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One-Step Fabrication of Magnetic Polymer/Montmorillonite Adsorbent for Highly Efficient Phenol Adsorption

Published online by Cambridge University Press:  01 January 2024

Pei Geng ,
Haidong Hao ,
Jingmao Guo ,
Yuxin Wang ,
Jianchao Ma  and
Xin Wang Open the ORCID record for Xin Wang [Opens in a new window]
Pei Geng
Affiliation:
College of Mining Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, People's Republic of China
Haidong Hao
Affiliation:
College of Mining Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, People's Republic of China
Jingmao Guo
Affiliation:
College of Mining Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, People's Republic of China
Yuxin Wang
Affiliation:
College of Mining Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, People's Republic of China
Jianchao Ma*
Affiliation:
College of Mining Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, People's Republic of China
Xin Wang*
Affiliation:
Shanxi Key Laboratory of Biomedical Metal Materials, School of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, People's Republic of China
*
e-mail: majianchao@tyut.edu.cn
e-mail: wangxin01@tyut.edu.cn
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Abstract

Phenol contaminants are highly biotoxic and have become a global problem threatening the environment and human health. The objective of the present study was to develop a very efficient and easily recyclable adsorbent to remove phenol. A magnetic montmorillonite composite with organic co-intercalation was fabricated by a simple one-step co-precipitation method and exhibited excellent phenol removal. Two surfactants, cetyltrimethylammonium bromide (CTAB) and erucic acid amide (EA), were successfully co-intercalated into the interlayer of Ca-montmorillonite, and Fe3O4 nanoparticles were simultaneously decorated to obtain Fe3O4-CTAB/EA-montmorillonite composite (Fe3O4-C/E-Mnt). The morphology and structure of Fe3O4-C/E-Mnt composite were explored by using different techniques such as X-ray diffraction, Fourier-Transform infrared spectroscopy, X-ray photoelectron microscopy and so on. The adsorption capacity of Fe3O4-C/E-Mnt for phenol was investigated under various conditions including temperature, pH, contact time, various phenol concentrations, and adsorbent dosage. The results showed that Fe3O4-C/E-Mnt retained a lamellar structure of Ca-Mnt with mesopores. Its interlayer space, surface area, and pore volume were increased. The Fe3O4-C/E-Mnt composite exhibited a good adsorption capacity (31.45 mg·g–1) for phenol with a removal efficiency of 85.46% at optimized conditions. Moreover, the adsorbent still maintained 78.32% of the adsorption capacity after five cycles. The adsorption test data of Fe3O4-C/E-Mnt followed the pseudo-second order kinetic model and the Langmuir model. The adsorption was a spontaneous, exothermic, entropy-decreasing process, and a possible adsorption mechanism of Fe3O4-C/E-Mnt was finally proposed.

Keywords

Adsorption technologyMontmorillonite compositeOne-step fabricationPhenol removal
Type
Original Paper
Information
Clays and Clay Minerals , Volume 71 , Issue 4 , August 2023 , pp. 377 - 396
Copyright
Copyright © Clay Minerals Society 2023

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Footnotes

Pei Geng and Haidong Hao contributed equally to this work.

