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Nuclear Magnetic Resonance (NMR) Study of Cd2+ Sorption on Montmorillonite

Published online by Cambridge University Press:  28 February 2024

Paola Di Leo  and
Paul O'Brien
Paola Di Leo*
Affiliation:
Istituto di Ricerca sulle Argille, CNR, Area di Ricerca di Potenza, Via S. loja, 85050 Tito Scalo (PZ), Italy
Paul O'Brien
Affiliation:
Imperial College of Science, Technology and Medicine, South Kensington, SW72AY London, England
*
E-mail of corresponding author: pdileo@ira.pz.cnr.it
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Abstract

113Cd solid-state nuclear magnetic resonance (NMR) was used to identify possible Cd2+ adsorption sites in montmorillonite. The montmorillonite was treated with 0.1 and 1 M CdCl2 aqueous solutions and samples with 13 and 8-µm particle size were used. The data are consistent with a two-site model for sorption of Cd2+ on montmorillonite. Cd2+ is localized in the montmorillonite in two different sites: 1) in the interlayers as hydrated Cd2+ and 2) on the external surface, probably with few H2O molecules hydrating to it. Cadmium is also adsorbed as CdCl+ in the interlayer. Treatment with a 0.1 M CdCl2 solution produces adsorption of free Cd2+ in the interlayer whereas treatment with 1 M CdCl2 resulted in adsorption of Cd2+ in both the interlayer and on surface sites and the adsorption of CdCl+ in the interlayer. A larger particle size favors Cd2+ adsorption on the external surface whereas a smaller particle size favors Cd2+ adsorption in the interlayer.

Keywords

AdsorptionCadmiumMontmorilloniteNuclear Magnetic Resonance
Type
Research Article
Information
Clays and Clay Minerals , Volume 47 , Issue 6 , December 1999 , pp. 761 - 768
Copyright
Copyright © 1999, The Clay Minerals Society

