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Microtopography of Regularly-Interstratified Mica and Smectite

Published online by Cambridge University Press:  28 February 2024

Ryuji Kitagawa
Affiliation:
Institute of Geology and Mineralogy, Faculty of Science, Hiroshima University, 1-3 Kagamiyama, Higashihiroshima 724, Japan
Toshihiko Matsuda
Affiliation:
Department of Earth Sciences, Okayama University, Tsushimanaka, Okayama 700, Japan

Abstract

The gold decoration technique of electron microscopy was used to observe the microtopography of natural (001) surfaces of 1:1 regularly-interstratified mica/smectite minerals (expandable layer: 40–45%) collected from four different pyrophyllite deposits in Japan. The specimens are characterized by parallel growth steps of malformed, circular or polygonal forms with varying step separations. Many particles exhibit paired steps that seem to show spiral growth. Microtopographic observations suggest that the growth of regular interstratification (at least for the specimens investigated in this study) normally takes place by an interlacing of paired steps. If the height of a single step corresponds to that of a mica or a smectite layer, the particles are estimated to be normally 40–300 Å in thickness. If the particles on which a spiral center is observed are single crystals of interstratified mica and smectite, then some crystals investigated in this study are far thicker than fundamental particles. The results of this study are interpreted to suggest that these regularly-interstratified mica/smectites were formed by hydrothermal metasomatism from their respective host rocks.