References

Abdelali, EG, Jose, MD, Elisenda, PM, Oscar, MG, Brahim, EB, Jose, AN, Abdelhak, K. Mesoporous pyrophyllite–titania nanocomposites: Synthesis and activity in phenol photocatalytic degradation. Research on Chemical Intermediates. 2019, 45, 333–353. 10.1007/s11164-018-3605-8Google Scholar
Adebayo, MA, Areo, F. Removal of phenol and 4-nitrophenol from wastewater using a composite prepared from clay and Cocos nucifera shell: Kinetic, equilibrium and thermodynamic studies. Resources, Environment and Sustainability. 2021, 3, 10.1016/j.resenv.2021.10002010.1016/j.resenv.2021.100020CrossRefGoogle Scholar
An, X, Zhang, L, He, Y, Zhu, W, Luo, Y. Kinetic, isotherm, and thermodynamic studies of Cr(VI) removal from aqueous solution using mesoporous silica materials prepared by fly ash. The Canadian Journal of Chemical Engineering. 2020, 98, 1825–1834. 10.1002/cjce.2372810.1002/cjce.23728CrossRefGoogle Scholar
Asnaoui, H, Dehmani, Y, Khalis, M, Hachem, EK. Adsorption of phenol from aqueous solutions by Na–bentonite: Kinetic, equilibrium and thermodynamic studies. International Journal of Environmental Analytical Chemistry. 2022, 102, 13 3043–3057. 10.1080/03067319.2020.176332810.1080/03067319.2020.1763328CrossRefGoogle Scholar
Barraqué, F, Montes, ML, Fernández, MA, Candal, R, Sánchez, RT, Marco-Brown, JL. Arsenate removal from aqueous solution by montmorillonite and organo-montmorillonite magnetic materials. Environmental Research. 2021, 192, 110247. 10.1016/j.envres.2020.11024710.1016/j.envres.2020.110247CrossRefGoogle ScholarPubMed
Battas, A, El Gaidoumi, A, Ksakas, A, Kherbeche, A. Adsorption study for the removal of nitrate from water using local clay. The Scientific World Journal. 2019, 10.1155/2019/952961810.1155/2019/9529618CrossRefGoogle ScholarPubMed
Bwatanglang, IB, Magili, ST, Kaigamma, I. Adsorption of phenol over bio-based silica/calcium carbonate (CS-SiO2/CaCO3) nanocomposite synthesized from waste eggshells and rice husks. PeerJ Physical Chemistry. 2021, 3, 10.7717/peerj-pchem.1710.7717/peerj-pchem.17CrossRefGoogle Scholar
Chang, J, Ma, J, Ma, Q, Zhang, D, Qiao, N, Hu, M, Ma, H. Adsorption of methylene blue onto Fe3O4/activated montmorillonite nanocomposite. Applied Clay Science. 2016, 119, 132–140. 10.1016/j.clay.2015.06.03810.1016/j.clay.2015.06.038CrossRefGoogle Scholar
Chen, CM, Yao, XY, Li, QX, Wang, QH, Liang, JH, Zhang, SM et al. Turf soil enhances treatment efficiency and performance of phenolic wastewater in an up-flow anaerobic sludge blanket reactor. Chemosphere. 2018, 204, 277–234. 10.1016/j.chemosphere.2018.04.04010.1016/j.chemosphere.2018.04.040CrossRefGoogle Scholar
Cheng, Z, Chen, Z, Li, J, Zuo, S, Yang, P. Mesoporous silica-pillared clays supported nanosized co3o4-ceo2 for catalytic combustion of toluene. Applied Surface Science. 2018, 459, 32–39. 10.1016/j.apsusc.2018.07.20310.1016/j.apsusc.2018.07.203CrossRefGoogle Scholar
Cheng, Y, Song, R, Wu, K, Peng, N, Yang, M, Luo, J et al. The enhanced visible-light-driven antibacterial performances of PTCDI-PANI(Fe(iii)-doped) heterostructure. Journal of Hazardous Materials. 2020, 383, 121166. 10.1016/j.jhazmat.2019.12116610.1016/j.jhazmat.2019.121166CrossRefGoogle ScholarPubMed
Cottet, L, Almeida, CAP, Naidek, N, Viante, MF, Lopes, MC, Debacher, NA. Adsorption characteristics of montmorillonite clay modified with iron oxide with respect to methylene blue in aqueous media. Applied Clay Science. 2014, 95, 25–31. 10.1016/j.clay.2014.03.02310.1016/j.clay.2014.03.023CrossRefGoogle Scholar
