Hostname: page-component-848d4c4894-tn8tq Total loading time: 0 Render date: 2024-06-22T09:26:13.311Z Has data issue: false hasContentIssue false
  • English
  • Français

Oxidation of Benzidine on Low-Iron Smectites: A Proposed Mechanism

Published online by Cambridge University Press:  02 April 2024

M. B. McBride  and
M. G. Johnson
M. B. McBride
Affiliation:
Department of Agronomy, Cornell University, Ithaca, New York 14853
M. G. Johnson*
Affiliation:
Department of Agronomy, Cornell University, Ithaca, New York 14853
*
1Present address: EPA, 200 SW 35th St., Corvallis, Oregon 97333.
Get access Rights & Permissions [Opens in a new window]

Abstract

An abstract is not available for this content so a preview has been provided. Please use the Get access link above for information on how to access this content.
Image of the first page of this content. For PDF version, please use the ‘Save PDF’ preceeding this image.'

Keywords

BenzidineCation exchangeIronOxidationSmectiteTetramethylbenzidine
Type
Notes
Information
Clays and Clay Minerals , Volume 34 , Issue 6 , December 1986 , pp. 686 - 688
Copyright
Copyright © 1986, The Clay Minerals Society

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Feldkamp, J. R. and White, J. L., 1979 Acid-base equilibria in clay suspension J. Colloid Interface Sci. 69 97–106.CrossRefGoogle Scholar
Furukawa, T. and Brindley, G. W., 1973 Adsorption and oxidation of benzidine and aniline by montmorillonite and hectorite Clays & Clay Minerals 21 279–288.CrossRefGoogle Scholar
Hayes, M. H. B., Pick, M. E. and Toms, B. A., 1978 The influence of organocation structure on the adsorption of mono- and of bipyridinium cations by expanding lattice clay minerals. I. Adsorption by Na-montmorillonite J. Colloid Interface Sci. 65 254–265.CrossRefGoogle Scholar
Hester, R. E. and Williams, K. P. J., 1981 Free-radical studies by resonance Raman spectroscopy. Photochemi-cally generated N-substituted benzidine cation radicals J. Chem. Soc. Faraday Trans. 2 77 541–547.CrossRefGoogle Scholar
McBride, M. B., 1979 Reactivity of adsorbed and structural iron in hectorite as indicated by oxidation of benzidine Clays & Clay Minerals 27 224–230.CrossRefGoogle Scholar
McBride, M. B., 1985 Surface reactions of 3,3‣,5,5‣-tetra-methyl benzidine on hectorite Clays & Clay Minerals 33 510–516.CrossRefGoogle Scholar
McBride, M. B., Pinnavaia, T. J., Mortland, M. M. and Suffet, I. H., 1977 Adsorption of aromatic molecules by clays in aqueous suspension Fate of Pollutants in the Air and Water Environments, Part I New York Wiley 145–154.Google Scholar
Meites, L. and Zuman, P., 1977 Handbook Series in Organic Electrochemistry Cleveland, Ohio CRC Press.Google Scholar