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References

Ackerman, J.J.H. Orr, T.V. Bartuska, V.J. and Maciel, G.E., 1979 Effect of halide complexation of cadmium(II) on cadmium-113 chemical shifts Journal of the American Chemical Society 101 341–347 10.1021/ja00496a011.CrossRefGoogle Scholar
Armitage, I.M. Pajer, R.T. Schoot Uiterkamp, A.J.M. Chlebowski, J.F. and Coleman, J.E., 1976 Cadmium-113 Fourier transform nuclear magnetic resonance of cadmium(II) carbonic anhydrases and cadmium(II) alkaline phosphate Journal of the American Chemical Society 98 3710–3715 10.1021/ja00434a058.CrossRefGoogle Scholar
Banin, A. and Lahav, N., 1968 Particle size and surfaces properties of acidic montmorillonite in suspension Israel Journal of Chemistry 6 235–250 10.1002/ijch.196800034.CrossRefGoogle Scholar
Bank, S. Bank, J.E. and Ellis, P.D., 1989 Solid-state 113Cd nuclear magnetic resonance of exchanged montmorillonites The Journal of Physical Chemistry 93 4878 4855 10.1021/j100349a034.CrossRefGoogle Scholar
Brown, G. Brindley, G.W., Brindley, G.W. and Brown, G., 1980 X-ray diffraction pro-cedures for clay minerals identification Crystal Structures of Clay Minerals and Their X-ray Identification London Mineralogical Society 305–360.CrossRefGoogle Scholar
Chapman, H.D., Blak, C.A. Evans, D.D. White, J.L. Ensminger, L.E. and Clark, F.E., 1965 Cation exchange capacity Methods of Soil Analysis Madison, Wisconsin American Society of Agronomy 891–901.Google Scholar
Ellis, P.D., 1983 Cadmium-113 magnetic resonance spectroscopy Science 221 1141–1146 10.1126/science.221.4616.1141.CrossRefGoogle ScholarPubMed
Fripiat, J.J., 1990 High resolution solid state nuclear magnetic resonance applied to clay surface studies Proceedings of the 9th International Clay Conference, Strasbourg, France, 1989 86 15–24.Google Scholar
Green-Kelly, R., 1953 Irreversible dehydration in montmorillonite. Part II Clay Minerals Bulletin 2 52–56 10.1180/claymin.1953.002.9.09.CrossRefGoogle Scholar
Green-Kelly, R., 1953 The identification of montmorillonoids Journal of Soil Science 4 233–237.Google Scholar
Güven, N., Giiven, N. and Pollastro, R.M., 1992 Molecular aspect of aqueous smectite suspension Clay-Water Interface and its Rheological Implication Boulder, Colorado Clay Mineral Society Workshop Lectures 2–6.Google Scholar
Ingri, N. Kakolowicz, W. Sillen, L.G. and Warnquist, B., 1967 HALTAFALL, a computer program for chemical equilibria Talanta 14 1261–1270 10.1016/0039-9140(67)80203-0.CrossRefGoogle Scholar
Kim, Y. Cygan, R.T. and Kirkpatrick, R.J., 1996 133Cs NMR and XPS investigation of cesium adsorbed on clay minerals and related phases Geochimica et Cosmochimica Acta 60 1041–1052 10.1016/0016-7037(95)00452-1.CrossRefGoogle Scholar
Kim, Y. Kirkpatrick, R.J. and Cygan, R.T., 1996 133Cs NMR study of cesium adsorbed on the surface of kaolinite and illite Geochimica et Cosmochim Acta 60 4059–4074 10.1016/S0016-7037(96)00257-8.CrossRefGoogle Scholar
Kirkpatrick, R.J. and Hawthorne, E.C., 1988 NMR spectroscopy and dynamic processes in mineralogy and geochemistry Spectroscopic Methods in Mineralogy and Geology, Reviews in Mineralogy Washington, D.C. Mineralogical Society of America 341–403 10.1515/9781501508974-011.CrossRefGoogle Scholar
Laperche, V. Lambert, J.F. Prost, R. and Fripiat, J.J., 1990 High-resolution solid-state NMR of exchangeable cations in the interlayer surface of swelling mica: 23Na, 111Cd, and 133Cs vermiculites The Journal of Physical Chemistry 94 8821–8831 10.1021/j100388a015.CrossRefGoogle Scholar
Nolle, A., 1978 Isotropic and anisotropic nuclear magnetic shielding of 113Cd in cadmiumhalides, cadmium chalcogenides and in cadmiumcarbonate Naturforsch 666–671.CrossRefGoogle Scholar
Schramm, L.L. and Kwak, J.C.T., 1982 Influence of exchangeable cation composition on the size and shape of montmorillonite particles in dilute suspension Clays and Clay Minerals 30 40–48 10.1346/CCMN.1982.0300105.CrossRefGoogle Scholar
Shainberg, I. Kemper, W.D. and Bailey, S.W., 1966 Electrostatic forces between clay and cations as calculated and inferred from electrical conductivity Clays and Clay Minerals Pro-ceedings 14th National Conference, Berkeley, California, 1965 New York Pergamon Press 117–132.Google Scholar
Shomer, I. and Mingelgrin, U., 1978 A direct procedure for determining the number of plates in tactoids of smectite: The Na/Ca-montmorillonite case Clays and Clay Minerals 26 135–138 10.1346/CCMN.1978.0260208.CrossRefGoogle Scholar
Sposito, G., 1989 The Chemistry of Soils New York Oxford University Press.Google Scholar
Stebbins, J.F. and Hawthorne, F.C., 1988 NMR spectroscopy and dynamic processes in mineralogy and geochemistry Spectroscopic Methods in Mineralogy and Geology, Reviews in Mineralogy Washington, D.C. Mineralogical Society of America 405–429 10.1515/9781501508974-012.CrossRefGoogle Scholar
Summers, M.F., 1988 113Cd NMR spectroscopy of coordination compounds and proteins Coordination Chemistry Reviews 86 43–134 10.1016/0010-8545(88)85012-4.CrossRefGoogle Scholar
Tinet, D. Faugere, A.M. and Prost, R., 1991 113Cd NMR chemical shift tensor analysis of cadmium-exchanged clays and clay gels The Journal of Physical Chemistry 95 8804–8807 10.1021/j100175a070.CrossRefGoogle Scholar
Weiss, C.A. Jr. Kirkpatrick, R.J. and Altaner, S.P., 1990 The structural environments of cations adsorbed onto clays: 133Cs variable temperature MAS NMR spectroscopic study of hectorite Geochimca et Cosmochim Acta 54 1697–1711 10.1016/0016-7037(90)90398-5.CrossRefGoogle Scholar