Das, R, Sypu, VS, Paumo, HK, Bhaumik, M, Maharaj, V, Maity, A. Silver decorated magnetic nanocomposite (Fe3O4-PPY-MAA/Ag) as highly active catalyst towards reduction of 4-nitrophenol and toxic organic dyes. Applied Catalysis b: Environmental. 2019, 244, 546–558. 10.1016/j.apcatb.2018.11.07310.1016/j.apcatb.2018.11.073CrossRefGoogle Scholar
Dehmani, Y, Sellaoui, L, Alghamdi, Y, Laine, J, Badawi, M, Amhoud, A et al. Kinetic, thermodynamic and mechanism study of the adsorption of phenol on Moroccan clay. Journal of Molecular Liquids. 2020, 312, 10.1016/j.molliq.2020.11338310.1016/j.molliq.2020.113383CrossRefGoogle Scholar
Fan, T, Pan, D, Zhang, H. Study on formation mechanism by monitoring the morphology and structure evolution of nearly monodispersed Fe3O4 submicroparticles with controlled particle sizes. Industrial & Engineering Chemistry Research. 2011, 50, 9009–9018. 10.1021/ie200970j10.1021/ie200970jCrossRefGoogle Scholar
Feng, G, Ma, J, Zhang, X, Zhang, Q, Xiao, Y, Ma, Q, Wang, S. Magnetic natural composite Fe3O4-chitosan-bentonite for removal of heavy metals from acid mine drainage. Journal of Colloid and Interface Science. 2019, 538, 132–141. 10.1016/j.jcis.2018.11.08710.1016/j.jcis.2018.11.087CrossRefGoogle ScholarPubMed
Freundlich, H. Über die adsorption in lösungen. Zeitschrift Für Physikalische Chemie. 1907, 57U, 385–470. 10.1515/zpch-1907-572310.1515/zpch-1907-5723CrossRefGoogle Scholar
Gaidoumi, AE, Benabdallah, AC, Bali, BE, Kherbeche, A. Synthesis and characterization of zeolite HS using natural pyrophyllite as new clay source. Arabian Journal for Science and Engineering. 2018, 43, 1 191–197. 10.1007/s13369-017-2768-810.1007/s13369-017-2768-8CrossRefGoogle Scholar
Gaidoumi, AE, Loqman, A, Benadallah, AC, Bali, BE, Kherbeche, A. Co (II)-pyrophyllite as catalyst for phenol oxidative degradation: Optimization study using response surface methodology. Waste and Biomass Valorization. 2019, 10, 4 1043–1051. 10.1007/s12649-017-0117-510.1007/s12649-017-0117-5CrossRefGoogle Scholar
Gaidoumi, AE, Doña-Rodríguez, JM, Melián, EP, González-Díaz, OM, Navío, JA, Bali, BE, Kherbeche, A. Catalytic efficiency of Cu-supported pyrophyllite in heterogeneous catalytic oxidation of phenol. Arabian Journal for Science and Engineering. 2019, 44, 7 6313–6325. 10.1007/s13369-019-03757-210.1007/s13369-019-03757-2CrossRefGoogle Scholar
Gaidoumi, AE, Doña-Rodríguez, JM, Melián, EP, González-Díaz, OM, Bali, BE, Navío, JA, Kherbeche, A. Mesoporous pyrophyllite–titania nanocomposites: Synthesis and activity in phenol photocatalytic degradation. Research on Chemical Intermediates. 2019, 45, 2 333–353. 10.1007/s11164-018-3605-810.1007/s11164-018-3605-8CrossRefGoogle Scholar
Gao, Y, Dai, Y, Zhang, H, Diao, E, Hou, H, Dong, H. Effects of organic modification of montmorillonite on the performance of starch-based nanocomposite films. Applied Clay Science. 2014, 99, 201–206. 10.1016/j.clay.2014.06.03310.1016/j.clay.2014.06.033CrossRefGoogle Scholar
Gupta, K, Khatri, OP. Fast and efficient adsorptive removal of organic dyes and active pharmaceutical ingredient by microporous carbon: Effect of molecular size and charge. Chemical Engineering Journal. 2019, 378, 122218. 10.1016/j.cej.2019.12221810.1016/j.cej.2019.122218CrossRefGoogle Scholar
Hameed, BH, Rahman, AA. Removal of phenol from aqueous solutions by adsorption onto activated carbon prepared from biomass material. Journal of Hazardous Materials. 2008, 160, 576–581. 10.1016/j.jhazmat.2008.03.02810.1016/j.jhazmat.2008.03.028CrossRefGoogle ScholarPubMed