Type
Research Article
Copyright
Copyright © 1992, The Clay Minerals Society

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References

Ahn, J. H. and Buseck, P. R., Layer-stacking sequences and structural disorder in mixed-layer illite/smectite: Image simulations and HRTEM imaging Amer. Mineral 1990 75 267275.Google Scholar
Ahn, J. H. and Peacor, D. R., Transmission and analytical electron microscopy of the smectite-to-illite transition Clays & Clay Minerals 1986 34 165179 10.1346/CCMN.1986.0340207.Google Scholar
Baronnet, A., Growth mechanism and polytypism in synthetic hydroxyl-bearing phlogopite Amer. Mineral 1972 57 12721293.Google Scholar
Baronnet, A., Polytypism in micas: A survey with emphasis on the crystal growth aspect Current Topics in Materials Science 1980 5 447548.Google Scholar
Bassett, W. A., Role of hydroxyl orientation in mica alteration Geol. Soc. Amer. Bull 1960 71 449456 10.1130/0016-7606(1960)71[449:ROHOIM]2.0.CO;2.CrossRefGoogle Scholar
Bell, T. E., Microstructure in mixed-layer illite/smec-tite and its relationship to the reaction of smectite to illite Clays & Clay Minerals 1986 34 146154 10.1346/CCMN.1986.0340205.CrossRefGoogle Scholar
Bethke, C. M. and Altaner, S. P., Layer-by-layer mechanism of smectite illitization and application to a new rate law Clays & Clay Minerals 1986 34 136145 10.1346/CCMN.1986.0340204.CrossRefGoogle Scholar
Bethke, C. M., Vergo, N. and Altaner, S. P., Pathways of smectite illitization and application to a new rate law Clays & Clay Minerals 1986 34 125135 10.1346/CCMN.1986.0340203.CrossRefGoogle Scholar
Eberl, D. and Hower, J., The hydrothermal transfor-mation of sodium and potassium smectite into mixed-layer clay Clays & Clay Minerals 1977 25 215227 10.1346/CCMN.1977.0250308.CrossRefGoogle Scholar
Giese, R. F. Jr., Hydroxyl orientation in muscovite as indicated by electrostatic energy calculations Science 1971 172 263264 10.1126/science.172.3980.263.CrossRefGoogle ScholarPubMed
Giese, R. F. Jr., General discussion of K-exchange in mica Proc. Int. Clay Conf., Madrid, 1972, J. M. Ser-ratosa, Div. Ciencias C.S.I.C, Madrid 1972 493495.Google Scholar
Gilkes, R. J., Young, R. C. and Quirk, J. P., Oxidation of octahedral iron in biotite Clays & Clay Minerals 1972 20 303315 10.1346/CCMN.1972.0200507.CrossRefGoogle Scholar
Gritsaenko, G., Samotoyin, N. and Heller, L., The decoration method applied to the study of clay minerals Proc. Int. Clay Conf., Jerusalem, 1966, Vol. 1 1966 Jerusalem Israel Universities Press 391400.Google Scholar
Hower, J., Eslinger, E., Hower, M. and Perry, E., The mechanism of burial diagenetic reactions in argillaceous sediments: 1. Mineralogical and chemical evidence Geol. Soc. Amer. Bull 1976 87 725737 10.1130/0016-7606(1976)87<725:MOBMOA>2.0.CO;2.2.0.CO;2>CrossRefGoogle Scholar
Iiyama, T. and Roy, R., Controlled synthesis of het-eropolytypic (mixed-layer) clay minerals Clays & Clay Minerals 1963 10 422 10.1346/CCMN.1961.0100103.CrossRefGoogle Scholar
Inoue, A., Kohyama, N., Kitagawa, R. and Watanabe, T., Chemical and morphological evidence for the conversion of smectite to illite Clays & Clay Minerals 1987 35 111120 10.1346/CCMN.1987.0350203.CrossRefGoogle Scholar
Inoue, A., Velde, B., Meunier, A. and Touchard, G., Mechanism of illite formation during smectite-to-illite conversion in a hydrothermal system Amer. Mineral 1988 73 13251334.Google Scholar
Keller, W. D., Reynolds, R. C. and Inoue, A., Morphology of clay minerals in the smectite-to-illite conversion series by scanning electron microscopy Clays & Clay Minerals 1986 34 187197 10.1346/CCMN.1986.0340209.CrossRefGoogle Scholar
Kitagawa, R., Takeno, S. and Sunagawa, I., Surface microtopographies of sericite crystals formed in different environmental conditions Miner. J 1983 11 282296 10.2465/minerj.11.282.CrossRefGoogle Scholar
Matsuda, M., Mineralogical study on regularly interstratified dioctahedral mica-smectites Clay Sci 1984 6 117148.Google Scholar
Matsuda, T., Henmi, Y., Nagasawa, K. and Honda, S., Chemical compositions and X-ray properties of regularly interstratified micasmectites: Kobutsugaku Zasshi Spec. Issue 1981 15 96106.Google Scholar
Matsuda, T., Nagasawa, K., Tsuzuki, Y. and Henmi, K., Regularly interstratified dioctahedral mica-smectite from Roseki deposits in Japan Clay Miner 1981 16 91102 10.1180/claymin.1981.016.1.07.CrossRefGoogle Scholar
Morita, K. and Kakitani, S., An interstratified mica-montmorillonite mineral in the pyrophyllite deposit at Ki-riishi mine, Hiroshima Prefecture Kobutsugaku Zasshi 1977 14 220230.Google Scholar
Nadeau, P. H., Tait, J. M., McHardy, W. J. and Wilson, M. J., Interstratified XRD characteristics of physical mixtures of elementary clay particles Clay Miner 1984 19 6776 10.1180/claymin.1984.019.1.07.CrossRefGoogle Scholar
Nadeau, P. H., Wilson, M. J., McHardy, W. J. and Tait, J. M., Interparticle diffraction: A new concept for interstratified clays Clay Miner 1984 19 757769 10.1180/claymin.1984.019.5.06.CrossRefGoogle Scholar
Nadeau, P. H., Wilson, M. J., McHardy, W. J. and Tait, J. W., The conversion of smectite to illite during diagenesis: Evidence from some illitic clays from bentonites and sandstones Miner. Mag 1985 49 393400 10.1180/minmag.1985.049.352.10.CrossRefGoogle Scholar
Norrish, K., Factors in the weathering of mica to vermiculite Proc. Int. Clay Conf., Madrid, 1972 1972 1972 417432.Google Scholar
Ramseyer, K. and Boles, J. R., Mixed-layer illite/ smectite minerals in Tertiary sandstones and shales, San Joaquin basin, California Clays & Clay Minerals 1986 34 115124 10.1346/CCMN.1986.0340202.CrossRefGoogle Scholar
Sato, H., Microstructure of mica cleavage surfaces J. Japan Assoc. Mineral. Petrol. Econ. Geol 1970 64 192198 10.2465/ganko1941.64.192.CrossRefGoogle Scholar
Sudo, T., Hayashi, H., Shimoda, S. and Swineford, A., Mineralogical problems of intermediate clay minerals Clays & Clay Minerals, Proc. 9th Natl. Conf, West Lafayette, Indiana, 1960 1962 Oxford Pergamon Press 378392.Google Scholar
Sunagawa, I., Natural crystallization J. Crystal Growth 1977 52 214223 10.1016/0022-0248(77)90197-X.CrossRefGoogle Scholar
Sunagawa, I. and Sunagawa, I., Growth of crystals in nature Materials Science of the Earth’s Interior 1984 Tokyo Terrapub 63105.Google Scholar
Sunagawa, I. and Koshino, Y., Growth spirals on kaolin group minerals Amer. Mineral 1975 60 407412.Google Scholar
Sunagawa, I., Koshino, Y., Asakura, M. and Yamamoto, T., Growth mechanisms of some clay minerals Fortshr. Mineral 1975 52 217224.Google Scholar
Tomita, K., Experimental transformation of 2M sericite into a rectorite-type mixed-layer mineral by treatment with various salts. II. Experiments using a magnetic stirrer and a centrifuge Clays & Clay Minerals 1978 26 209216 10.1346/CCMN.1978.0260304.CrossRefGoogle Scholar
Tomura, S., Kitamura, M. and Sunagawa, I., Surface microtopography of metamorphic white micas Phys. Chem. Minerals 1979 5 6581 10.1007/BF00308169.CrossRefGoogle Scholar
Watanabe, T., The structural model of illite/smectite interstratified minerals and the diagram for its identification Clay Sci. 1 1988 91114.Google Scholar