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Determination of Hansen Solubility Parameters of Raw Muscovite

Published online by Cambridge University Press:  02 April 2024

Ming Weng Open the ORCID record for Ming Weng [Opens in a new window]  and
Xiuhua Wang Open the ORCID record for Xiuhua Wang [Opens in a new window]
Ming Weng
Affiliation:
College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, People's Republic of China
Xiuhua Wang*
Affiliation:
National & Local United Engineering Laboratory for Textile Fiber Materials and Processing Technology, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, People's Republic of China
*
e-mail: wxiuhua@126.com
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Abstract

Muscovite has been used increasingly as a substrate in flexible electronics and fillers in high-performance nanocomposites. Muscovite-based interfacial interactions play a crucial rule in material fabrication. Hansen solubility parameters (HSPs) have proven useful in characterizing molecular interactions within/between condensed phases. The present study aimed to determine the HSPs of raw muscovite (RM) and to investigate solvent dispersion mechanisms of RM. To achieve this, the solubilities of RM in 17 solvents were evaluated by dispersion tests, and the HSPs of RM were calculated as the center of the optimal solubility rotated-ellipsoid in HSP space, which included all good solvents, had the smallest number of outliers, and had the smallest volume. The resulting dispersion, polar, and hydrogen bonding components of RM were 18.301, 2.366, and 3.727 MPa1/2, respectively. By considering the HSPs and Kamlet-Taft's solvatochromic parameters of solvents, we concluded that the low polarity of RM is due to hindered K+/H+ exchange on the RM surface, resulting from limited water/moisture contact. For solvent dispersion of RM, essential conditions include strong dispersion forces and weak polar forces, finely tuned to match the surface property of RM at a certain hydration level. The HSPs of RM determined from dispersion tests were restricted to predicting/characterizing RM-based interfacial phenomena in an environment with strictly controlled water/moisture content. The HSP calculation method proposed herein was applicable to any clay mineral.

Keywords

DispersionHansen solubility parametersMuscoviteSolubility rotated-ellipsoid
Type
Original Paper
Information
Clays and Clay Minerals , Volume 71 , Issue 6 , December 2023 , pp. 673 - 683
Copyright
Copyright © The Author(s), under exclusive licence to The Clay Minerals Society 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

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Footnotes

Associate Editor: Luyi Sun

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