Han, SJ, Lee, HI, Jeong, HM, Kim, BK, Raghu, AV, Reddy, KR. Graphene modified lipophilically by stearic acid and its composite with low density polyethylene. Journal of Macromolecular Science, Part B. 2014, 53, 1193–1204. 10.1080/00222348.2013.87980410.1080/00222348.2013.879804CrossRefGoogle Scholar
Han, JL, Xia, X, Haider, MR, Jiang, WL, Tao, Y, Liu, MJ et al. Functional graphene oxide membrane preparation for organics/inorganic salts mixture separation aiming at advanced treatment of refractory wastewater. Science of the Total Environment. 2018, 628, 261–270. 10.1016/j.scitotenv.2018.02.04310.1016/j.scitotenv.2018.02.043CrossRefGoogle ScholarPubMed
He, R, Yuan, X, Huang, Z, Wang, H, Jiang, L, Huang, J, Tan, M, Li, H. Activated biochar with iron-loading and its application in removing cr (vi) from aqueous solution. Colloids and Surfaces a: Physicochemical and Engineering Aspects. 2019, 579, 123642. 10.1016/j.colsurfa.2019.12364210.1016/j.colsurfa.2019.123642CrossRefGoogle Scholar
He, HJ, Xu, EP, Qiu, ZH, Wu, T, Wang, SF, Lu, YH, Chen, GN. Phenol Adsorption Mechanism of Organically Modified Bentonite and Its Microstructural Changes. Sustainability. 2022, 14, 3 1318. 10.3390/su1403131810.3390/su14031318CrossRefGoogle Scholar
Ho, ZH, Adnan, LA. Phenol removal from aqueous solution by adsorption technique using coconut shell activated carbon. Tropical Aquatic and Soil Pollution. 2021, 1, 2 98–107. 10.53623/tasp.v1i2.2110.53623/tasp.v1i2.21CrossRefGoogle Scholar
Ho, YS, McKay, G. Pseudo-second order model for sorption processes. Process Biochemistry. 1999, 34, 5 451–465. 10.1016/S0032-9592(98)00112-510.1016/S0032-9592(98)00112-5CrossRefGoogle Scholar
Jiang, DH, Liu, ZR, Fu, LJ, Yang, HM. Interfacial Chemical-Bond-Modulated Charge Transfer of Heterostructures for Improving Photocatalytic Performance. ACS Applied Materials & Interfaces. 2020, 12, 8 9872–9880. 10.1021/acsami.9b1718310.1021/acsami.9b17183CrossRefGoogle ScholarPubMed
Jiang, K, Liu, K, Peng, Q, Zhou, MY. Adsorption of Pb (II) and Zn (II) ions on humus-like substances modified montmorillonite. Colloids and Surfaces a: Physicochemical and Engineering Aspects. 2021, 631, 127706. 10.1016/j.colsurfa.2021.12770610.1016/j.colsurfa.2021.127706CrossRefGoogle Scholar
Kamiya, K, Hashimoto, K, Nakanishi, S. Instantaneous one-pot synthesis of Fe-N-modified graphene as an efficient electrocatalyst for the oxygen reduction reaction in acidic solutions. Chemical Communications. 2012, 48, 10213–10215. 10.1039/c2cc34719a10.1039/c2cc34719aCrossRefGoogle ScholarPubMed
Karaca, S, Önal, EÇ, Açışlı, Ö, Khataee, A. Preparation of chitosan modified montmorillonite biocomposite for sonocatalysis of dyes: Parameters and degradation mechanism. Materials Chemistry and Physics. 2021, 260, 124125. 10.1016/j.matchemphys.2020.12412510.1016/j.matchemphys.2020.124125CrossRefGoogle Scholar
Kaur, R, Bakshi, MS. Mechanistic aspects of simultaneous extraction of silver and gold nanoparticles across aqueous–organic interfaces by surface active iron oxide nanoparticles. Langmuir. 2020, 36, 7505–7516. 10.1021/acs.langmuir.0c0110210.1021/acs.langmuir.0c01102CrossRefGoogle ScholarPubMed
Kong, Z, Li, L, Xue, Y, Yang, M, Li, YY. Challenges and prospects for the anaerobic treatment of chemical-industrial organic wastewater: A review. Journal of Cleaner Production. 2019, 231, 913–927. 10.1016/j.jclepro.2019.05.23310.1016/j.jclepro.2019.05.233CrossRefGoogle Scholar
Lagergren, SK. About the theory of so-called adsorption of soluble substances. Sven. Vetenskapsakad. Handingarl. 1898, 24, 1–39Google Scholar
