before Fe and Mn could be mobilized.

Type
Research Article
Copyright
Copyright © 1985, The Clay Minerals Society

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Bârdossy, G.y., 1982 Karst Bauxites Amsterdam Elsevier.Google Scholar
Bârdossy, G.y., Bottyân, L., Gadó, P., Griger, and Sasvâri, J., 1980 Automated quantitative phase analysis of bauxites Amer. Mineral. 65 135141.Google Scholar
Bârdossy, G.y., Csanâdy, A. and Csordâs-Toth, A., 1978 Scanning electron microscope study of bauxites of different ages and origins Clays & Clay Minerals 26 245262.CrossRefGoogle Scholar
Ostwald, J., Turner, K. E. and England, B. M., 1983 Morphological studies of iron and manganese ores using a Philips SEM 505 scanning electron microscope Electron Optics Bull. 119 17.Google Scholar