Langmuir, I. The constitution and fundamental properties of solids and liquids Part I Solids. Journal of the American chemical society. 1916, 38, 11 2221–2295. 10.1021/ja02268a00210.1021/ja02268a002CrossRefGoogle Scholar
Lawal, IA, Moodley, B. Synthesis, characterisation and application of imidazolium based ionic liquid modified montmorillonite sorbents for the removal of amaranth dye. RSC Advances. 2015, 5, 76 61913–61924. 10.1039/C5RA09483F10.1039/C5RA09483FCrossRefGoogle Scholar
Li, B, Mao, H, Li, X, Ma, W, Liu, Z. Synthesis of mesoporous silica-pillared clay by intragallery ammonia-catalyzed hydrolysis of tetraethoxysilane using quaternary ammonium surfactants as gallery templates. Journal of Colloid and Interface Science. 2009, 336, 244–249. 10.1016/j.jcis.2009.03.03910.1016/j.jcis.2009.03.039CrossRefGoogle ScholarPubMed
Li, JM, Meng, XG, Hu, CW, Du, J. Adsorption of phenol, p-chlorophenol and p-nitrophenol onto functional chitosan. Bioresource Technology. 2009, 100, 1168–1173. 10.1016/j.biortech.2008.09.01510.1016/j.biortech.2008.09.015CrossRefGoogle ScholarPubMed
Li, Y, Hu, X, Liu, X, Zhang, Y, Zhao, Q, Ning, P, Tian, S. Adsorption behavior of phenol by reversible surfactant-modified montmorillonite: Mechanism, thermodynamics, and regeneration. Chemical Engineering Journal. 2018, 334, 1214–1221. 10.1016/j.cej.2017.09.14010.1016/j.cej.2017.09.140CrossRefGoogle Scholar
Li, X, Cui, K, Guo, Z, Yang, T, Cao, Y, Xiang, Y et al. Heterogeneous fenton-like degradation of tetracyclines using porous magnetic chitosan microspheres as an efficient catalyst compared with two preparation methods. Chemical Engineering Journal. 2020, 379, 122324. 10.1016/j.cej.2019.12232410.1016/j.cej.2019.122324CrossRefGoogle Scholar
Li, HJ, Yao, YT, Yang, XY, Zhou, XS, Lei, R, He, SF. Degradation of phenol by photocatalysis using TiO2/montmorillonite composites under UV light. Environmental Science and Pollution Research. 2022, 29, 68293–68305. 10.1007/s11356-022-20638-810.1007/s11356-022-20638-8CrossRefGoogle Scholar
Liu, XT, Yang, G. Mechanisms for cation exchange at the interfaces of montmorillonite nanoparticles: Insights for Pb control2+. Colloids and Surfaces a: Physicochemical and Engineering Aspects. 2022, 641, 128556. 10.1016/j.colsurfa.2022.12855610.1016/j.colsurfa.2022.128556CrossRefGoogle Scholar
Liu, QS, Zheng, T, Wang, P, Jiang, JP, Li, N. Adsorption isotherm, kinetic and mechanism studies of some substituted phenols on activated carbon fibers. Chemical Engineering Journal. 2010, 157, 348–356. 10.1016/j.cej.2009.11.01310.1016/j.cej.2009.11.013CrossRefGoogle Scholar
Liu, H, Chen, W, Liu, C, Liu, Y, Dong, C. Magnetic mesoporous clay adsorbent: Preparation, characterization and adsorption capacity for atrazine. Microporous and Mesoporous Materials. 2014, 194, 72–78. 10.1016/j.micromeso.2014.03.03810.1016/j.micromeso.2014.03.038CrossRefGoogle Scholar
Liu, YB, Yu, L, Ong, CN, Xie, JP. Nitrogen-doped graphene nanosheets as reactive water purification membranes. Nano Research. 2016, 9, 1983–1993. 10.1007/s12274-016-1089-710.1007/s12274-016-1089-7CrossRefGoogle Scholar
Liu, R, Dai, L, Si, CL. Mussel-inspired cellulose-based nanocomposite fibers for adsorption and photocatalytic degradation. ACS Sustainable Chemistry, & Engineering. 2018, 6, 15756–15763. 10.1021/acssuschemeng.8b0432010.1021/acssuschemeng.8b04320CrossRefGoogle Scholar
Liu, X, Tian, J, Li, Y, Sun, N, Mi, S, Xie, Y, Chen, Z. Enhanced dyes adsorption from wastewater via Fe3O4 nanoparticles functionalized activated carbon. Journal of Hazardous Materials. 2019, 373, 397–407. 10.1016/j.jhazmat.2019.03.10310.1016/j.jhazmat.2019.03.103CrossRefGoogle ScholarPubMed
Liu, S, Chen, M, Cao, X, Li, G, Zhang, D, Li, M et al. Chromium (VI) removal from water using cetylpyridinium chloride (CPC)-modified montmorillonite. Separation and Purification Technology. 2020, 214, 116732. 10.1016/j.seppur.2020.11673210.1016/j.seppur.2020.116732CrossRefGoogle Scholar
Loqman, A, El Bali, B, El Gaidoumi, A, Boularbah, A, Kherbeche, A, Lützenkirchen, J. The First Application of Moroccan Perlite as Industrial Dyes Removal. SILICON. 2022, 14, 2813–2838. 10.1007/s12633-021-01056-w10.1007/s12633-021-01056-wCrossRefGoogle Scholar
Luo, Z, Gao, M, Yang, S, Yang, Q. Adsorption of phenols on reduced-charge montmorillonites modified by bispyridinium dibromides: Mechanism, kinetics and thermodynamics studies. Colloids and Surfaces a: Physicochemical and Engineering Aspects. 2015, 482, 222–230. 10.1016/j.colsurfa.2015.05.01410.1016/j.colsurfa.2015.05.014CrossRefGoogle Scholar
Ma, XW, Li, SY, Hou, Y, Lv, H, Li, JJ, Cheng, TY et al. Adsorption of low-concentration organic pollutants from typical coal-fired power plants by activated carbon injection. Process Safety and Environmental Protection. 2022, 159, 1174–1183. 10.1016/j.psep.2022.02.00210.1016/j.psep.2022.02.002CrossRefGoogle Scholar
Maleki, ST, Sadati, SJ. Synthesis and investigation of hyperthermia properties of Fe3O4/HNTs magnetic nanocomposite. Inorganic Chemistry Communications. 2022, 145, 10.1016/j.inoche.2022.110000Google Scholar
Mandal, A, Mukhopadhyay, P, Das, SK. The study of adsorption efficiency of rice husk ash for removal of phenol from wastewater with low initial phenol concentration. SN Applied Sciences. 2019, 1, 2 1–13. 10.1007/s42452-019-0203-310.1007/s42452-019-0203-3CrossRefGoogle Scholar
Mao, H, Liu, X, Yang, J, Li, B, Chen, Q, Zhong, J. Fabrication of magnetic silica-pillared clay (spc) nanocomposites with ordered interlayer mesoporous structure for controlled drug release. Microporous and Mesoporous Materials. 2014, 184, 169–176. 10.1016/j.micromeso.2013.10.02010.1016/j.micromeso.2013.10.020CrossRefGoogle Scholar
Mehdi, AK, Susmita, SG, Krishna, GB, Dhruba, C. Montmorillonite and modified montmorillonite as adsorbents for removal of watersoluble organic dyes: A review on current status of the art. Inorganic Chemistry Communications. 2022, 143, 10.1016/j.inoche.2022.109686Google Scholar
Minisy, IM, Salahuddin, NA, Ayad, MM. Adsorption of methylene blue onto chitosan–montmorillonite/polyaniline nanocomposite. Applied Clay Science. 2021, 203, 10.1016/j.clay.2021.10599310.1016/j.clay.2021.105993CrossRefGoogle Scholar
Nourmoradi, H, Nikaeen, M, Khiadani, M. Removal of benzene, toluene, ethylbenzene and xylene (btex) from aqueous solutions by montmorillonite modified with nonionic surfactant: Equilibrium, kinetic and thermodynamic study. Chemical Engineering Journal. 2012, 191, 341–348. 10.1016/j.cej.2012.03.02910.1016/j.cej.2012.03.029CrossRefGoogle Scholar
Papazi, A, Karamanli, M, Kotzabasis, K. Comparative biodegradation of all chlorinated phenols by the microalga Scenedesmus obliquus—the biodegradation strategy of microalgae. Journal of Biotechnology. 2019, 296, 61–68. 10.1016/j.jbiotec.2019.03.01010.1016/j.jbiotec.2019.03.010CrossRefGoogle ScholarPubMed
Park, KW, Jung, JH, Seo, HJ, Kwon, OY. Mesoporous silica-pillared kenyaite and magadiite as catalytic support for partial oxidation of methane. Microporous and Mesoporous Materials. 2009, 121, 219–225. 10.1016/j.micromeso.2009.02.00210.1016/j.micromeso.2009.02.002CrossRefGoogle Scholar
Park, Y, Sun, Z, Ayoko, GA, Frost, RL. Bisphenol A sorption by organo-montmorillonite: Implications for the removal of organic contaminants from water. Chemosphere. 2014, 107, 249–256. 10.1016/j.chemosphere.2013.12.05010.1016/j.chemosphere.2013.12.050CrossRefGoogle ScholarPubMed
Piumetti, M, Fino, D, Russo, N. Mesoporous manganese oxides prepared by solution combustion synthesis as catalysts for the total oxidation of vocs. Applied Catalysis b: Environmental. 2015, 163, 277–287. 10.1016/j.apcatb.2014.08.01210.1016/j.apcatb.2014.08.012CrossRefGoogle Scholar
Rahmani, S, Zeynizadeh, B, Karami, S. Removal of cationic methylene blue dye using magnetic and anionic-cationic modified montmorillonite: Kinetic, isotherm and thermodynamic studies. Applied Clay Science. 2020, 184, 10.1016/j.clay.2019.10539110.1016/j.clay.2019.105391CrossRefGoogle Scholar
Rashidi, R, Omidi-Khaniabadi, Y, Ghaderpoori, M. Adsorption of Eriochrome black-T from aqueous environment by raw Montmorillonite. International Journal of Environmental Analytical Chemistry. 2023, 103, 11 2601–2615. 10.1080/03067319.2021.189513910.1080/03067319.2021.1895139CrossRefGoogle Scholar
Reddy, KR, Gomes, VG, Hassan, M. Carbon functionalized tio2 nanofibers for high efficiency photocatalysis. Materials Research Express. 2014, 1, 10.1088/2053-1591/1/1/01501210.1088/2053-1591/1/1/015012CrossRefGoogle Scholar
Ren, X, Zhang, Z, Luo, H, Hu, B, Dang, Z, Yang, C, Li, L. Adsorption of arsenic on modified montmorillonite. Applied Clay Science. 2014, 97, 17–23. 10.1016/j.clay.2014.05.02810.1016/j.clay.2014.05.028CrossRefGoogle Scholar
Ren, HP, Tian, SP, Zhu, M, Zhao, YZ, Li, KX, Ma, Q et al. Modification of montmorillonite by gemini surfactants with different chain lengths and its adsorption behavior for methyl orange. Applied Clay Science. 2018, 151, 29–36. 10.1016/j.clay.2017.10.02410.1016/j.clay.2017.10.024CrossRefGoogle Scholar
Sanqin, W, Zepeng, Z, Yunhua, W, Libing, L, Jiansheng, Z. Influence of montmorillonites exchange capacity on the basal spacing of cation–anion organo-montmorillonites. Materials Research Bulletin. 2014, 59, 59–64. 10.1016/j.materresbull.2014.06.00710.1016/j.materresbull.2014.06.007CrossRefGoogle Scholar
Silvano, J, Mello, JM, Silva, L, Riella, H, Fiori, M. Erucamide-nanoclay systems obtained by intercalation process. Materials Science Forum. 2017, 899, 36–41. 10.4028/www.scientific.net/MSF.899.3610.4028/www.scientific.net/MSF.899.36CrossRefGoogle Scholar
Sing, KSW. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure and Applied Chemistry. 1985, 57, 603–619. 10.1351/pac19855704060310.1351/pac198557040603CrossRefGoogle Scholar
Su, J, Lin, HF, Wang, QP, Xie, ZM, Chen, ZL. Adsorption of phenol from aqueous solutions by organomontmorillonite. Desalination. 2011, 269, 1–3 163–169. 10.1016/j.desal.2010.10.05610.1016/j.desal.2010.10.056CrossRefGoogle Scholar
Tamang, M, Paul, KK. Adsorptive treatment of phenol from aqueous solution using chitosan/calcined eggshell adsorbent: Optimization of preparation process using Taguchi statistical analysis. Journal of the Indian Chemical Society. 2022, 99, 1. 10.1016/j.jics.2021.10025110.1016/j.jics.2021.100251CrossRefGoogle Scholar
Tong, DS, Wu, CW, Adebajo, MO, Jin, GC, Yu, WH, Ji, SF, Zhou, CH. Adsorption of methylene blue from aqueous solution onto porous cellulose-derived carbon/montmorillonite nanocomposites. Applied Clay Science. 2018, 161, 256–264. 10.1016/j.clay.2018.02.01710.1016/j.clay.2018.02.017CrossRefGoogle Scholar
Uddin, MK. A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade. Chemical Engineering Journal. 2017, 308, 438–462. 10.1016/j.cej.2016.09.02910.1016/j.cej.2016.09.029CrossRefGoogle Scholar
Vanzetti, L, Pasquardini, L, Potrich, C, Vaghi, V, Battista, E, Causa, F, Pederzolli, C. Xps analysis of genomic DNA adsorbed on pei-modified surfaces. Surface and Interface Analysis. 2016, 48, 611–615. 10.1002/sia.593210.1002/sia.5932CrossRefGoogle Scholar
Wu, P, Wu, W, Li, S, Xing, N, Zhu, N, Li, P et al. Removal of Cd2+ from aqueous solution by adsorption using fe-montmorillonite. Journal of Hazardous Materials. 2009, 169, 824–830. 10.1016/j.jhazmat.2009.04.02210.1016/j.jhazmat.2009.04.022CrossRefGoogle ScholarPubMed
Xia, Q, Huang, B, Yuan, X, Wang, H, Wu, Z, Jiang, L et al. Modified stannous sulfide nanoparticles with metal-organic framework: Toward efficient and enhanced photocatalytic reduction of chromium (vi) under visible light. Journal of Colloid and Interface Science. 2018, 530, 481–492. 10.1016/j.jcis.2018.05.01510.1016/j.jcis.2018.05.015CrossRefGoogle ScholarPubMed
Xiong, Z, Li, S, Xia, Y. Highly stable water-soluble magnetic nanoparticles synthesized through combined co-precipitation, surface-modification, and decomposition of a hybrid hydrogel. New Journal of Chemistry. 2016, 40, 9951–9957. 10.1039/C6NJ02051H10.1039/C6NJ02051HCrossRefGoogle Scholar
Xu, W, Chen, Y, Zhang, W, Li, B. Fabrication of graphene oxide/bentonite composites with excellent adsorption performances for toluidine blue removal from aqueous solution. Advanced Powder Technology. 2019, 30, 493–501. 10.1016/j.apt.2018.11.02810.1016/j.apt.2018.11.028CrossRefGoogle Scholar
Yao, Y, Miao, S, Liu, S, Ma, LP, Sun, H, Wang, S. Synthesis, characterization, and adsorption properties of magnetic Fe3O4-graphene nanocomposite. Chemical Engineering Journal. 2012, 184, 326–332. 10.1016/j.cej.2011.12.01710.1016/j.cej.2011.12.017CrossRefGoogle Scholar
Yousef, RI, El-EswedAla’a H, B. Adsorption characteristics of natural zeolites as solid adsorbents for phenol removal from aqueous solutions: Kinetics, mechanism, and thermodynamics studies. Chemical Engineering Journal. 2011, 171, 3 1143–1149. 10.1016/j.cej.2011.05.01210.1016/j.cej.2011.05.012CrossRefGoogle Scholar
Zhang, Y, Li, K, Liao, J. Facile synthesis of reduced-graphene-oxide/rare-earth-metal-oxide aerogels as a highly efficient adsorbent for rhodamine-b. Applied Surface Science. 2020, 504, 10.1016/j.apsusc.2019.14437710.1016/j.apsusc.2019.144377CrossRefGoogle Scholar
Zhang, JC, Qin, L, Yang, YZ, Liu, XG. Porous carbon nanospheres aerogel based molecularly imprinted polymer for efficient phenol adsorption and removal from wastewater. Separation and Purification Technology. 2021, 274, 10.1016/j.seppur.2021.11902910.1016/j.seppur.2021.119029CrossRefGoogle Scholar
Zhou, F, Huang, J, Man, R. Hydrogen bonding of acylamino-modified macroporous cross-linked polystyrene resins with phenol. Journal of Chemical & Engineering Data. 2018, 63, 1917–1924. 10.1021/acs.jced.7b0101610.1021/acs.jced.7b01016CrossRefGoogle Scholar
Zhou, CH, Cun, JL, Gates, WP, Zhu, TT, Wei, HY. Co-intercalation of organic cations/amide molecules into montmorillonite with tunable hydrophobicity and swellability. Applied Clay Science. 2019, 179, 10.1016/j.clay.2019.10515710.1016/j.clay.2019.105157CrossRefGoogle Scholar
Zhu, J, Wang, T, Zhu, R, Ge, F, Yuan, P, He, H. Expansion characteristics of organo montmorillonites during the intercalation, aging, drying and rehydration processes: Effect of surfactant/CEC ratio. Colloids and Surfaces a: Physicochemical and Engineering Aspects. 2011, 384, 401–407. 10.1016/j.colsurfa.2011.04.02310.1016/j.colsurfa.2011.04.023CrossRefGoogle Scholar